Skip to main content
SpringerLink
Log in

Mechanisms of pinning accompanying evaporation of colloidal dispersion droplets

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

Experiments have been performed to clarify the mechanism of pinning, i.e., the phenomenon of fixing menisci of evaporating dispersion droplets, related to the formation of ring-shaped deposits (coffee ring effect). The influence of particle concentration in dispersions and the degree of hydrophilicity (hydrophobicity) of substrates on pinning has been studied. It has been shown that there are three main mechanisms of pinning, with the first one being due to the hysteresis of droplet contact angle, the second mechanism resulting from the adhesion of particles to substrates, and the third one being caused by the formation of a dense adsorption layer on a substrate. A relation has been revealed between the pinning mechanism that occurs and the degree of substrate hydrophilicity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Molchanov, S.P., Roldughin, V.I., and Chernova-Kharaeva, I.A., Colloid J., 2015, vol. 77, p. 761.

    Article  CAS  Google Scholar 

  2. Molchanov, S.P., Roldughin, V.I., and Chernova-Kharaeva, I.A., Colloid J., 2015, vol. 77, p. 770.

    Article  CAS  Google Scholar 

  3. Molchanov, S.P., Roldughin, V.I., Chernova-Kharaeva, I.A., and Yurasik, G.A., Colloid J., 2016, vol. 78, p. 633.

    Article  CAS  Google Scholar 

  4. Deegan, R.D., Bakajin, O., Dupont, T.F., Huber, G., Nagel, S.R., and Witten, T.A., Nature (London), 1997, vol. 389, p. 827.

    Article  CAS  Google Scholar 

  5. Deegan, R.D., Bakajin, O., Dupont, T.F., Huber, G., Nagel, S.R., and Witten, T.A., Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top., 2000, vol. 62, p. 756.

    Article  CAS  Google Scholar 

  6. Kumnorkaew, P., Ee, Y.-K., Tansu, N., and Gilchrist, J.F., Langmuir, 2008, vol. 24, p. 12150.

    Article  CAS  Google Scholar 

  7. Zhang, D., Vangala, K., Jiang, D., Zou, S., and Pechan, T., Appl. Spectrosc., 2010, vol. 64, p. 1078.

    Article  CAS  Google Scholar 

  8. Bhardwaj, R., Fang, X., Somasundaran, P., and Attinger, D., Langmuir, 2010, vol. 26, p. 7833.

    Article  CAS  Google Scholar 

  9. Dugyala, V.R. and Basavaraj, M.G., Langmuir, 2014, vol. 30, p. 8680.

    Article  CAS  Google Scholar 

  10. Yunker, P.J., Still, T., Lohr, M.A., and Yodh, A.G., Nature (London), 2011, vol. 476, p. 308.

    Article  CAS  Google Scholar 

  11. Shen, X., Ho, C.-M., and Wong, T.-S., J. Phys. Chem. B, 2010, vol. 114, p. 5269.

    Article  CAS  Google Scholar 

  12. Li, Y.-F., Sheng, Y.-J., and Tsao, H.-K., Langmuir, 2013, vol. 29, p. 7802.

    Article  CAS  Google Scholar 

  13. Vysotskii, V.V., Roldughin, V.I., Uryupina, O.Ya., and Zaitseva, A.V., Colloid J., 2011, vol. 73, p. 176.

    Article  CAS  Google Scholar 

  14. Vysotskii, V.V., Uryupina, O.Ya., Senchikhin, I.N., and Roldughin, V.I., Colloid J., 2013, vol. 75, p. 142.

    Article  CAS  Google Scholar 

  15. Vysotskii, V.V., Uryupina, O.Ya., Senchikhin, I.N., and Roldughin, V.I., Colloid J., 2013, vol. 75, p. 634.

    Article  CAS  Google Scholar 

  16. Vysotskii, V.V., Roldughin, V.I., Uryupina, O.Ya., Senchikhin, I.N., and Zaitseva, A.V., Colloid J., 2014, vol. 76, p. 531.

    Article  CAS  Google Scholar 

  17. Nazarov, V.G. and Stolyarov, V.P., Colloid J., 2016, vol. 78, p. 75.

    Article  CAS  Google Scholar 

  18. Huang, W., Cui, L., Li, J., Luo, C., Zhang, J., Luan, S., Ding, Y., and Han, Y., Colloid Polym. Sci., 2006, vol. 284, p. 366.

    Article  CAS  Google Scholar 

  19. Sefiane, K. and Bennacer, R., J. Fluid Mech., 2011, vol. 667, p. 260.

    Article  Google Scholar 

  20. David, S., Sefiane, K., and Tadrist, L., Colloids Surf. A, 2007, vol. 298, p. 108.

    Article  CAS  Google Scholar 

  21. Vysotskii, V.V., Roldughin, V.I., Uryupina, O.Ya., Senchikhin, I.N., and Zaitseva, A.V., Colloid J., 2015, vol. 77, p. 431.

    Article  CAS  Google Scholar 

  22. Roldughin, V.I., Usp. Khim., 2004, vol. 73, p. 123.

    Article  Google Scholar 

  23. Terekhin, V.V., Dement’eva, O.V., and Rudoy, V.M., Usp. Khim., 2011, vol. 80, p. 477.

    Article  Google Scholar 

  24. Lebedev-Stepanov, P.V., Kadushnikov, R.M., Molchanov, S.P., Ivanov, A.A., Mitrokhin, V.P., Vlasov, K.O., Rubin, N.I., Yurasik, G.A., Nazarov, V.G., and Alfimov, M.V., Nanotechnol. Russ., 2013, vol. 8, nos. 3–4, p. 137.

    Article  Google Scholar 

  25. Vysotskii, V.V., Roldughin, V.I., and Uryupina, O.Ya., Colloid J., 2004, vol. 66, p. 777.

    Article  CAS  Google Scholar 

  26. Bhardwaj, R., Fang, X., and Attinger, D., New J. Phys., 2009, vol. 11, p. 075020.

    Article  Google Scholar 

  27. Roldughin, V.I., Fizikokhimiya poverkhnosti (Surface Physical Chemistry), Dolgoprudnyi Izd. Dom Intellekt, 2011.

    Google Scholar 

  28. Men’shikova, A.Yu., Shabsel’s, B.M., Evseeva, T.G., Shevchenko, N.N., and Bilibin, A.Yu., Russ. J. Appl. Chem., 2005, vol. 78, p. 159.

    Article  Google Scholar 

  29. Stöber, W., Fink, A., and Bohn, E., J. Colloid Interface Sci., 1968, vol. 26, p. 62.

    Article  Google Scholar 

  30. Derjaguin, B.V. and Churaev, N.V., Smachivayushchie plenki (Wetting Films), Moscow Nauka, 1984.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119071, Russia

    S. P. Molchanov

  2. Photochemistry Center, Russian Academy of Sciences, ul. Novatorov 7a, bldg. 1, Moscow, 119421, Russia

    S. P. Molchanov, I. A. Chernova-Kharaeva & G. A. Yurasik

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, bldg. 4, Moscow, 119071, Russia

    V. I. Roldughin

Authors
  1. S. P. Molchanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Roldughin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Chernova-Kharaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Yurasik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Roldughin.

Additional information

Original Russian Text © S.P. Molchanov, V.I. Roldughin, I.A. Chernova-Kharaeva, G.A. Yurasik, 2017, published in Kolloidnyi Zhurnal, 2017, Vol. 79, No. 2, pp. 182–191.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Molchanov, S.P., Roldughin, V.I., Chernova-Kharaeva, I.A. et al. Mechanisms of pinning accompanying evaporation of colloidal dispersion droplets. Colloid J 79, 234–243 (2017). https://doi.org/10.1134/S1061933X17020089

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X17020089

Search

Navigation