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A terahertz spectroscopic study of chitosan-based bionanocomposites containing clay nanoparticles

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Abstract

Dielectric properties of bionanocomposites resulting from regulated self-organization of chitosan and nanoparticles of synthetic saponite clay have been investigated by terahertz pulsed spectroscopy. Spectral characteristics of the composites considered in correlation with their structural features, which have been characterized by atomic force microscopy and scanning electron microscopy, depend on the concentration ratio of the components. The study of the effect of temperature on terahertz absorption spectra has led to the conclusion that hydrogen bonding may be involved in the formation of the bionanocomposites.

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References

  1. Ruiz-Hitzky, E., Darder, M., and Aranda, P., in BioInorganic Hybrid Nanomaterials, Ruiz-Hitzky, E., Ariga, K., and Lvov, Y.M., Eds., Weinheim: WileyVCH, 2008, p. 1.

  2. Ramakrishna, S., Huang, Z.M., Kumar, G.V., Batchelor, A.W., and Mayer, J., An Introduction to Biocomposites, London Imperial College Press, 2004.

    Book  Google Scholar 

  3. Shchipunov, Y., Pure Appl. Chem., 2012, vol. 84, p. 2579.

    Article  CAS  Google Scholar 

  4. Darder, M., Aranda, P., and Ruiz-Hitzky, E., Adv. Mater. (Weinheim, Fed. Repub. Ger.), 2007, vol. 19, p. 1309.

    Article  CAS  Google Scholar 

  5. Roberts, G.A.F., Chitin Chemistry, London MacMillan, 1992.

    Book  Google Scholar 

  6. Hirano, S., in Ullmann’s Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2000, p. 471.

    Google Scholar 

  7. Dash, M., Chiellini, F., Ottenbrite, R.M., and Chiellini, F., Prog. Polym. Sci., 2011, vol. 36, p. 981.

    Article  CAS  Google Scholar 

  8. Kotz, J. and Kosmella, S., in Adv. Chitin Sci. 7th Int. Conf. on Chitin and Chitosan, Domard, A., Roberts, G.A., and Varum, K.M., Eds., Lyon: Jacques Andre, 1998, p. 476.

    Google Scholar 

  9. Drogoz, A., David, L., Rochas, C., Domard, A., and Delair, T., Langmuir, 2007, vol. 23, p. 10950.

    Article  CAS  Google Scholar 

  10. Shchipunov, Y.A. and Postnova, I.V., Compos. Interfaces, 2009, vol. 16, p. 251.

    Article  CAS  Google Scholar 

  11. Sandford, P.A., in Chitin and Chitosan. Sources, Chemistry, Biochemistry, Physical Properties and Applications, Skjak-Braek, G., Anthonsen, T., and Sandford, P.A., Eds., London: Elsevier Appl. Sci., 1989, p. 51.

  12. Betigeri, S.S. and Neau, S.H., Biomaterials, 2002, vol. 23, p. 3627.

    Article  CAS  Google Scholar 

  13. Shumilina, E.V. and Shchipunov, Yu.A., Colloid J., 2002, vol. 64, p. 413.

    Article  Google Scholar 

  14. Schatz, C., Lucas, J.-M., Viton, C., Domard, A., Pichot, C., and Delair, T., Langmuir, 2004, vol. 20, p. 7766.

    Article  CAS  Google Scholar 

  15. Hirano, S., Macromol. Symp., 2001, vol. 168, p. 21.

    Article  CAS  Google Scholar 

  16. Shtil’man, M.I., Polimery mediko-biologicheskogo naznacheniya (Polymers of Biomedical Use), Moscow Akademkniga, 2006.

    Google Scholar 

  17. Kim, H.-J., Lee, H.-C., Oh, J.-S., Shin, B.-A., Oh, C.-S., Park, R.-D., Yang, K.-S., and Cho, C.-S., J. Biomater. Sci., Polym. Ed., 1999, vol. 10, p. 543.

    Article  CAS  Google Scholar 

  18. Zhao, Q., Han, B., Wang, Z., Gao, C., Peng, C., and Shen, J., Nanomed.: Nanotechnol. Biol. Med., 2007, vol. 3, p. 63.

    CAS  Google Scholar 

  19. Brigatti, M.F., Galan, E., and Theng, B.K.G., in Handbook of Clay Science. Developments in Clay Science, Bergaya, F., Theng, B.K.G., and Lagaly, G., Eds., Amsterdam: Elsevier, 2006, p. 19.

  20. Utracki, L.A., Clay-Containing Polymeric Nanocomposites, Shrewsbury, UK RAPRA Technology, 2004.

    Google Scholar 

  21. Wang, S., Chen, L., and Tong, Y., J. Polym. Sci., Part A: Polym. Chem., 2006, vol. 44, p. 686.

    Article  CAS  Google Scholar 

  22. Darder, M., Aranda, P., Ruiz, A.I., Fernandes, F.M., and Ruiz-Hitzky, E., Mater. Sci. Technol., 2008, vol. 24, p. 1100.

    Article  CAS  Google Scholar 

  23. Okada, O., Kawasumi, M., Usuki, A., Kojima, Y., Karauchi, T., and Kamigaito, O., MRS Symp. Proc., 1990, vol. 171, p. 45.

    Article  CAS  Google Scholar 

  24. Alexandre, M. and Dubois, P., Mater. Sci. Eng. R, 2000, vol. 28, p. 1.

    Article  Google Scholar 

  25. Ray, S.S. and Okamoto, M., Prog. Polym. Sci., 2003, vol. 28, p. 1539.

    Article  CAS  Google Scholar 

  26. Shchipunov, Y.A., Ivanova, N., and Silant’ev, V., Green Chem., 2009, vol. 11, p. 1758.

    Article  CAS  Google Scholar 

  27. Shchipunov, Yu.A., Silant’ev, V.E., and Postnova, I.V., Colloid J., 2012, vol. 74, p. 627.

    Article  CAS  Google Scholar 

  28. Shchipunov, Yu.A., Sarin, S.A., Silant’ev, V.E., and Postnova, I.V., Colloid J., 2012, vol. 74, p. 636.

    Article  CAS  Google Scholar 

  29. Smirnova, I.N., Sapozhnikov, D.A., Kargovsky, A.V., Volodin, V.A., Cherkasova, O.P., Bocquet, R., and Shkurinov, A.P., Vibr. Spectrosc., 2012, vol. 62, p. 238.

    Article  CAS  Google Scholar 

  30. Siripatrawan, U. and Harte, B.R., Food Hydrocolloids, 2010, vol. 24, p. 770.

    Article  CAS  Google Scholar 

  31. Katti, K.S., Katti, D.R., and Dash, R., Biomed. Mater., 2008, vol. 3, p. 034122.

    Article  Google Scholar 

  32. Abdollahi, M., Rezaei, M., and Farzi, G., J. Food Eng., 2012, vol. 111, p. 343.

    Article  CAS  Google Scholar 

  33. Darder, M., Colilla, M., and Ruiz-Hitzky, E., Chem. Mater., 2003, vol. 15, p. 3774.

    Article  CAS  Google Scholar 

  34. Lertworasirikul, A., Noguchi, K., Ogawa, K., and Okuyama, K., Carbohydr. Res., 2004, vol. 339, p. 835.

    Article  CAS  Google Scholar 

  35. Dolgaleva, K. and Boyd, R.W., Adv. Opt. Photon., 2012, vol. 4, p. 1.

    Article  Google Scholar 

  36. Landauer, R., J. Appl. Phys., 1952, vol. 23, p. 779.

    Article  CAS  Google Scholar 

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Correspondence to I. A. Ozheredov.

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Original Russian Text © E.A. Migal’, M.D. Mishchenko, I.A. Ozheredov, I. V. Postnova, D.A. Sapozhnikov, A.P. Shkurinov, Yu.A. Shchipunov, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 2, pp. 171–178.

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Migal’, E.A., Mishchenko, M.D., Ozheredov, I.A. et al. A terahertz spectroscopic study of chitosan-based bionanocomposites containing clay nanoparticles. Colloid J 78, 189–195 (2016). https://doi.org/10.1134/S1061933X16020095

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  • DOI: https://doi.org/10.1134/S1061933X16020095

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