Abstract
Dielectric properties of bionanocomposites resulting from regulated self-organization of chitosan and nanoparticles of synthetic saponite clay have been investigated by terahertz pulsed spectroscopy. Spectral characteristics of the composites considered in correlation with their structural features, which have been characterized by atomic force microscopy and scanning electron microscopy, depend on the concentration ratio of the components. The study of the effect of temperature on terahertz absorption spectra has led to the conclusion that hydrogen bonding may be involved in the formation of the bionanocomposites.
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Ruiz-Hitzky, E., Darder, M., and Aranda, P., in BioInorganic Hybrid Nanomaterials, Ruiz-Hitzky, E., Ariga, K., and Lvov, Y.M., Eds., Weinheim: WileyVCH, 2008, p. 1.
Ramakrishna, S., Huang, Z.M., Kumar, G.V., Batchelor, A.W., and Mayer, J., An Introduction to Biocomposites, London Imperial College Press, 2004.
Shchipunov, Y., Pure Appl. Chem., 2012, vol. 84, p. 2579.
Darder, M., Aranda, P., and Ruiz-Hitzky, E., Adv. Mater. (Weinheim, Fed. Repub. Ger.), 2007, vol. 19, p. 1309.
Roberts, G.A.F., Chitin Chemistry, London MacMillan, 1992.
Hirano, S., in Ullmann’s Encyclopedia of Industrial Chemistry, Weinheim: Wiley-VCH, 2000, p. 471.
Dash, M., Chiellini, F., Ottenbrite, R.M., and Chiellini, F., Prog. Polym. Sci., 2011, vol. 36, p. 981.
Kotz, J. and Kosmella, S., in Adv. Chitin Sci. 7th Int. Conf. on Chitin and Chitosan, Domard, A., Roberts, G.A., and Varum, K.M., Eds., Lyon: Jacques Andre, 1998, p. 476.
Drogoz, A., David, L., Rochas, C., Domard, A., and Delair, T., Langmuir, 2007, vol. 23, p. 10950.
Shchipunov, Y.A. and Postnova, I.V., Compos. Interfaces, 2009, vol. 16, p. 251.
Sandford, P.A., in Chitin and Chitosan. Sources, Chemistry, Biochemistry, Physical Properties and Applications, Skjak-Braek, G., Anthonsen, T., and Sandford, P.A., Eds., London: Elsevier Appl. Sci., 1989, p. 51.
Betigeri, S.S. and Neau, S.H., Biomaterials, 2002, vol. 23, p. 3627.
Shumilina, E.V. and Shchipunov, Yu.A., Colloid J., 2002, vol. 64, p. 413.
Schatz, C., Lucas, J.-M., Viton, C., Domard, A., Pichot, C., and Delair, T., Langmuir, 2004, vol. 20, p. 7766.
Hirano, S., Macromol. Symp., 2001, vol. 168, p. 21.
Shtil’man, M.I., Polimery mediko-biologicheskogo naznacheniya (Polymers of Biomedical Use), Moscow Akademkniga, 2006.
Kim, H.-J., Lee, H.-C., Oh, J.-S., Shin, B.-A., Oh, C.-S., Park, R.-D., Yang, K.-S., and Cho, C.-S., J. Biomater. Sci., Polym. Ed., 1999, vol. 10, p. 543.
Zhao, Q., Han, B., Wang, Z., Gao, C., Peng, C., and Shen, J., Nanomed.: Nanotechnol. Biol. Med., 2007, vol. 3, p. 63.
Brigatti, M.F., Galan, E., and Theng, B.K.G., in Handbook of Clay Science. Developments in Clay Science, Bergaya, F., Theng, B.K.G., and Lagaly, G., Eds., Amsterdam: Elsevier, 2006, p. 19.
Utracki, L.A., Clay-Containing Polymeric Nanocomposites, Shrewsbury, UK RAPRA Technology, 2004.
Wang, S., Chen, L., and Tong, Y., J. Polym. Sci., Part A: Polym. Chem., 2006, vol. 44, p. 686.
Darder, M., Aranda, P., Ruiz, A.I., Fernandes, F.M., and Ruiz-Hitzky, E., Mater. Sci. Technol., 2008, vol. 24, p. 1100.
Okada, O., Kawasumi, M., Usuki, A., Kojima, Y., Karauchi, T., and Kamigaito, O., MRS Symp. Proc., 1990, vol. 171, p. 45.
Alexandre, M. and Dubois, P., Mater. Sci. Eng. R, 2000, vol. 28, p. 1.
Ray, S.S. and Okamoto, M., Prog. Polym. Sci., 2003, vol. 28, p. 1539.
Shchipunov, Y.A., Ivanova, N., and Silant’ev, V., Green Chem., 2009, vol. 11, p. 1758.
Shchipunov, Yu.A., Silant’ev, V.E., and Postnova, I.V., Colloid J., 2012, vol. 74, p. 627.
Shchipunov, Yu.A., Sarin, S.A., Silant’ev, V.E., and Postnova, I.V., Colloid J., 2012, vol. 74, p. 636.
Smirnova, I.N., Sapozhnikov, D.A., Kargovsky, A.V., Volodin, V.A., Cherkasova, O.P., Bocquet, R., and Shkurinov, A.P., Vibr. Spectrosc., 2012, vol. 62, p. 238.
Siripatrawan, U. and Harte, B.R., Food Hydrocolloids, 2010, vol. 24, p. 770.
Katti, K.S., Katti, D.R., and Dash, R., Biomed. Mater., 2008, vol. 3, p. 034122.
Abdollahi, M., Rezaei, M., and Farzi, G., J. Food Eng., 2012, vol. 111, p. 343.
Darder, M., Colilla, M., and Ruiz-Hitzky, E., Chem. Mater., 2003, vol. 15, p. 3774.
Lertworasirikul, A., Noguchi, K., Ogawa, K., and Okuyama, K., Carbohydr. Res., 2004, vol. 339, p. 835.
Dolgaleva, K. and Boyd, R.W., Adv. Opt. Photon., 2012, vol. 4, p. 1.
Landauer, R., J. Appl. Phys., 1952, vol. 23, p. 779.
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Original Russian Text © E.A. Migal’, M.D. Mishchenko, I.A. Ozheredov, I. V. Postnova, D.A. Sapozhnikov, A.P. Shkurinov, Yu.A. Shchipunov, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 2, pp. 171–178.
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Migal’, E.A., Mishchenko, M.D., Ozheredov, I.A. et al. A terahertz spectroscopic study of chitosan-based bionanocomposites containing clay nanoparticles. Colloid J 78, 189–195 (2016). https://doi.org/10.1134/S1061933X16020095
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DOI: https://doi.org/10.1134/S1061933X16020095