Abstract
Chitosan films prepared by the thermal method from molding solutions containing ethanol as a chitosan precipitant have been used as separating membranes for pervaporation of an aqueous isopropanol solution. The flux density and permeate composition have been determined as functions of the composition of a molding solution and a solution to be separated, as well as the concentration prehistory of the separation process. The concentration prehistory reflects the specific features of swelling polymer sorbents, which are distinguished by a labile structure and macroscopic sorption deformations. The existence of a concentration prehistory implies that, at a fixed concentration of an initial solution, parameters characterizing the transport properties of a polymer depend on the process route in which this concentration has been achieved. The composition of a molding solution and the route of variations in the initial concentration of a solution to be separated that correspond to the highest value of our criterion for the process efficiency have been determined. It has been shown that, in the case of films formed from a solution containing 20 wt % ethanol, the water flux density reversibly increases by more than 100 times as compared with the flux density of a water-alcohol solution.
Similar content being viewed by others
References
Bykova, V.M. and Nemtseva, S.V., in Khitin i khitozan. Poluchenie, svoistva i primenenie (Chitin and Chitosan. Synthesis, Properties, Application), Skryabin, K.G., Vikhoreva, G.A., and Varlamov, V.P., Eds., Moscow: Nauka, 2002, p. 7.
Sinitsyna, G.M., Vlodavets, I.N., and Rehbinder, P.A., Dokl. Akad. Nauk SSSR, 1967, vol. 175, p. 399.
Vikhoreva, G.A. and Gal’braikh, L.S., in Khitin i khitozan. Poluchenie, svoistva i primenenie (Chitin and Chitosan. Synthesis, Properties, Application), Skryabin, K.G., Vikhoreva, G.A., and Varlamov, V.P., Eds., Moscow: Nauka, 2002, p. 217.
Uspenskii, S.A., Vikhoreva, G.A., Sonina, A.N., and Gal’braikh, L.S., Khim. Volokna, 2010, no. 2, p. 11.
Uspenskii, S.A., Sonina, A.N., Vikhoreva, G.A., Chernyshenko, A.O., Kechek’yan, A.S., Obolonkova, E.S., and Gal’braikh, L.S., Khim. Volokna, 2010, no. 6, p. 18.
Ageev, E.P., Matushkina, N.N., and Strusovkaya, N.L., Membr. Membr. Tekhnol., 2013, vol. 3, p. 9.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.P. Ageev, N.N. Matushkina, 2015, published in Kolloidnyi Zhurnal, 2015, Vol. 77, No. 3, pp. 267–272.
Rights and permissions
About this article
Cite this article
Ageev, E.P., Matushkina, N.N. Peculiarities of the transport properties of chitosan films. 1. Concentration prehistory of pervaporation. Colloid J 77, 251–255 (2015). https://doi.org/10.1134/S1061933X15030023
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X15030023