Abstract
The form of the empirical Simon equation describing the dependence of the phase-transition temperature on pressure is shown to be asymptotically strict when the system tends to absolute zero of temperature, and then only for crystalline phases.
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F. E. Simon and G. Glatzel, Z. Anorg. Allg. Chem. 178 (3), 309 (1929).
V. P. Skripov and M. Z. Faizulin, Liquids-Vapor Phase Transitions and Thermodynamic Similarity (Fizmatlit, Moscow, 2003) [in Russian].
A. Yu. Basharin, V. S. Dozhdikov, A. V. Kirillin, M. A. Turchaninov, and L. R. Fokin, Pis’ma Zh. Tekh. Fiz. 36 (12), 39 (2010).
V. P. Skripov, in Metastable States and Phase Transitions (In-t teplofiziki Uro RAN, Yekaterinburg, 1997), No. 1, pp. 21–46 [in Russian].
L. S. Shvindlerman, Zh. Fiz. Khim. 42 (2), 492 (1968).
P. P. Fedorov, Kristallografiya 40 (2), 308 (1995).
P. P. Fedorov and B. P. Sobolev, Kristallografiya 40 (2), 315 (1995).
P. P. Fedorov, M. V. Nazarkin, and R. M. Zakalyukin, Crystallogr. Rep. 47 (2), 281 (2002).
P. P. Fedorov, Crystallogr. Rep. 55 (1), 116 (2008).
E. Yu. Tonkov, High Pressure Phase Transformations. A Handbook, Vol. 3 (Gordon and Breach Publ., Australia, 1996).
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Original Russian Text © P.P. Fedorov, 2016, published in Doklady Akademii Nauk, 2016, Vol. 470, No. 1, pp. 30–31.
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Fedorov, P.P. Derivation of the Simon equation. Dokl. Phys. 61, 427–428 (2016). https://doi.org/10.1134/S1028335816090020
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DOI: https://doi.org/10.1134/S1028335816090020