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Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface

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Abstract—

We report on a synthesis procedure for obtaining a UiO-66 metal-organic framework in the form of nanoparticles with a modified surface. A distinctive feature of the developed procedure is that modification occurs directly during synthesis. Biocompatible polyethylene glycol (PEG) is selected as the organic polymer covering the surface of the UiO-66 nanoparticles. The effect of the degree of PEG polymerization on the size, morphology, and surface charge of UiO-66 nanoparticles is studied. The presence of PEG molecules is confirmed by infrared (IR) spectroscopy. The materials obtained are single phase and characterized by a high degree of crystallinity. The particle size varies from 80 to 120 nm, depending on the type of PEG used. A high surface charge in an aqueous medium (ζ-potential over 20 mV) indicates the possibility of forming a stable suspension. Thus, the obtained materials are promising as nanocontainers for the delivery of biologically active substances.

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Funding

The study was supported by the Russian Science Foundation, project no. 19-73-10 069.

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Authors and Affiliations

  1. The Smart Materials Research Institute, Southern Federal University, 344090, Rostov-on-Don, Russia

    V. V. Butova, O. A. Burachevskaya, P. V. Medvedev, I. E. Gorban, A. A. Kuzharov & M. A. Soldatov

  2. Shubnikov Institute of Crystallography FSRC “Crystallography and Photonics”, Russian Academy of Sciences, 119333, Moscow, Russia

    D. B. Trushina

  3. Sechenov First Moscow State Medical University, 119991, Moscow, Russia

    D. B. Trushina

Authors
  1. V. V. Butova
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  2. O. A. Burachevskaya
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  3. P. V. Medvedev
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  4. I. E. Gorban
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  5. A. A. Kuzharov
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  6. D. B. Trushina
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  7. M. A. Soldatov
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Corresponding author

Correspondence to V. V. Butova.

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Translated by V. Kudrinskaya

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Butova, V.V., Burachevskaya, O.A., Medvedev, P.V. et al. Synthesis of the Metal-Organic Framework UiO-66 in the Form of Nanoparticles with a Modified Surface. J. Surf. Investig. 15, 920–926 (2021). https://doi.org/10.1134/S1027451021050037

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  • DOI: https://doi.org/10.1134/S1027451021050037

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