Skip to main content
SpringerLink
Log in

Release of Hydrogen Isotopes from Pd under Radiation, Joule, and Thermal Exposure

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

The release of hydrogen isotopes (H, D) from Pd is studied under linear heating (a) by an accelerated electron beam, (b) by alternating current Joule heat (50 Hz) passed through the samples, and in external coaxial furnaces in (c) metallic (stainless steel) and (d) quartz vacuum cells. The cathode saturation of Pd samples with hydrogen and deuterium is used. The studies are performed in a high-vacuum installation. The recording of gases leaving the materials is carried out by mass spectrometry. The maximum shift in the position of the temperature maxima of the thermal-gas release of hydrogen and deuterium from palladium to the low-temperature region is observed when the samples are heated by electric current and heated in the quartz vacuum cell. The mechanisms of the release of hydrogen isotopes from metals due to the accumulation of electron-beam energy and electromagnetic field by the hydrogen subsystem of the crystals are considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. E. C. H. Sykes, L. C. Fernandez-Torres, S. U. Nanayakkara, B. A. Mantooth, R. M. Nevin, and P. S. Weiss, Proc. Natl. Acad. Sci. U. S. A. 102, 17907 (2005). https://doi.org/10.1073/pnas.0506657102

    Article  CAS  Google Scholar 

  2. M. Blanco-Rey, M. Alducin, J. I. Juaristi, and P. L. de Andres, Phys. Rev. Lett. 108, 115902 (2012). https://doi.org/10.1103/PhysRevLett.108.115902

    Article  CAS  Google Scholar 

  3. I. P. Chernov, A. S. Rusetsky, D. N. Krasnov, V. V. Larionov, T. I. Sigfusson, and Y. I. Tyurin, J. Eng. Thermophys. 20, 360 (2011). https://doi.org/10.1134/S1810232811040059

    Article  Google Scholar 

  4. V. M. Silkin, I. P. Chernov, Y. M. Koroteev, and E. V. Chulkov, Phys. Rev. B 80, 245114 (2009). https://doi.org/10.1103/PhysRevB.80.245114

    Article  CAS  Google Scholar 

  5. Y. I. Tyurin, N. N. Nikitenkov, I. T. Sigfusson, A. Hashhash, V. Yaomin, and A. S. Dolgov, Vacuum 131, 73 (2016). https://doi.org/10.1016/J.VACUUM.2016.06.001

    Article  CAS  Google Scholar 

  6. E. J. Spahr, L. Wen, M. Stavola, L. A. Boatner, L. C. Feldman, and N. H. Tolk, Phys. Rev. Lett. 104, 205901 (2010). https://doi.org/10.1103/PhysRevLett.104.205901

    Article  CAS  Google Scholar 

  7. A. D. Johonson, K. J. Manynard, S. P. Daley, Q. Y. Yang, and S. T. Ceyer, Phys. Rev. Lett. 67, 927 (1991).

    Article  Google Scholar 

  8. F. Ladstädter, P. F. de Pablos, U. Hohenester, P. Puschnig, C. Ambrosch-Draxl, and P. L. de Andrés, Phys. Rev. B 68, 085107 (2003). https://doi.org/10.1103/PhysRevB.68.085107

    Article  CAS  Google Scholar 

  9. S. Gao, M. Persson, and B. I. Lundqvist, Phys. Rev. B 55, 4825 (1997). https://doi.org/10.1103/PhysRevB.55.4825

    Article  CAS  Google Scholar 

  10. D. Menzel, J. Chem. Phys. 137, 091702 (2012). https://doi.org/10.1063/1.4746799

    Article  CAS  Google Scholar 

  11. Y. I. Tyurin, N. N. Nikitenkov, T. I. Sigfusson, A. Hashhash, Y. Van, and N. D. Tolmacheva, Int. J. Hydrogen Energy 42, 12448 (2017). https://doi.org/10.1016/J.IJHYDENE.2017.03.058

    Article  CAS  Google Scholar 

  12. D. V. Grankin, A. I. Bazhin, and V. P. Grankin, Bull. Russ. Acad. Sci.: Phys. 82, 159 (2018). https://doi.org/10.3103/S1062873818020132

    Article  CAS  Google Scholar 

  13. M. Ikeya, T. Miki, and M. Touge, Nature 292, 613 (1981). https://doi.org/10.1038/292613a

    Article  CAS  Google Scholar 

  14. A. N. Gorban, A. S. Yanovsky, and S. V. Kolomoets, Phys. Low Dimens. Struct. 9, 65 (1998).

    Google Scholar 

  15. T. Mitsui, E. Fomin, D. F. Ogletree, M. Salmeron, A. U. Nilekar, and M. Mavrikakis, Angew. Chem. 119, 5859 (2007). https://doi.org/10.1002/ange.200604498

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Research Tomsk Polytechnic University, 634050, Tomsk, Russia

    Yu. I. Tyurin, V. S. Sypchenko, N. N. Nikitenkov, Zhang Hongzhu & I. P. Chernov

Authors
  1. Yu. I. Tyurin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. S. Sypchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Nikitenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhang Hongzhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. P. Chernov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Sypchenko.

Additional information

Translated by E. Boltukhina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tyurin, Y.I., Sypchenko, V.S., Nikitenkov, N.N. et al. Release of Hydrogen Isotopes from Pd under Radiation, Joule, and Thermal Exposure. J. Surf. Investig. 14, 1264–1269 (2020). https://doi.org/10.1134/S1027451020050389

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451020050389

Keywords:

Search

Navigation