Skip to main content
Log in

Study of the Surface of Polycrystalline Tin Bombarded with Nitrogen Ions

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract—The surface layers of polycrystalline tin are analyzed by Auger electron spectroscopy at temperatures of 293–473 K after being in contact with a nitrogen medium at different pressures and after 100–700-eV nitrogen-ion bombardment. It is established that after nitrogen-ion bombardment, a 389-eV peak appears in the Auger spectra, which is assigned to the nitrogen Auger transition KL2,3L2,3. The dependences of the surface nitrogen concentration on the sample temperature, the bombardment duration, and the energy of nitrogen ions are studied. It is noted that the appearance of nitrogen on the surface of Sn results in a shift of the Sn MNN peaks to lower energies, which indicates the formation of a Sn3N2 film. Argon-ion profiling of the sample surface shows that the thickness of the obtained tin-nitride film is one single layer. From the Auger-analysis data it follows that the film does not decompose up to the melting point of tin.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. S. Seo, G. Y. Zhao, and D. Pavlidis, Electron. Lett. 44, 244 (2008).

    Article  CAS  Google Scholar 

  2. Y. Taniyasu, M. Kasu, and T. Makimoto, Nature 441, 325 (2006).

    Article  CAS  Google Scholar 

  3. S. Nakamura, T. Mukai, and M. Sengh, Appl. Phys. Lett. 64, 1687 (1994).

    Article  CAS  Google Scholar 

  4. M. Yang, S. J. Wang, Y. P. Feng, et al., J. Appl. Phys. 102, 013507 (2007).

    Article  Google Scholar 

  5. T. Maeda, T. Yasuda, M. Nishizawa, et al., J. Appl. Phys. 100, 014101 (2006).

    Article  Google Scholar 

  6. F. Fisher and G. Iliovichi, Ber. Dtsch. Chem. Ges. 41, 3802 (1908).

    Article  Google Scholar 

  7. F. Fisher and G. Iliovichi, Ber. Dtsch. Chem. Ges. 42, 527 (1909).

    Article  Google Scholar 

  8. T. Lindgren, M. Larsson, and S.-E. Lindquist, Proc. 14th Int. Workshop on Quantum Solar Energy Conversion (Rauris, 2002), p. 377.

  9. K. S. Park, Y. J. Park, M. K. Kim, et al., J. Power Sources 103, 67 (2001).

    Article  CAS  Google Scholar 

  10. N. Takahashi, M. Takekawa, T. Takahashi, et al., Solid State Sci. 5, 587 (2003).

    Article  CAS  Google Scholar 

  11. Properties of Elements, Ed. by G. V. Samsonov (Metallurgiya, Moscow, 1976), part 2, p. 364 [in Russian].

  12. B. Wang and M. J. Callahan, Cryst. Growth Des. 6, 1227 (2006).

    Article  CAS  Google Scholar 

  13. N. Takahashi, K. Terada, and T. Nakamura, J. Mater. Sci. Lett. 20, 227 (2001).

    Article  CAS  Google Scholar 

  14. D. M. Hoffman, S. P. Rangarajan, S. D. Athavale, et al., J. Vac. Sci. Technol., A 13, 820 (1995).

    Article  CAS  Google Scholar 

  15. R. Kamei, T. Migita, T. Tanaka, et al., Vacuum 59, 764 (2000).

    Article  CAS  Google Scholar 

  16. M. Zervos and A. Othonos, Nanoscale Res. Lett. 4, 1103 (2009).

    Article  CAS  Google Scholar 

  17. B. V. Nekrasov, Fundamentals of General Chemistry (Khimiya, Moscow, 1973), Vol. 2 [in Russian].

    Google Scholar 

  18. O. G. Ashkhotov, Doctoral Dissertation in Mathematics and Physics (Kabardino-Balkarian State Univ., Nal'chik, 1996).

  19. W. A. Coghlan and R. E. Clausing, At. Data 5, 317 (1973).

    Article  CAS  Google Scholar 

  20. M. P. Seah and W. A. Dench, Surf. Interface Anal. 1, 2 (1979).

    Article  CAS  Google Scholar 

  21. H. Morabito, Surf. Sci. 83, 391 (1979).

    Article  Google Scholar 

  22. H. Tokutaka, K. Nishimori, and H. Hayashi, Surf. Sci. 149, 349 (1985).

    Article  CAS  Google Scholar 

  23. S. Tanuma, C. J. Powell, and D. R. Penn, Surf. Sci. 192, 849 (1987).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. G. Ashkhotov.

Additional information

Translated by L. Chernikova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ashkhotov, O.G., Ashkhotova, I.B. Study of the Surface of Polycrystalline Tin Bombarded with Nitrogen Ions. J. Surf. Investig. 14, 97–100 (2020). https://doi.org/10.1134/S1027451020010036

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451020010036

Keywords:

Navigation