Skip to main content
SpringerLink
Log in

Composition, Morphology and Mechanisms of the Formation of Oxygen-Containing Phases in Surface Heterosegregation Processes

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

By X-ray microprobe analysis, X-ray phase analysis, IR spectroscopy, high resolution scanning electron microscopy, and atomic force microscopy thermally stimulated surface heterosegregation is studied in non-oxygen and oxygen-containing single crystals with the participation of oxygen. It is concluded that sodium chlorite NaClO2 and sodium hydrocarbonate NaHCO3 are formed on the surface of sodium chloride NaCl, gallium oxide Ga2O3 on the surface of gallium arsenide GaAs, titanium dioxide TiO2 and lead oxide PbO on the surface of lead titanate PbTiO3, the complex oxide Bi2Ti4O11 and bismuth oxide Bi2O3 on the surface of bismuth titanate Bi4Ti3O12, the complex oxides Bi2Fe4O9, Bi26– xFexO39 and bismuth oxide Bi2O3 on the surface of bismuth ferrite BiFeO3, the complex oxide Pb3GeO5 and lead oxide PbO on the surface of lead germanate Pb5Ge3O11. The mechanisms of the formation of surface oxygen-containing phases including the self-diffusion of matrix crystal atoms to the surface, the migration of segregated atoms on the surface, the evaporation and absorption of molecules of water, carbon oxides, hydrocarbons, oxygen, as well as the surface reactions of segregated atoms with the participation of both lattice oxygen and oxygen of the external environment are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Yu. Ya. Tomashpolsky, V. M. Matyuk, and N. V. Sadovskaya, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech., 9 (3), 581 (2015).

    Article  Google Scholar 

  2. Yu. Ya. Tomashpolsku, Surface Autosegregation in Chemical Compounds (Nauchnyi mir, Moscow, 2013) [in Russian].

  3. Yu. Ya. Tomashpolsky, N. V. Sadovskaya, and G. A. Grigorieva, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech., 7 (5), 900 (2013).

    Article  Google Scholar 

  4. Yu. Ya. Tomashpolskii, Russ. J. Gen. Chem. 72 (4), 632 (2002).

    Article  Google Scholar 

  5. Yu. Ya. Tomashpol’skii, I. Ya. Kolotyrkin, and O. V. Petrova, Poverkhnost: Fiz., Khim., Mekh., No. 8, 103 (1985).

  6. E. N. Lubnin, Candidate’s Dissertation in Physics and Mathematics (Moscow, 1983).

  7. Yu. Ya. Tomashpolsky and N. V. Sadovskaya, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech., 4 (5), 811 (2010).

    Article  Google Scholar 

  8. Yu. F. Kargin, V. I. Burkov, A. A. Mar’in, et al., Bi 12 M x O 20 ± δ Crystals with a Sillenite Structure: Synthesis, Structure, and Properties (Nauka, Moscow, 2004) [in Russian].

    Google Scholar 

  9. Yu. F. Kargin, Doctoral Dissertation in Chemistry (Moscow, 1998).

  10. Yu. Ya. Tomashpolsky, I. Ya. Kolotyrkin, and E. N. Lubnin, J. Microsc. Spectrosc. Electron. 10, 521 (1985).

    Google Scholar 

  11. I. Ya. Kolotyrkin, O. V. Petrova, and Yu. Ya. Tomashpolsky, Neorg. Mater. 21 (11), 1968 (1985).

    Google Scholar 

  12. P. A. Shcheglov, S. A. Men’shikh, S. G. Prutchenko, et al., Neorg. Mater. 6 (1), 77 (2000).

    Google Scholar 

  13. K. Okazaki, Ceramic Engineering for Dielectrics (Gakkensha, Tokyo, 1964; Energiya, Moscow, 1976).

  14. V. V. Prisedskii, V. P. Komarov, G. F. Pan’ko, et al., Dokl. Akad. Nauk SSSR 247 (3), 620 (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of the Karpov Institute of Physical Chemistry, 105064, Moscow, Russia

    Yu. Ya. Tomashpolsky, V. M. Matyuk, N. V. Sadovskaya, S. G. Lakeev & N. V. Kozlova

Authors
  1. Yu. Ya. Tomashpolsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Matyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Sadovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. G. Lakeev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. V. Kozlova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yu. Ya. Tomashpolsky or V. M. Matyuk.

Additional information

Translated by L. Mosina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Tomashpolsky, Y.Y., Matyuk, V.M., Sadovskaya, N.V. et al. Composition, Morphology and Mechanisms of the Formation of Oxygen-Containing Phases in Surface Heterosegregation Processes. J. Surf. Investig. 13, 442–450 (2019). https://doi.org/10.1134/S1027451019030200

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451019030200

Keywords:

Search

Navigation