Skip to main content
SpringerLink
Log in

Mössbauer study of products from the arc synthesis of Fe-carbon nanoclusters

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

This paper presents the results of research into the phase and magnetic state of products of the arc synthesis of Fe-carbon nanoclusters by Mössbauer spectroscopy. These nanoclusters are prepared by the burning of iron-graphite electrodes and carbon-condensate extraction in organic solvents of varying polarity. The local inhomogeneity of the distribution of iron atoms is revealed in the studied samples. It is found that iron atoms are distributed between four iron-containing phases: α-Fe, γ-Fe, FeC n and iron carbide FeC2 at different ratios with an accuracy to the resonant absorption factor f. It is shown that the singlet line with a negative chemical shift observed in the Mössbauer spectra of the samples corresponds to the γ-Fe phase and not to iron metallofullerene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. Sano, H. Wang, I. M. Alexandrou, et al., J. Appl. Phys. 92, 2783 (2002).

    Article  Google Scholar 

  2. Y. Yang, L. Li, G. Chen, and E. Liu, J. Magn. Magn. Mater. 320 (15), 2030 (2008).

    Article  Google Scholar 

  3. N. Y. Hernandez-Pedro, E. Rangel-Lopez, R. Magana-Maldonado, et al., Bio Med Res. Int. 2013, Art. ID 351031 (2013).

    Google Scholar 

  4. K. Gallagher, F. Johnson, E. M. Kirkpatrik, et al., IEEE Trans. Magn. 32 (5), 4842 (1996).

    Article  Google Scholar 

  5. Wen Liu and Qing Sen Meng, J. Phys.: Conf. Ser. 188, 012035 (2009).

    Google Scholar 

  6. A. A. Hosseini, M. Allahyari, and S. Daftari Besheli, Int. J. Sci., Environ. Technol. 1 (3), 217 (2012).

    Google Scholar 

  7. A. V. Eletskii, Usp. Fiz. Nauk 170 (2), 113 (2000).

    Article  Google Scholar 

  8. H. Shinohara, Rep. Prog. Phys. 63, 843 (2000).

    Article  Google Scholar 

  9. Xing Lu, Lai Feng, Takeshi Akasaka, and Shigeru Nagase, Chem. Soc. Rev. 41, 7723 (2012).

    Article  Google Scholar 

  10. T. Pradeep, G. U. Kulkarrii, K. R. Kannan, et al., J. Am. Chem. Soc. 114, 2272 (1992).

    Article  Google Scholar 

  11. G. L. Zhang, E. H. du Marchie van Voorthuysen, K. Szymanski, et al., Il Nuovo Cimento D 18 (2), 281 (1996).

    Article  Google Scholar 

  12. V. G. Semenov, L. N. Moskvin, and A. A. Efimov, Russ. Chem. Rev. 75, 317 (2006).

    Article  Google Scholar 

  13. Y. Blyakhman, N. I. Polushkin, A. D. Akhsakhalyan, S. A. Gusev, N. N. Salashchenko, and V. G. Semenov, Phys. Rev. B 52, 10303 (1995).

    Article  Google Scholar 

  14. V. S. Kozlov, M. V. Suyasova, and V. T. Lebedev, Russ. J. Appl. Chem. 87 (2), 121 (2014).

    Article  Google Scholar 

  15. Yu. S. Grushko, V. S. Kozlov, T. O. Artamonova, and M. A. Khodorkovskii, Fullerenes, Nanotubes, Carbon Nanostruct. 20 (4–7), 351 (2012).

    Article  Google Scholar 

  16. V. P. Sedov, S. G. Kolesnik, V. V. Kukorenko, et al., Report of Petersburg Nuclear Physics Institute named by B. P. Konstantinov No. 2798 (Gatchina, 2009).

    Google Scholar 

  17. V. P. Sedov, A. A. Szhogina, V. T. Lebedev, Yu. P. Chernenkov, V. L. Aksenov, and M. V. Koval’chuk, Preprint 2963 (Petersburg Nuclear Physics Institute named by B. P. Konstantinov, Gatchina, 2014).

    Google Scholar 

  18. A. E. Tikhonova and V. S. Kozlov, Phys. Solid State 56 (1), 17 (2014).

    Article  Google Scholar 

  19. A. L. Prudnikava, J. A. Fedotova, J. V. Kasiuk, et al., Semicond. Phys., Quantum Electron. Optoelectron. 13 (2), 125 (2010).

    Google Scholar 

  20. I. Morjan, F. Dumitrache, R. Alexandrescu, et al., Adv. Powder Technol. 23, 88 (2012).

    Article  Google Scholar 

  21. N. Saegusa and M. Kusunoki, Jpn. J. Appl. Phys., Part 1 29 (5), 876 (1990).

    Article  Google Scholar 

  22. M. Kusunoki and T. Ichihashi, Jpn. J. Appl. Phys. 25 (3), L 219 (1986).

    Article  Google Scholar 

  23. B. Wei, M. Shima, R. Pati, et al., Small 2 (6), 804 (2006).

    Article  Google Scholar 

  24. D. Begin, E. Alain, G. Furdin, et al., Carbon 34 (3), 331 (1996).

    Article  Google Scholar 

  25. V. A. Tsurin, A. Ye. Yermakov, M. A. Uimin, et al., Phys. Solid State 56 (2), 287 (2014).

    Article  Google Scholar 

  26. S. Bandow, H. Shinohara, Y. Saito, et al., J. Phys. Chem. 97, 6101 (1993).

    Article  Google Scholar 

  27. J. Jiao, S. Seraphin, X. Xikun Wang, and J. C. P. Withers, J. Appl. Phys. 80 (1), 103 (1996).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Petersburg Nuclear Physics Institute, National Research Center “Kurchatov Institute”, Gatchina, Leningrad oblast, 188300, Russia

    V. S. Kozlov

  2. Institute of Chemistry, St. Petersburg State University, St. Petersburg, 199034, Russia

    V. G. Semenov & V. V. Panchuk

Authors
  1. V. S. Kozlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Semenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Panchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Kozlov.

Additional information

Original Russian Text © V.S. Kozlov, V.G. Semenov, V.V. Panchuk, 2017, published in Poverkhnost’, 2017, No. 9, pp. 17–21.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kozlov, V.S., Semenov, V.G. & Panchuk, V.V. Mössbauer study of products from the arc synthesis of Fe-carbon nanoclusters. J. Surf. Investig. 11, 908–911 (2017). https://doi.org/10.1134/S1027451017050093

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451017050093

Keywords

Search

Navigation