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Electrochemical control of association and deposition of tetraviologen calix[4]resorcin

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Abstract

The association and deposition of tetraviologen calix[4]resorcin MVCA-C 8+5 can be controlled using the electrochemical reduction-reoxidation cycle of viologen units. The monomeric MVCA-C 8+5 was converted into the highly molecular (MVCA-C 4+·5 ) n associate (π-polymer) by reducing it to the MVCA-C 4+·5 tetra(radical cation) and completely returns to the starting monomeric state by reverse oxidation. The reduction to the neutral state MVCA-C 05 allowed calixresorcin to pass from solution to precipitate and the reverse oxidation led to its returning in solution.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Kazan, Russia

    G. R. Nasybullina, V. V. Yanilkin, A. Yu. Ziganshina, V. I. Morozov, E. D. Sultanova, D. E. Korshin, V. A. Milyukov, R. P. Shekurov & A. I. Konovalov

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  1. G. R. Nasybullina
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  2. V. V. Yanilkin
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  3. A. Yu. Ziganshina
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  9. A. I. Konovalov
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Correspondence to V. V. Yanilkin.

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Original Russian Text © G.R. Nasybullina, V.V. Yanilkin, A.Yu. Ziganshina, V.I. Morozov, E.D. Sultanova, D.E. Korshin, V.A. Milyukov, R.P. Shekurov, A.I. Konovalov, 2014, published in Elektrokhimiya, 2014, Vol. 50, No. 8, pp. 841–857.

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Nasybullina, G.R., Yanilkin, V.V., Ziganshina, A.Y. et al. Electrochemical control of association and deposition of tetraviologen calix[4]resorcin. Russ J Electrochem 50, 756–772 (2014). https://doi.org/10.1134/S1023193514080096

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