Abstract—
The effect of pH, ionic strength, and ambient temperature on the behavior of hydrogels of network paired polymers synthesized by reactive blending of poly-N-vinylpyrrolidone and poly-N-vinylcaprolactam with poly-1-vinyl-3-amino-1,2,4-triazole is demonstrated. It is found that hydrophobic interactions of the fragments of the polymer chains have a major role in the changes of the sorption properties of the hydrogels in response to variation in the solvent properties.
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REFERENCES
A. O. Baranov, A. V. Kotova, A. N. Zelenetskii, and E. V. Prut, Russ. Chem. Rev. 66, 877 (1997).
A. A. Askadskii, Russ. Chem. Rev. 68, 317 (1999).
N. A. Plate, A. D. Litmanovich, and Ya. V. Kudryavtsev, Macromolecular Reactions in Polymer Melts and Blends (Nauka, Moscow, 2008) [in Russian].
V. N. Kizhnyaev, F. A. Pokatilov, R. G. Zhitov, A. G. Proidakov, and E. A. Krakhotkina, Polym. Sci., Ser. B 57, 504 (2015).
G. Erdodi and J. Kennedy, Progr. Polym. Sci. 31, 1 (2006).
J. Tobis, Y. Thomann, and J. C. Tiller, Polymer 51, 35 (2010).
M. D. Rikkou, E. Loizou, C. S. Patrickios, and L. Porcar, Eur. Polym. J. 46, 441 (2010).
V. N. Kizhnyaev, F. A. Pokatilov, and E. V. Akamova, Polym. Sci., Ser. B 62, 483 (2020).
O. E. Philippova, Polym. Sci., Ser. C 42, 208 (2000).
F. Horkay, I. Tasaki, and P. Basser, Biomacromolecules 1, 84 (2000).
V. O. Aseyev, H. Tenhu, and F. M.Winnik, Adv. Polym. Sci. 196, 1 (2006).
E. Yu. Kramarenko, O. E. Philippova, and A. R. Khokhlov, Polym. Sci., Ser. C 48, 1 (2006).
S. Chaterji, I. K. Kwon, and K. Park, Prog. Polym. Sci. 32, 1083 (2007).
I. Galaev and B. Mattiasson, Smart Polymers: Applications in Biotechnology and Biomedicine (CRC, New York, 2007).
M. R. Aguilar, C. Elvira, A. Gallardo, B. Vazquez, and J. S. Roman, Topics Tissue Eng. 3, 1 (2007).
L. Z. Rogovina, V. G. Vasil’ev, and E. E. Braudo, Polym. Sci., Ser. C 50, 85 (2008).
Y. E. Kirsh, Water Soluble Poly-N-Vinylamides (Wiley-VCH, Weinheim, 1998).
S. Chaterji, I. K. Kwon, and K. Park, Prog. Polym. Sci. 32, 1083 (2007).
V. A. Kruglova, V. V. Annenkov, L. I. Vereshchagin, V. V. Pavlenko, V. B. Kazimirovskaya, L. G. Moskvitina, N. M. Boiko, L. A. Mansurova, A. B. Skornyakova, and S. V. Kalmykov, Pharm. Chem. J. 21, 87 (1987).
E. E. Makhaeva, Le Thi Minh Thanh, S. G. Starodoubtsev, and A. R. Khokhlov, Macromol. Chem. Phys. 197, 1973 (1996).
I. V. Bakeeva, I. I. Pashkin, Yu. E. Kirsh, V. A. Tverskoi, and V. P. Zubov, Polym. Sci., Ser. A 42, 673 (2000).
V. N. Kizhnyaev, F. A. Pokatilov, R. G. Zhitov, A. G. Proidakov, T. V. Golobokova, and L. I. Vereshchagin, Polym. Sci., Ser. B 57, 497 (2015).
T. V. Golobokova, L. I. Vereshchagin, G. V. Ratovskii, A. G. Proidakov, and V. N. Kizhnyaev, Russ. J. Org. Chem. 52, 1039 (2016).
K. Schofield, M. R. Grimmett, and B. R. T. Keene, Heteroaromatic Nitrogen Compounds: the Azoles (Cambridge Univ. Press, Cambridge, 1976).
A. Pich, A. Tessier, V. Boyko, Y. Lu, and H.-J. P. Adler, Macromolecules 39, 7701 (2006).
Yu. E. Kirsh, N. A. Yanul, K. K. Kalninsh, and V. G. Maslov, J. Mol. Liq. 82, 117 (1999).
Yu. E. Kirsh, N. A. Yanul, Yu. M. Popkov, and S. F. Timashev, Russ. J. Phys. Chem. 73, 253 (1999).
Yu. E. Kirsh, Yu. M. Popkov, and S. F. Timashev, Russ. J. Phys. Chem. 73, 415 (1999).
A. A. A. De Queiroz, A. Gallardo, and J. S. Roman, Biomaterials 21, 1631 (2000).
Y. Maeda, T. Nakamura, and I. Ikeda, Macromolecules 35, 217 (2002).
B. I. Nakhmanovich, N. I. Pakuro, E. I. Akhmet’eva, G. I. Litvinenko, and A. A. Arest-Yakubovich, Polym. Sci., Ser. B 49, 136 (2007).
N. I. Pakuro, B. I. Nakhmanovich, D. V. Pergushov, and F. Kh. Chibirova, Polym. Sci., Ser. B 53, 6 (2011).
Ch. E. Sing, J. W. Zwanikken, and M. O. Cruz, Macromolecules 46, 5053 (2013).
E. V. Vorobieva, Dokl. Natl. Acad. Sci. Belarus 64, 293 (2020).
Yu. E. Kirsh, Yu. M. Popkov, and S. F. Timashev, Russ. J. Phys. Chem. 73, 486 (1999).
Funding
This study was supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the basic part of the state assignment in the field of scientific activity (project no. 075-03-2020-176/3; project code in Parus 8: FZZE-2020-0022).
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Kizhnyaev, V.N., Pokatilov, F.A., Akamova, E.V. et al. Behavior of Hydrogels of Paired Polymers Containing Lactam and Triazole Rings in Aquatic Media. Polym. Sci. Ser. A 64, 108–114 (2022). https://doi.org/10.1134/S0965545X22010059
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DOI: https://doi.org/10.1134/S0965545X22010059