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Hydrodynamic and Conformational Properties of Nitrile-Butadiene Rubbers in Ester Solutions

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Abstract

Dilute solutions of nitrile-butadiene rubbers in toluene, methyl acetate, ethyl acetate, and butyl acetate are studied by viscometry. The rubbers are obtained using paraffinate emulsifiers and contain the same amounts of acrylonitrile and different molecular weights. The effect of rubber molecular weight and solvent nature on the intrinsic viscosity [η], viscometric Huggins k' and Kraemer k'' constants, the hydrodynamic volume of the macromolecule, and the root-mean-square end-to-end distance is estimated. Using these data, laws controlling changes in the thermodynamic quality of solvents with respect to nitrile-butadiene rubbers, which are confirmed by static light scattering measurements, are revealed.

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Authors and Affiliations

  1. Institute of Fine Chemical Technologies, Russian University of Technology (MIREA), 119454, Moscow, Russia

    Yu. A. Naumova, L. A. Kolesova, L. R. Lyusova & S. V. Kotova

  2. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    S. G. Karpova & A. A. Popov

Authors
  1. Yu. A. Naumova
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  2. L. A. Kolesova
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  3. S. G. Karpova
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  4. L. R. Lyusova
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  5. S. V. Kotova
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  6. A. A. Popov
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Corresponding author

Correspondence to S. G. Karpova.

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Naumova, Y.A., Kolesova, L.A., Karpova, S.G. et al. Hydrodynamic and Conformational Properties of Nitrile-Butadiene Rubbers in Ester Solutions. Polym. Sci. Ser. A 62, 155–161 (2020). https://doi.org/10.1134/S0965545X20020017

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  • DOI: https://doi.org/10.1134/S0965545X20020017

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