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Omniphobic Coatings Based on Vinyl Pivalate–Perfluorohexylethyl Methacrylate Copolymers Formed in Supercritical Carbon Dioxide

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Abstract

A new approach to the formation of omniphobic coatings with a reduced content of fluorocarbon radicals has been proposed. The synthesis of vinyl pivalate–perfluorohexylethyl methacrylate copolymers has been first performed via radical polymerization with the use of supercritical CO2 as a solvent. The solubility of copolymers and also the hydrophobic and oleophobic properties of related coatings deposited from solutions in supercritical CO2 on fabrics have been studied. The coatings are characterized by a uniform morphology and an improved adhesion to fibers, which is of great practical interest.

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation (grant no. 17-13-01359).

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Authors and Affiliations

  1. Faculty of Physics, Moscow State University, 119991, Moscow, Russia

    P. S. Kazaryan, V. V. Zefirov, I. V. El’manovich & M. S. Kondratenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    A. I. Stakhanov & A. R. Khokhlov

Authors
  1. P. S. Kazaryan
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  2. V. V. Zefirov
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  3. I. V. El’manovich
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  4. A. I. Stakhanov
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  5. M. S. Kondratenko
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  6. A. R. Khokhlov
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Corresponding author

Correspondence to P. S. Kazaryan.

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Translated by L. Tkachenko

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Kazaryan, P.S., Zefirov, V.V., El’manovich, I.V. et al. Omniphobic Coatings Based on Vinyl Pivalate–Perfluorohexylethyl Methacrylate Copolymers Formed in Supercritical Carbon Dioxide. Polym. Sci. Ser. A 61, 157–161 (2019). https://doi.org/10.1134/S0965545X19020056

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  • DOI: https://doi.org/10.1134/S0965545X19020056

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