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Behavior of Organosilicon Surfactants in Langmuir Films on the Surface of Water

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Abstract

The behavior of organosilicon surfactants of different structure in model systems—Langmuir films—at the water/air interface is studied. It is shown that, under the compression of Langmuir films, the conformational states of surfactants of different structure are different. The obtained data make it possible to explain a high stability of polymer suspensions synthesized in the presence of organosilicon surfactants.

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REFERENCES

  1. I. A. Gritskova, D. I. Shragin, S. M. Levachev, A. A. Ezho-va, E. V. Milushkova, V. M. Kopylov, S. A. Gusev, N. I. Prokopov, and N. A. Lobanova, Tonkie Khim. Tekhnol. 11 (2), 5 (2016).

    CAS  Google Scholar 

  2. I. A. Gritskova, Izv. Akad. Nauk, Ser. Khim., No. 1, 132 (2019).

  3. I. A. Gritskova, Dokl. Akad. Nauk 334, 57 (1994).

    CAS  Google Scholar 

  4. A. A. Poteryaev, Vestn. Kazan. Tekhnol. Univ. 19, 29 (2016).

    CAS  Google Scholar 

  5. D. I. Shragin, Silicon 7, 217 (2015).

    Article  CAS  Google Scholar 

  6. N. I. Prokopov, Russ. Chem. Rev. 65, 167 (1996).

    Article  Google Scholar 

  7. I. A. Gritskova, V. M. Kopylov, G. A. Simakova, S. A. Gusev, I. Yu. Markuze, and E. N. Levshenko, Polym. Sci., Ser. B 52, 542 (2010).

    Article  Google Scholar 

  8. I. A. Gritskova, D. B. Adikanova, V. S. Papkov, N. I. Prokopov, D. I. Shragin, S. A. Gusev, S. M. Levachev, E.V. Milushkova, A. A. Ezhova, and A. D. Lukashevich, Polym. Sci., Ser. B 58, 163 (2016).

    Article  CAS  Google Scholar 

  9. N. M. Solodukhina, Appl. Biochem. Microbiol. 48, 740 (2012).

    Article  CAS  Google Scholar 

  10. S. C. Mehta, P. Somasundaran, C. Maldarelli, and R. Kulkarni, Langmuir 22, 9566 (2006).

    Article  CAS  PubMed  Google Scholar 

  11. V. V. Arslanov, Russ. Chem. Rev. 63, 1 (1994).

    Article  Google Scholar 

  12. C. Kim, M. C. Gurau, P. S. Cremer, and Y. Hyuk, Langmuir 24, 10155 (2008).

    Article  CAS  PubMed  Google Scholar 

  13. M. I. Bessonov and V. E. Smirnova, Vysokomol. Soedin. 13, 352 (1971).

    CAS  Google Scholar 

  14. G. Von Damaschun, Kolloid Z. Z. Polym. 180, 65 (1962).

    Article  Google Scholar 

  15. F. C. Schilling, M. A. Gomez, and A. E. Tonelli, Macromolecules 24, 6552 (1991).

    Article  CAS  Google Scholar 

  16. T. J. Lenk, D. H. T. Lee, and J. T. Koberstein, Langmuir 10, 1857 (1994).

    Article  CAS  Google Scholar 

  17. I. A. Gritskova, Yu. N. Malakhova, V. M. Kopylov, D. I. Shragin, E. V. Milushkova, A. I. Buzin, A. A. Ezhova, A. D. Lukashevich, S. M. Levachev, and N. I. Pro-kopov, Polym. Sci., Ser. B 57, 396 (2015).

    Article  CAS  Google Scholar 

  18. A. R. Esker and Y. Hyuk, in Silicone Surface Science, Advances in Silicon Science 4, Ed. by M. J. Owen and P. R. Dvornic (Springer, Dordrecht, 2012), Chap. 7, p. 195.

    Google Scholar 

  19. Yu. N. Malakhova, A. I. Buzin, and S. N. Chvalun, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 12, 339 (2018).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This work was supported by the Russian Foundation for Basic Research, project nos. mol_a_16-33-60194 and mol_a 18-33-01193\18.

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Correspondence to A. A. Ezhova.

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Translated by T. Soboleva

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Ezhova, A.A., Gritskova, I.A., Chalykh, A.E. et al. Behavior of Organosilicon Surfactants in Langmuir Films on the Surface of Water. Polym. Sci. Ser. A 61, 149–156 (2019). https://doi.org/10.1134/S0965545X19020044

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  • DOI: https://doi.org/10.1134/S0965545X19020044

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