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Effect of Zinc–Porphyrin Complex on the Structure and Properties of Poly(3-hydroxybutyrate) Ultrathin Fibers

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Abstract

The effect of small amounts of the zinc–tetraphenylporpyrin complex (1–5%) on the structure and properties of ultrathin fibers based on poly(3-hydroxybutyrate) is investigated using differential scanning calorimetry, X-ray diffraction, spin-probe EPR spectroscopy, scanning electron microscopy, and IR spectroscopy. It is shown that, upon introduction of the porphyrin complex in the fibers, the fraction of paracrystalline structures decreases and molecular mobility in the amorphous regions of the polymer slows down, while the degree of crystallinity remains unchanged. Annealing of the fibers at 140°C leads to an increase in the content of paracrystalline structures and in the degree of crystallinity of the fibers.

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Authors and Affiliations

  1. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    S. G. Karpova, A. A. Ol’khov, A. V. Krivandin & O. V. Shatalova

  2. Plekhanov Russian University of Economics, 117997, Moscow, Russia

    A. A. Ol’khov & A. A. Popov

  3. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 119991, Moscow, Russia

    A. A. Ol’khov, A. V. Lobanov & A. L. Iordanskii

Authors
  1. S. G. Karpova
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  2. A. A. Ol’khov
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  3. A. V. Krivandin
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  4. O. V. Shatalova
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  5. A. V. Lobanov
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  6. A. A. Popov
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  7. A. L. Iordanskii
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Correspondence to S. G. Karpova.

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Translated by T. Soboleva

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Karpova, S.G., Ol’khov, A.A., Krivandin, A.V. et al. Effect of Zinc–Porphyrin Complex on the Structure and Properties of Poly(3-hydroxybutyrate) Ultrathin Fibers. Polym. Sci. Ser. A 61, 70–84 (2019). https://doi.org/10.1134/S0965545X19010140

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  • DOI: https://doi.org/10.1134/S0965545X19010140

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