Abstract
The effect of zone annealing on a microstructure from horizontal and vertical cylinders in the microphase-separated films of polystyrene–polybutadiene–polystyrene triblock copolymer and polystyrene–poly(4-vinylpyridine) diblock copolymer is studied. It is shown that processing of the films of different thicknesses at various maximum thermal front temperatures which do not exceed the temperature of orderdisorder transition does not lead to a noticeable increase in their degree of ordering. On the contrary, once the transition temperature is approached, the interfacial area between domains formed by different types of blocks is increased and the order in their arrangement disappears, with the thermal stability of the structure falling with an increase in film thickness. Thus, the substantial microstructure ordering during the cold zone annealing of the polystyrene–poly(methyl methacrylate) diblock copolymer described in the literature has not yet been reproduced for other systems. The maximum rate of gradient zone motion at which this effect is to be expected is estimated.
Similar content being viewed by others
References
C. M. Bates and F. S. Bates, Macromolecules 50 (3), 3 (2017).
V. Abetz and P. F. W. Simon, in Block Copolymers, Ed. by V. Abetz (Springer, Berlin; Heidelberg, 2005), Vol. 189.
A. J. Meuler, M. A. Hillmyer, and F. S. Bates, Macromolecules 42 (19), 7221 (2009).
F. S. Bates, M. A. Hillmyer, T. P. Lodge, C. M. Bates, K. T. Delaney, and G. H. Fredrickson, Science 336 (6080), 434 (2012).
I. W. Hamley, Prog. Polym. Sci. 34 (11), 1161 (2009).
H.-C. Kim, S.-M. Park, and W. D. Hinsberg, Chem. Rev. 110 (1), 146 (2010).
P. D. Topham, A. J. Parnell, and R. C. Hiorns, J. Polym. Sci., Polym. Phys. Ed. 49 (16), 1131 (2013).
H. Zhang and P. K. Shen, Chem. Rev. 112 (5), 2780 (2012).
S. O. Kim, H. H. Solak, M. P. Stoykovich, N. J. Ferrier, J. J. de Pablo, and P. F. Nealey, Nature 424 (6947), 411 (2003).
R. Ruiz, H. Kang, F. A. Detcheverry, E. Dobisz, D. S. Kercher, T. R. Albrecht, J. J. de Pablo, and P. F. Nealey, Science 321 (5891), 936 (2008).
J. Y. Cheng, C. T. Rettner, D. P. Sanders, H. C. Kim, and W. D. Hinsberg, Adv. Mater. 20 (16), 3155 (2008).
R. A. Segalman, H. Yokoyama, and E. J. Kramer, Adv. Mater. 13 (15), 1152 (2001).
S. Park, D. H. Lee, J. Xu, B. Kim, S. W. Hong, U. Jeong, T. Xu, and T. P. Russell, Science 323 (5917), 1030 (2009).
J. K. W. Yang, Y. S. Jung, J.-B. Chang, R. A. Mickiewicz, A. Alexander-Katz, C. A. Ross, and K. K. Berggren, Nat. Nanotechnol. 5 (4), 256 (2010).
I. Bita, J. K. W. Yang, Y. J. Jung, C. A. Ross, E. L. Thomas, and K. K. Berggren, Science 321 (5891), 939 (2008).
R. Register, Nat. Nanotechnol. 8 (9), 618 (2013).
M. S. Onses, C. Song, L. Williamson, E. Sutanto, P. M. Ferreira, A. G. Alleyne, P. F. Nealey, H. Ahn, and J. A. Rogers, Nat. Nanotechnol. 8 (9), 667 (2013).
J. A. Luo and T. H. Epps, Macromolecules 46 (19), 7567 (2013).
S. B. Darling, Prog. Polym. Sci. 32 (10), 1152 (2007).
C. Sinturel, M. Vayer, M. Morris, and M. A. Hillmyer, Macromolecules 46 (14), 5399 (2013).
C. Liedel, K. A. Schindler, M. J. Pavan, C. Lewin, C. W. Pester, M. Ruppel, V. S. Urban, R. Shenhar, and A. Boeker, Small 9 (19), 3276 (2013).
C. M. Bates, M. J. Maher, D. W. Janes, C. J. Ellison, and C. G. Wilson, Macromolecules 47 (1), 2 (2014).
Y. Gao, N. Guo, B. Gauvreau, M. Rajabian, O. Skorobogata, E. Pone, O. Zabeida, L. Martinu, C. Dubois, and M. Skorobogatiy, J. Mater. Res. 21 (9), 2246 (2006).
K. W. Gotrik and C. A. Ross, Nano Lett. 13 (11), 5117 (2013).
H. Hu, M. Gopinadhan, and C. C. Osuji, Soft Matter 10 (22), 3867 (2014).
D. Yong, H. M. Jin, S. O. Kim, and J. U. Kim, Macromolecules 51 (4), 1418 (2018).
K. Stoeffler, C. Dubois, A. Ajji, N. Guo, F. Boismenu, and M. Skorobogatiy, Polym. Eng. Sci. 50 (6), 1122 (2010).
S. S. Lamarre, C. Lemay, C. Labresque, and A. M. Ritcey, Langmuir 29 (34), 10891 (2013).
A. Halevi, S. Halivni, M. Oded, A. H. E. Mueller, U. Banin, and R. Shenhar, Macromolecules 47 (9), 3022 (2014).
B. C. Berry, A. W. Bosse, J. F. Douglas, R. L. Jones, and A. Karim, Nano Lett. 7 (9), 2789 (2007).
K. G. Yager, N. J. Fredin, X. Zhang, B. C. Berry, A. Karim, and R. L. Jones, Soft Matter 6 (1), 92 (2010).
G. Singh, K. G. Yager, D.-M. Smilgies, M. M. Kulkarni, D. G. Bucknall, and A. Karim, Macromolecules 45 (17), 7107 (2012).
C. Ye, Y. Sun, A. Karim, and B. D. Vogt, Macromolecules 48 (20), 7567 (2015).
S. Samant, J. Strzalka, K. G. Yager, K. Kisslinger, D. Grolman, M. Basutkar, N. Salunke, G. Singh, B. Berry, and A. Karim, Macromolecules 49 (22), 8633 (2016).
G. Singh, K. G. Yager, B. Berry, H.-C. Kim, and A. Karim, ACS Nano 6 (11), 10335 (2012).
G. Singh, S. Batra, R. Zhang, H. Yuan, K. G. Yager, M. Cakmak, B. Berry, and A. Karim, ACS Nano 7 (6), 5291 (2013).
V. V. Ginzburg, J. D. Weinhold, and P. Trefonas, J. Polym. Sci., Polym. Phys. Ed. 53 (2), 90 (2015).
H. Takahashi, N. Laachi, K. T. Delaney, S.-M. Hur, C. J. Weinheimer, D. Shykind, and G. H. Fredrickson, Macromolecules 45 (15), 6253 (2012).
N. Laachi, K. T. Delaney, B. Kim, S.-M. Hur, R. Bristol, D. Shykind, C. J. Weinheimer, and G. H. Fredrickson, J. Polym. Sci.,Polym. Phys. Ed. 53 (2), 142 (2015).
A. A. Rudov, E. S. Patyukova, I. V. Neratova, P. G. Khalatur, D. Posselt, C. M. Papadakis, and I. I. Potemkin, Macromolecules 46 (14), 5786 (2013).
S.-M. Hur, G. S. Khaira, A. Ramirez-Hernandez, M. Moeller, P. F. Nealey, and J. J. de Pablo, ACS Macro Lett 4 (1), 11 (2015).
N. Dixit, A. Pape, L. Rong, E. Joseph, and S. M. Martin, Macromolecules 48 (4), 1144 (2015).
A. Singh, R. Krishnan, and S. Puri, Eur. Polym. Lett. 109 (2), 26006 (2015).
P. W. Majewski and K. G. Yager, J. Phys.: Condens. Matter 28 (40) (2016).
Zh. Cong, L. Zhang, L. Wang, and J. Lin, J. Chem. Phys. 144 (11), 114901 (2016).
J. D. Hill and P. C. Millett, Sci. Rep. 7, Article No. 5250 (2017).
X. Wan, T. Gao, L. Zhang, and J. Lin, Phys. Chem. Chem. Phys. 19 (9), 6707 (2017).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.S. Merekalov, Y.I. Derikov, A.A. Ezhov, E.N. Govorun, Y.V. Kudryavtsev, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2018, Vol. 60, No. 6, pp. 441–451.
Rights and permissions
About this article
Cite this article
Merekalov, A.S., Derikov, Y.I., Ezhov, A.A. et al. Evolution of Microstructure in Block Copolymer Thin Films during Zone Annealing. Polym. Sci. Ser. A 60, 723–733 (2018). https://doi.org/10.1134/S0965545X18060068
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X18060068