Abstract
Swelling chitosan–polyaniline composite systems demonstrating a pronounced electromechanical response are obtained. The formation of a crosslinked structure in chitosan allows one to enhance elasticstrain properties of composites, but this is accompanied by a decrease in the bending angle under an electric field. Polyaniline as an electroactive component improves the composite system capability of deformation induced by an electric field. The factors contributing to the deformation value are investigated.
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References
Electromechanically Active Polymers, Ed. by F. Carpi (Springer Int. Publ., Cham, Switzerland, 2016).
Y. Osada and J. Gong, Prog. Polym. Sci. 18, 187 (1993).
T. Shiga, Adv. Polym. Sci. 134, 131 (1997).
I. Yu. Dmitriev, V. P. Ivanov, N. V. Bobrova, Z. F. Zoolshoev, I. S. Kuryndin, and G. K. Elyashevich, Russ. J. Appl. Chem. 89 (11), 1838 (2016).
S. Sun and A. F. T. Mak, J. Polym. Sci., Polym. Phys. Ed. 39, 236 (2001).
S. J. Kim, M. S. Kim, S. R. Shin, I. Y. Kim, S. I. Kim, S. H. Lee, T. S. Lee, and G. M. Spinks, Smart Mater. Struct. 14, 889 (2005).
Q. He, M. Yu, Xu. Yang, K. J. Kim, and Zh. Dai, Smart Mater. Struct. 24, 065026 (2015).
E. Altinkaya, Y. Seki, Ö. C. Yilmaz, L. Çetin, O. Ozdemir, I. Sen, K. Sever, B. O. Gürses, and M. Sarikanat, Compos. Sci. Technol. 129, 108 (2016).
J.-H. Jeon, R. K. Cheedarala, Ch.-D. Kee, and O. Il-Kwon, Adv. Funct. Mater. 23 (48), 6007 (2013).
S. J. Kim, M. S. Kim, S. I. Kim, G. M. Spinks, B. Ch. Kim, and G. G. Wallace, Chem. Mater. 18 (24), 5805 (2006).
T. F. Otero, Polym. Rev. 53 (3), 311 (2013).
A. Tiwaril and S. K. Shukla, eXPRESS Polym. Lett. 3 (9), 553 (2009).
L. A. Nud’ga, V. Petrova, V. I. Frolov, I. V. Gofman, A. V. Maslyakova, and N. M. Zhuravleva, Polym. Sci., Ser. A 47 (2), 90 (2005).
S. Hosseini, J. Simiari, and B. Farhadpour, Iran. Polym. J. 18 (1), 3 (2009).
S. R. Khairkar and A. R. Raut, Am. J. Mater. Sci. Eng. 2 (4), 62 (2014).
E. Yu. Rosova, N. G. Bel’nikevich, Z. F. Zoolshoev, N. N. Saprykina, and G. K. Elyashevich, Russ. J. Appl. Chem. 88 (11), 1788 (2015).
G. Vikhoreva and A. S. Kechek’yan, Polym. Sci., Ser. B 46 (1–2), 39 (2004).
A. Zajac, J. Hanuza, M. Wandas, and L. Dyminska, Spectrochim. Acta, Part A 134, 114 (2015).
S. G. Bachhav and D. R. Patil, Am. J. Mater. Sci. 5 (4), 90 (2015).
M. Grzeszczuk, A. Granska, and R. Szostak, Int. J. Electrochem. Sci. 8, 8951 (2013).
I. Yu. Dmitriev, P. V. Vlasov, M. F. Lebedeva, I. V. Gofman, V. Y. Elokhovsky, E. N. Popova, M. S. Lozhkin, E. N. Vlasova, I. S. Kuryndin, M. A. Smirnov, and G. K. Elyashevich, Mater. Chem. Phys. 187, 88 (2017).
M. A. Smirnov, P. V. Vlasov, I. Yu. Dmitriev, V. K. Lavrent’ev, and G. K. Elyashevich, Polym. Sci., Ser. B 54 (9–10), 477 (2012).
E. Smela, W. Lu, and B. R. Mattes, Synth. Met. 151 (1), 25 (2005).
T.-Sh. Tsai, V. Pillay, Y. E. Choonara, L. C. Toit, G. Modi, D. Naidoo, and Pr. Kumar, Polymers 3, 150 (2011).
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Original Russian Text © I.Yu. Dmitriev, E.Yu. Rozova, Z.F. Zoolshoev, P.V. Nesterov, I.S. Kuryndin, E.S. Krainyukov, S.V. Lebedev, G.K. Elyashevich, 2018, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2018, Vol. 60, No. 3, pp. 217–226.
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Dmitriev, I.Y., Rozova, E.Y., Zoolshoev, Z.F. et al. Electromechanical Response and Structure of Chitosan–Polyaniline Composite Systems. Polym. Sci. Ser. A 60, 322–331 (2018). https://doi.org/10.1134/S0965545X18030033
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DOI: https://doi.org/10.1134/S0965545X18030033