Skip to main content
SpringerLink
Log in

Phase equilibria in a polyethylene–polystyrene system

  • Polymer Blends
  • Published:
Polymer Science, Series A Aims and scope Submit manuscript

Abstract

The method of optical interferometry is used to study the interaction of PE with PS in situ. On the basis of the obtained data, phase diagrams of the PE–PS system are constructed for a number of molecular masses of the components. For PE and PS oligomers, the UCMT values are determined. Pair parameters for the interaction of homopolymers are calculated, and their dependences on temperature and molecular mass are considered. The quantitative analysis of the behavior of high-molecular-mass fractions of PE and PS at high temperatures is carried out, and the regions of a partial compatibility of the components are predicted.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. D. Sjoerdsma, A. S. A. M. Bleijenberg, and D. Heikens, in Polymer Blends. Processing, Morphology and Properties, Ed. by E. Martuscelli, R. Palumbo, and M. Kryszewscki (Plenum Press, New York; London, 1979), p.201.

  2. W. M. Barentsen and D. Heikens, Polymer 14, 579 (1973).

    Article  CAS  Google Scholar 

  3. W. M. Barentsen, D. Heikens, and P. Piet, Polymer 15, 119 (1974).

    Article  CAS  Google Scholar 

  4. D. Heikens and W. M. Barentsen, Polymer 18, 69 (1977).

    Article  CAS  Google Scholar 

  5. N. I. Puchkov, Candidate’s Dissertation in Chemistry (IFKh RAN, Moscow, 1983).

    Google Scholar 

  6. Polymer Blends, Ed. by D. R. Paul and S. Newman (Acad. Press, London, 1978), Vol.2.

  7. O. Olabisi, L. M. Robeson, and M. T. Shaw, Polymer-Polymer Miscibility (Acad. Press, New York, 1979).

    Google Scholar 

  8. Polymer Blends. Performance, Ed. by D. R. Paul and C. B. Bucknall (Wiley, New York, 2000), Vol. II.

  9. J. K. Kim, S. Kim, and C. E. Park, Polymer 38 (9), 2155 (1997).

    Article  CAS  Google Scholar 

  10. N. D. B. Lazo and C. E. Scott, Polymer 40 (20), 5469 (1999).

    Article  CAS  Google Scholar 

  11. J. Reignier and B. D. Favis, Macromolecules 33 (19), 6998 (2000).

    Article  CAS  Google Scholar 

  12. S. Okamoto and H. Ishida, Macromolecules 34 (21), 7392 (2001).

    Article  CAS  Google Scholar 

  13. T. Kallel, V. Massardier-Nageotte, M. Jaziri, J.-F. Gerard, and B. Elleuch, J. Appl. Polym. Sci. 90 (9), 2475 (2003).

    Article  CAS  Google Scholar 

  14. B. Lin, F. Mighri, M. A. Huneault, and U. Sundararaj, Macromolecules 38 (13), 5609 (2005).

    Article  CAS  Google Scholar 

  15. R. Salehiyan, Y. Yoo, W. J. Choy, and K. Hyun, Macromolecules 47 (12), 4066 (2014).

    Article  CAS  Google Scholar 

  16. Z. Wang, C.-M. Chan, S. H. Zhu, and J. Shen, Polymer 39 (26), 6801 (1998).

    Article  CAS  Google Scholar 

  17. R. Fayt, R. Jerome, and Ph. Teyssie, J. Polym. Sci., Part B: Polym. Phys. 27 (4), 775 (1989).

    Article  CAS  Google Scholar 

  18. C. Harrats, R. Fayt, R. Jerome, and S. Blacher, J. Polym. Sci., Part B: Polym. Phys. 41 (2), 202 (2003).

    Article  CAS  Google Scholar 

  19. G. Chen, S. Guo, and H. Li, J. Appl. Polum. Sci. 86 (1), 23 (2002).

    Article  CAS  Google Scholar 

  20. Polymer Blends, Ed. by D. R. Paul and S. Newman (Acad. Press, London, 1978), Vol.1.

  21. V. N. Kuleznev, Polymer Blends (Khimiya, Moscow, 1980) [in Russian].

    Google Scholar 

  22. R. J. Kern and R. J. Slocombe, J. Polym. Sci. 15 (79), 183 (1955).

    Article  CAS  Google Scholar 

  23. S. Krause, J. Polym. Sci., Part A-2: Polym. Phys. 7 (1), 249 (1969).

    Article  CAS  Google Scholar 

  24. D. J. Dunn and S. Krause, Polym. Lett. Ed. 12 (10), 591 (1974).

    Article  CAS  Google Scholar 

  25. A. E. Chalykh, V. K. Gerasimov, A. D. Aliev, V. V.Matveev, N. V. Shevlyakova, M. G. D’yakova, and V. A. Tverskoi, Polym. Sci., Ser. A 52 (4), 453 (2010).

    Article  Google Scholar 

  26. A. Ya. Malkin and A. E. Chalykh, Diffusion and Viscosity of Polymers: Measurement Techniques (Khimiya, Moscow, 1979) [in Russian].

    Google Scholar 

  27. A. E. Chalykh, A. I. Zagaitov, D. P. Korotchenko, and V. V. Gromov, Optical Diffusiometer (IFKh RAN, Moscow, 1996) [in Russian].

    Google Scholar 

  28. A. E. Chalykh, U. V. Nikulova, and A. A. Shcherbina, Polym. Sci., Ser. A 57 (4), 445 (2015).

    Article  CAS  Google Scholar 

  29. R. R. Khasbiullin, Candidate’s Dissertation in Chemistry (IFKh RAN, Moscow, 2003).

    Google Scholar 

  30. A. E. Chalykh, V. K. Gerasimov, and Yu. M. Mikhailov, Phase State Diagrams of Polymer Systems (Yanus-K, Moscow, 1998) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. E. Chalykh, U. V. Nikulova, A. A. Shcherbina & V. V. Matveev

Authors
  1. A. E. Chalykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. U. V. Nikulova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Shcherbina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Shcherbina.

Additional information

Original Russian Text © A.E. Chalykh, U.V. Nikulova, A.A. Shcherbina, V.V. Matveev, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 1, pp. 86–94.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chalykh, A.E., Nikulova, U.V., Shcherbina, A.A. et al. Phase equilibria in a polyethylene–polystyrene system. Polym. Sci. Ser. A 59, 107–115 (2017). https://doi.org/10.1134/S0965545X17010023

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X17010023

Search

Navigation