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The structural features of fluorinated paraffins

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Abstract

A systematic study of the molecular and supramolecular structural features of fluorinated paraffins has been conducted with the use of a set of physical methods and quantum-chemical calculations of the parameters of the IR and NMR spectra. The presence of nonuniformity in the morphological structures of samples obtained from different initial products has been shown. Incomplete substitution of fluorine for hydrogen during synthesis has been revealed, and the types of structural groups in which the substitution occurs have been determined. Fluoroparaffins have been found to effectively dissolve in supercritical carbon dioxide, a phenomenon that opens new fields of application for these materials.

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Authors and Affiliations

  1. State Research Center of the Russian Federation—All-Russia Research Institute of Aviation Materials, ul. Radio 17, Moscow, 105005, Russia

    V. M. Buznik & G. Yu. Yurkov

  2. National Research Tomsk State University, Tomsk, pr. Lenina 36, 634050, Russia

    V. M. Buznik

  3. Faculty of Physics, Moscow State University, Moscow, 119891, Russia

    Yu. E. Vopilov

  4. Baikov Institute of Metallurgy and Material Science, Russian Academy of Sciences, Leninskii pr. 49, Moscow, 119991, Russia

    G. Yu. Yurkov

  5. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    L. N. Ignat’eva

  6. OOO GaloPolimer Kirovo-Chepetsk, Pozharnyi per. 2, Kirovo-Chepetsk, 613040, Russia

    A. N. Toropov

  7. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, 142432, Russia

    M. A. Smirnov

Authors
  1. V. M. Buznik
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  2. Yu. E. Vopilov
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  3. G. Yu. Yurkov
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  4. L. N. Ignat’eva
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  5. A. N. Toropov
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  6. M. A. Smirnov
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Correspondence to V. M. Buznik.

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Original Russian Text © V.M. Buznik, Yu.E. Vopilov, G.Yu. Yurkov, L.N. Ignat’eva, A.N. Toropov, M.A. Smirnov, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 4, pp. 323–332.

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Buznik, V.M., Vopilov, Y.E., Yurkov, G.Y. et al. The structural features of fluorinated paraffins. Polym. Sci. Ser. A 57, 415–424 (2015). https://doi.org/10.1134/S0965545X15040045

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  • DOI: https://doi.org/10.1134/S0965545X15040045

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