Abstract
Modern concepts about the structural organization of cellulose and the character of formation of its inter- and intermolecular hydrogen bonds are analyzed. A scheme for the structure of the cellulose microfibril that supposes the presence of slit-shaped micropores in its structure is proposed. The proton magnetic relaxation study of sorption processes reveals that, at a moisture content of 7–10%, the filling of cellulose micropores occurs with a concomitant increase in their lateral sizes and decreases in the degrees of crystallinity of samples.
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Original Russian Text © L.Yu. Grunin, Yu.B. Grunin, V.I. Talantsev, E.A. Nikolskaya, D.S. Masas, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 1, pp. 46–55.
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Grunin, L.Y., Grunin, Y.B., Talantsev, V.I. et al. Features of the structural organization and sorption properties of cellulose. Polym. Sci. Ser. A 57, 43–51 (2015). https://doi.org/10.1134/S0965545X15010034
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DOI: https://doi.org/10.1134/S0965545X15010034