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Optimization of Metal-Organic Framework MOF-5 Synthesis for Use in Cryo-Adsorption Hydrogen Storage

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Abstract

Synthesis of MOF-5 at room temperature was optimized. The phase-pure crystalline structure with high hydrogen capacity was prepared at room temperature and atmospheric pressure. The MOF-5 pressing and subsequent fractionation singificantly improves its operation properties. An adsorption apparatus was designed and assembled to study the adsorption properties of the synthesized materials under the conditions close to the real one. Experiments on studying the adsorption properties of MOF-5 under the conditions of cryogenic hydrogen adsorption showed that the samples adsorbed up 3.3 wt % H2 at a 30 atm pressure and –196°С.

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Funding

Synthesis of the samples and their sorption tests were financially supported by the Russian Science Foundation (project no. 21-43-04406). The physicochemical parameters of the materials were studied within the framework of the government assignment, theme: Physical Chemistry of the Surface, Adsorption, and Catalysis.

Studies of the phase composition of the samples were financially supported by the Science and Universities National Project.

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    A. I. Nikiforov, V. D. Kravchenko, E. A. Chesnokov & A. G. Popov

  2. Institute of Chemistry, Saratov State University, 410012, Saratov, Russia

    I. A. Nikiforov

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  1. A. I. Nikiforov
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  2. V. D. Kravchenko
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  3. E. A. Chesnokov
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Correspondence to A. I. Nikiforov.

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Nikiforov, A.I., Kravchenko, V.D., Chesnokov, E.A. et al. Optimization of Metal-Organic Framework MOF-5 Synthesis for Use in Cryo-Adsorption Hydrogen Storage. Pet. Chem. 63, 805–813 (2023). https://doi.org/10.1134/S0965544123060257

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