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Hydrogenation of Lignocellulosic Biomass-Derived Furfural over Ruthenium and Nickel Catalysts Supported on Mesoporous Aluminosilicate

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Abstract

The paper describes synthesis of ruthenium and nickel catalysts supported on aluminum-modified SBA-15 (Santa Barbara Amorphous-15) mesoporous silicate, designated as Al-SBA-15, with a Si/Al ratio of 20. The catalysts were investigated in aqueous-phase hydrogenation of furfural, a valuable product obtained from lignocellulosic biomass. Elevating the reaction temperature from 200 to 250°C and the hydrogen pressure from 3 to 5 MPa enhanced the selectivity towards methyltetrahydrofuran (MTHF). The ruthenium catalyst outperformed its nickel counterpart in terms of activity in aqueous-phase furfural hydrogenation (250°C, 5 MPa H2).

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Funding

The study was supported by the Russian Science Foundation (project no. 22-79-10077, https://rscf.ru/project/22-79-10077).

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Authors and Affiliations

  1. Faculty of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    E. A. Roldugina, M. P. Boronoev, I. I. Shakirov, Yu. S. Kardasheva, S. V. Kardashev, A. L. Maximov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maximov

Authors
  1. E. A. Roldugina
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  2. M. P. Boronoev
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  3. I. I. Shakirov
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  4. Yu. S. Kardasheva
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  5. S. V. Kardashev
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  6. A. L. Maximov
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  7. E. A. Karakhanov
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Contributions

E.A. Karakhanov: conceptualization.

M.P. Boronoev: adaptation of catalyst synthesis method.

I.I. Shakirov: synthesis of catalysts.

Yu.S. Kardasheva: catalytic test.

S.V. Kardashev: physicochemical characterization of catalysts.

E.A. Roldugina: qualitative and quantitative analysis of reaction products.

A.L. Maximov: interpretation of catalysis results.

Corresponding author

Correspondence to E. A. Roldugina.

Ethics declarations

A.L. Maximov and E.A. Karakhanov, co-authors, are the Chief Editor and an Editorial Board member at the Nanogeterogennyi kataliz (Nanoheterogeneous Catalysis) Journal, respectively. The other co-authors declare no conflict of interest requiring disclosure in this article.

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Roldugina, E.A., Boronoev, M.P., Shakirov, I.I. et al. Hydrogenation of Lignocellulosic Biomass-Derived Furfural over Ruthenium and Nickel Catalysts Supported on Mesoporous Aluminosilicate. Pet. Chem. 63, 655–662 (2023). https://doi.org/10.1134/S0965544123040072

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