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Butadiene Synthesis from Formaldehyde and Propylene on Mesoporous Metal Phosphates

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Abstract

One-step gas-phase synthesis of butadiene from formaldehyde and propylene on aluminum (AlP), zirconium (ZrP), and niobium (NbP) phosphates with the pore volumes of 0.51, 0.25, and 0.19 cm3/g, respectively, was studied for the first time. The physicochemical properties of the catalysts were studied by X-ray fluorescence analysis, low-temperature nitrogen adsorption, X-ray diffraction analysis, scanning electron microscopy, temperature-programmed NH3 desorption, IR spectroscopy of adsorbed pyridine, and 31Р MAS NMR. Evaluation of the catalytic properties of the phosphates showed that they can be ranked in the following order with respect to the formaldehyde conversion and target product (butadiene) formation selectivity: AlP < ZrP < NbP, which correlates with metal electronegativity series. The СН2О conversion on the most active NbP was 4.5%, and the molar selectivity of the butadiene formation was 45.3%.

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Funding

Studies on the synthesis and MAS NMR analysis of the samples were financially supported by the Russian Science Foundation (project no. 20-13-00203). The acid properties were studied within the framework of the government assignment “Physical Chemistry of Surface, Adsorption, and Catalysis.” The phase composition of the samples was studied within the framework of the federal project “Development of the Infrastructure for Scientific Research and Training,” Science and Universities National Project.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    O. A. Ponomareva, I. V. Dobryakova, I. A. Kostyukov, E. D. Kuskova, A. L. Grachev, T. A. Ryabchun, T. M. Roshchina & I. I. Ivanova

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    O. A. Ponomareva & I. I. Ivanova

Authors
  1. O. A. Ponomareva
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  2. I. V. Dobryakova
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  3. I. A. Kostyukov
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  4. E. D. Kuskova
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  5. A. L. Grachev
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  6. T. A. Ryabchun
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  7. T. M. Roshchina
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  8. I. I. Ivanova
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Correspondence to O. A. Ponomareva.

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Ivanova I.I. is the Editor-in-Chief of Sovremennye Molekulyarnye Sita. Advanced Molecular Sieves Journal. The other authors declare no conflict of interest requiring disclosure in this article.

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Ponomareva, O.A., Dobryakova, I.V., Kostyukov, I.A. et al. Butadiene Synthesis from Formaldehyde and Propylene on Mesoporous Metal Phosphates. Pet. Chem. 63, 769–777 (2023). https://doi.org/10.1134/S0965544123030088

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