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Effects of Grain Size on the Activity of H-MFI Zeolites in Liquid-Phase Condensation of Propene with Formaldehyde

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Abstract

This study investigated the activity of H-MFI catalysts modified by the top-down method in the liquid-phase Prins reaction between propene and formaldehyde. The physicochemical characterization of the catalyst demonstrated that grinding the catalyst reduces the specific surface area and affects the micropore to mesopore ratio in the samples. Reducing the grain size was found to increase the initial substrate consumption rate and reduce the diffusion limitations in the system. At the same time, grinding shifts the product composition towards a higher proportion of byproducts. An assessment of the kinetic curves enabled the researchers to propose a number of equations that accurately reflect catalyst deactivation. Both the reaction rate and deactivation rate vary directly with the zeolite dispersion, while the deactivation of the sample is more sensitive to the grain size.

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ACKNOWLEDGMENTS

This work was performed using equipment of the Shared Research Center “Analytical center of deep oil processing and petrochemistry of TIPS RAS”. The authors are sincerely grateful to colleagues from this Center, and especially to Dr. Levin, PhD (Phys.-Math.), for his cooperation in XRD examination, and to Dr. Sadovnikov, PhD (Chem.), for his cooperation in SEM examination of the samples.

Funding

The reported study was funded by RFBR (project number 20-33-90112).

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    S. P. Bedenko, A. A. Mukusheva, V. V. Malyavin & K. I. Dement’ev

  2. Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia

    A. A. Mukusheva

Authors
  1. S. P. Bedenko
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  2. A. A. Mukusheva
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  3. V. V. Malyavin
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  4. K. I. Dement’ev
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Correspondence to S. P. Bedenko.

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K.I. Dement’ev, a co-author, is a Deputy Chief Editor at the Neftekhimiya (Petroleum Chemistry) Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.

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Bedenko, S.P., Mukusheva, A.A., Malyavin, V.V. et al. Effects of Grain Size on the Activity of H-MFI Zeolites in Liquid-Phase Condensation of Propene with Formaldehyde. Pet. Chem. 63, 268–276 (2023). https://doi.org/10.1134/S0965544123010115

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