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Catalytic Performance of Microporous and Hierarchical Zeolites in Condensation of Acetone with Ammonia

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Abstract

The study investigates the catalytic performance of microporous (H–Y) and micro–meso–macroporous (H–Yh, Fe2O3/H–Yh, PbO/H–Yh, and La–H–Yh ) FAU-type zeolites in the condensation of acetone with ammonia. In the presence of H–Yh, Fe2O3/H–Yh, and La–H–Yh, 2,4,6-trimethylpyridine was synthesized with selectivity of 54%, 58%, and 24%, respectively. In the presence of H–Y and PbO/H–Yh, the predominant reaction was acetone condensation, with the reaction products mostly consisting of diacetone alcohol and mesityl oxide.

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REFERENCES

  1. Tian, J., Chen, L., Zhang, C., Yan, X., and Li, Y., J. Heterocyclic Chem., 2015, vol. 52, no. 5, pp. 1377–1381. https://doi.org/10.1002/jhet.2242

    Article  CAS  Google Scholar 

  2. Gliozzi, G., Frattini, L., Righi, P., and Cavani, F., J. Mol. Catal. A: Chemical, 2014, vol. 393, pp. 325–332. https://doi.org/10.1016/j.molcata.2014.06.023

    Article  CAS  Google Scholar 

  3. Kirchhoff, J. and Kraushaar, F., Polymer. Polymer Compos., 2000, vol. 8, no. 4, pp. 245–254.

    CAS  Google Scholar 

  4. Patent US 4701529, 1987.

  5. Patent GB 817038, 1959.

  6. Patent US 4220783, 1980.

  7. Guomin, X. and Jin, Z., Huaxue Shijie, 2002, vol. 43, no. 5, pp. 255–256.

    Google Scholar 

  8. Rama Rao, A.V., Kulkarni, S.J., Ramachandra Rao, R., and Subrahmanyanm, M., Appl. Catal., A, 1994, vol. 111, pp. 101–108. https://doi.org/10.1016/0926-860X(94)85044-5

    Article  Google Scholar 

  9. Patent US 279642, 1957.

  10. Shiri, L. and Ghorbani-Choghamarani, A., J. Chilean Chem. Soc., 2009, vol. 54, no. 2, pp. 191–193. https://doi.org/10.4067/S0717-97072009000200022

    Article  CAS  Google Scholar 

  11. Zhu, H.L., Xu, W., Wang, J.F., and Zheng, Y.Q., Synthetic Metals, 2012, vol. 162, nos. 13–14, pp. 1327–1334. https://doi.org/10.1016/j.synthmet.2012.05.016

    Article  CAS  Google Scholar 

  12. Patent US 4752636, 1988.

  13. Patent US 4668766, 1987.

  14. Entry on Kollidin. ROEMPP Online Encyclopedia, Georg Thieme Verlag, 2017.

  15. Sirlibaev, T.S., O’zbekiston Respublikasi Fanlar Akademiyasining Maruzalari, 2007, vol. 5, pp. 49–52.

    Google Scholar 

  16. Xiong, Y., Lu, J., Hunter, J., Li, L., Scott, D., Choi, H.G., Lim, S.M., Manandhar, A., Gondi, S., Sim, T., Westover, K.D., and Gray, N.S., ACS Med. Chem. Lett., 2017, vol. 8, no. 1, pp. 61–66. https://doi.org/10.1021/acsmedchemlett.6b00373

    Article  CAS  PubMed  Google Scholar 

  17. Boiko, V.N., Filatov, A.A., Yagupolskii, Y.L., Tyrra, W., Naumann, D., Pantenburg, I., Fischer, H.T.M., and Schulz, F., J. Fluor. Chem., 2011, vol. 132, no. 12, pp. 1219–1226. https://doi.org/10.1016/j.jfluchem.2011.06.045

    Article  CAS  Google Scholar 

  18. Pavlov, M.L., Travkina, O.S., Khazipova, A.N., Basimova, R.A., Shavaleeva, N.N., and Kutepov, B.I., Petrol. Chem., 2015, vol. 55, pp. 552–556. https://doi.org/10.1134/S0965544115070105

    Article  CAS  Google Scholar 

  19. Travkina, O.S., Agliullin, M.R., Filippova, N.A., Khazipova, A.N., Danilova, I.G., Grigor’eva, N.G., Narender, N., Pavlov, M.L., and Kutepov, B.I., RSC Adv., 2017, no. 7, pp. 32581–32590. https://doi.org/10.1039/C7RA04742H

    Article  CAS  Google Scholar 

  20. Auroux, A., Calorimetry and Thermal Methods in Catalysis, Springer., 2013, vol. 154.

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Funding

This work was performed within the State Program of IPC UFRC RAS (project no. FMRS-2022-0080). The structural investigation was carried out at the Agidel Regional Center for Collective Use of UFRC RAS within the State Program of IPC UFRC RAS (project no. FMRS-2022-0081).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    N. G. Grigor’eva, N. A. Filippova, S. V. Bubennov & B. I. Kutepov

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  1. N. G. Grigor’eva
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  2. N. A. Filippova
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  3. S. V. Bubennov
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  4. B. I. Kutepov
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Correspondence to N. G. Grigor’eva.

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Grigor’eva, N.G., Filippova, N.A., Bubennov, S.V. et al. Catalytic Performance of Microporous and Hierarchical Zeolites in Condensation of Acetone with Ammonia. Pet. Chem. 62, 942–949 (2022). https://doi.org/10.1134/S0965544122070131

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