Abstract
Cracking of high-sulfur natural bitumen of the Mordovo-Karmal and Ashalchi fields (Russia, Republic of Tatarstan) at a temperature of 450°C and different process times was studied. The characteristic features of the changes in the material and group compositions of the cracking products and the nature of the transformation of the group composition of the sulfur-containing compounds of oils as dependent on the cracking conditions were demonstrated. The kinetic regularities of the formation and decomposition of benzo- and dibenzothiophene derivatives in the cracking products of the natural bitumens were elucidated. Cracking was shown to involve breakdown of large molecules (resins and asphaltenes) with formation of a broad range of low-molecular-weight sulfur-containing compounds falling into oils. The sets of benzo- and dibenzothiophene homologs thereby formed were identical, but the rates of formation and decomposition of the sulfur-containing compounds were dependent on the thermal stability of the components of the initial bitumens. The data obtained provide a substantially better understanding of the laws governing the transformation of the sulfur-containing compounds of heavy hydrocarbon feedstock in thermal processes.
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REFERENCES
Shahandeh, H. and Li, Z., Energy Fuels, 2016, vol. 30, pp. 5202–5213. https://doi.org/10.1021/acs.energyfuels.6b00037
Yakubov, M.R., Milordov, D.V., Yakubova, S.G., Borisov, D.N., Ivanov, V.T., and Sinyashin, K.O., Petrol. Chem., 2016, vol. 56, no. 1, pp. 16–20. https://doi.org/10.1134/S0965544116010072
Yakubov, M.R., Milordov, D.V., Yakubova, S.G., Borisov, D.N., Gryaznov, P.I., Mironov, N.A., Abilova, G.R., Borisova, Y.Y., and Tazeeva, E.G., Petrol. Sci. Technol., 2016, vol. 34, no. 2, pp. 177–183. https://doi.org/10.1080/10916466.2015.1122627
Mullins, O.C., Annu. Rev. Anal. Chem., 2011, vol. 4, pp. 393–418. https://doi.org/10.1146/annurev-anchem-061010-113849
Palermo, A., Solovyov, A., Ertler, D., Okrut, A., Gates, B.C., and Katz, A., Chem. Sci., 2017, vol. 8, no. 7, pp. 4951–4960. https://doi.org/10.1039/C7SC00686A
Kayukova, G.P., Gubaidullin, A.T., Petrov, S.M., Romanov, G.V., Petrukhina, N.N., and Vakhin, A.V., Energy Fuels, 2016, vol. 30, pp. 773–783. https://doi.org/10.1021/acs.energyfuels.5b01328
Pang, W.-W., Kuramae, M., Kinoshita, Y., Lee, J.-K., Zhang, Y.Z., Yoon, S.-H., and Mochida, I., Fuel, 2009, vol. 88, pp. 663–669. https://doi.org/10.1016/j.fuel.2008.09.020
Lee, J.M., Shin, S., Ahn, S., Chun, J.H., Lee, K.B., Mun, S., Jeon, S.G., Na, J.G., and Nho, N.S., Fuel Process. Technol., 2014, vol. 119, pp. 204–210. https://doi.org/10.1016/j.fuproc.2013.11.014
Martinez-Grimaldo, H., Ortiz-Moreno, H., SanchezMinero, F., Ramírez, J., Cuevas-Garcia, R., and Ancheyta-Juarez, J., Catal. Today, 2014, vols. 220–222, pp. 295–300. https://doi.org/10.1016/j.cattod.2013.08.012
Wang, D., Li, Y., Jin, L., Hao, K., Wei, B., Yao, D., and Hu, H., Appl. Catal. B: Environ., 2019, vol. 258, p. 117944. https://doi.org/10.1016/j.apcatb.2019.117944
Castaneda, L.C., Munoz, J.A.D., and Ancheyta, J., Catal. Today, 2014, vols. 220–222, pp. 248–273. https://doi.org/10.1016/j.cattod.2013.05.016
Sviridenko, N.N., Golovko, A.K., Kirik, N.P., and Anshitz, A.G., J. Taiwan Inst. Chem. Eng., 2020, vol. 112, pp. 97–105. https://doi.org/10.1016/j.jtice.2020.06.018
Guo, K., Hansen, V.F., Li, H., and Yu, Z., Fuel, 2018, vol. 211, pp. 697–703. https://doi.org/10.1016/j.fuel.2017.09.097
Chen, X., Li, H., Zhang, L., Shi, Q., Zhao, S., and Xu, C., Fuel, 2020, vol. 278, p. 118334. https://doi.org/10.1016/j.fuel.2020.118334
Muhieddine, A.-S., Tahani, A.-S., Rawan, A.-M., Rashed, B., and Xiaoliang, M., Energy Fuels, 2017, vol. 31, pp. 7464–7470. https://doi.org/10.1021/acs.energyfuels.7b01272
Kohli, K., Prajapati, R., Maity, S.K., Sau, M., and Garg, M.O., Fuel, 2016, vol. 175, pp. 264–273. https://doi.org/10.1016/j.fuel.2016.02.036
Lorentz, C., Laurenti, D., Zotin, J. L., and Geantet, C., Catal. Today, 2017, vol. 292, pp. 26–37. https://doi.org/10.1016/j.cattod.2017.04.052
Sviridenko, N.N., Krivtsov, E.B., and Golovko, A.K., Chem. Sust. Dev., 2018, vol. 26, no. 2, pp. 179–186. https://doi.org/10.15372/CSD20180210
Krivtsov, E.B., Sviridenko, N.N., and Golovko, A.K., Izv. Tomsk. Politekh. Univ., 2013, vol. 323, no. 3, pp. 37–41.
Bava, Y.B., Geronés, M., Giovanetti, L.J., Andrini, L., and Erben, M.F., Fuel, 2019, vol. 256, p. 115952. https://doi.org/10.1016/j.fuel.2019.115952
ACKNOWLEDGMENTS
This study was carried out within the framework of the State assignment of the Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, financially supported by the Ministry of Science and Higher Education of the Russian Federation.
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Translated from Neftekhimiya, 2021, Vol. 61, No. 6, pp. 926–933 https://doi.org/10.31857/S0028242121060174.
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Krivtsov, E.B., Sviridenko, N.N. Calculation of the Kinetic Parameters for the Reactions of Formation and Decomposition of Thiophene Derivatives in the Process of High-Suifur Natural Bitumens Cracking. Pet. Chem. 61, 1319–1325 (2021). https://doi.org/10.1134/S0965544121110049
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DOI: https://doi.org/10.1134/S0965544121110049