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Nonoxidative Methane Conversion on Granulated Mo/ZSM-5 Catalysts

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Abstract

Nonoxidative conversion of methane to aromatic hydrocarbons on granulated Мо/ZSM-5 catalysts was studied. The catalysts prepared using zeolites with the hierarchic pore system surpass in activity the catalysts prepared by the traditional method, mixing of powdered Н-ZSM-5 with pseudoboehmite, followed by granulation and calcination. The textural characteristics of the granulated zeolites and of Mo-containing catalysts based on them were studied. The catalyst samples contain micro-, meso-, and macropores, but the pore formation pattern in the granulated catalysts with the hierarchic pore system and in the catalysts containing 30% binder is different.

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Funding

The study was performed within the framework of the government assignment for the Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences (project V.46.2.1), funded by the Ministry of Science and Higher Education of the Russian Federation. The results of studying the physicochemical properties of granulated ZSM-5 zeolites with high degree of crystallinity and hierarchic pore structure were obtained within the framework of project no. 19-33-60009 of the Russian Foundation for Basic Research, Polyfunctional Catalytic Systems Based on ZSM-5 Zeolite with Hierarchic Pore Structure: a Way to a Highly Efficient Technology for Producing Practically Important N-Heterocyclic Compounds.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, 634055, Tomsk, Russia

    A. A. Stepanov, L. L. Korobitsyna & A. V. Vosmerikov

  2. Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450075, Bashkortostan, Russia

    R. Z. Kuvatova, O. S. Travkina & B. I. Kutepov

Authors
  1. A. A. Stepanov
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  2. R. Z. Kuvatova
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  3. L. L. Korobitsyna
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  4. O. S. Travkina
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  5. A. V. Vosmerikov
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  6. B. I. Kutepov
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Corresponding author

Correspondence to A. V. Vosmerikov.

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Translated from Sovremennye Molekulyarnye Sita. Advanced Molecular Sieves, 2021, Vol. 3, No. 1, pp. 125–132.

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Stepanov, A.A., Kuvatova, R.Z., Korobitsyna, L.L. et al. Nonoxidative Methane Conversion on Granulated Mo/ZSM-5 Catalysts. Pet. Chem. 61, 370–377 (2021). https://doi.org/10.1134/S0965544121020092

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