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The Synthesis of (2S, 3S, 4R)-2,3-Dialkyl-N-Phenyl-1,2,3,4-Tetrahydro-4-Quinolinamines in the Presence of Crystalline and Amorphous Aluminosilicates

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Abstract

The catalytic activity of micro- and micro–meso–macroporous zeolites of the FAU structural type and an ASM mesoporous aluminosilicate in the reaction of aniline with C3–C5 aldehydes has been studied. It has been established that under the studied conditions, (2S, 3S, 4R)-2,3-dialkyl-N-phenyl-1,2,3,4-tetrahydro-4-quinolinamines are the main products formed over the tested catalysts with the selectivity of up to 71%.

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ACKNOWLEDGEMENTS

The structural studies of compounds 1–3 were performed at the Agidel Shared-Use Center at the Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences.

Funding

This work was supported by the Russian Science Foundation (joint Russian–Indian grant no. 16-43-02010) and state task no. AAAA-A17-117012610058-4.

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Authors and Affiliations

  1. Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Bashkortostan, Russia

    N. G. Grigor’eva, S. A. Kostyleva, S. V. Bubennov & B. I. Kutepov

  2. Ufa State Petroleum Technological University, 450062, Ufa, Bashkortostan, Russia

    N. G. Grigor’eva, A. S. Artem’eva & B. I. Kutepov

Authors
  1. N. G. Grigor’eva
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  2. S. A. Kostyleva
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  3. A. S. Artem’eva
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  4. S. V. Bubennov
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  5. B. I. Kutepov
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Corresponding author

Correspondence to N. G. Grigor’eva.

Additional information

Translated by E. Boltukhina

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Grigor’eva, N.G., Kostyleva, S.A., Artem’eva, A.S. et al. The Synthesis of (2S, 3S, 4R)-2,3-Dialkyl-N-Phenyl-1,2,3,4-Tetrahydro-4-Quinolinamines in the Presence of Crystalline and Amorphous Aluminosilicates. Pet. Chem. 60, 525–531 (2020). https://doi.org/10.1134/S0965544120040088

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  • DOI: https://doi.org/10.1134/S0965544120040088

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