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Sunflower Oil Hydrodeoxygenation in the Presence of NiMoS/B2O3–Al2O3 Catalysts

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Abstract

It has been shown that borate-containing alumina can be used as a support for sunflower oil hydrodeoxygenation catalysts at 380°C, 4.0 MPa, and a feed space velocity of 1 h–1 with a liquid product yield of 81–85 wt %. It has been found that, with an increase in the boron oxide content in the catalyst, owing to an increase in the catalyst acidity, the fraction of isoalkanes in the products increases to 77–78% and the contribution of decarboxylation/decarbonylation reactions to the formation of the products increases.

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REFERENCES

  1. M. Al-Sabawi and J. Chen, Energy Fuels 26, 5373 (2012).

    Article  CAS  Google Scholar 

  2. M. Laakkonen, J. Myllyoja, B. Toukoniitty, et al., US Patent No. 20130090502 (2012).

  3. J. A. Petry and T. L. Marker, EP Patent No. 1728844 (2006).

  4. R. Abhari, L. Tomlinson, P. Havlik, and N. Jannasch, US Patent No. 7968757 (2008).

  5. D. R. Ghonasgi, L. Sughrue, E. J. Yao, and X. Xu, US Patent No. 7955401 (2007).

  6. J. R. Gomes, J. L. Zotin, M. E. Pacheco, and R. M. Cotta Ferreira Da Silva, US Patent No. 20100270207 (2010).

  7. E. Jonson, Energies 12, 250 (2019).

    Article  Google Scholar 

  8. Y. Fujiyama and T. Okuhara, US Patent No. 6045690 (1997).

  9. S. J. Ju, H. J. Jeon, J. M. Park, et al., EP Patent No. 2628781 (2010).

  10. T. N. Kalnes, T. Marker, K. P. Koers, and D. R. Shonnard, Biofuels Technol., Q4, 7 (2008).

    Google Scholar 

  11. P. Šimácek, D. Kubicka, G. Šebor, and M. Pospíšil, Fuel 89, 611 (2010).

    Article  Google Scholar 

  12. J. Jakkula, P. Aalto, V. Niemi, et al., WO Patent No. 2004/022674 (2004).

  13. J. Jakkula, P. Aalto, V. Niemi, et al., EP Patent No, 1 396 531 (2004).

    Google Scholar 

  14. M. Herskowitz, M. V. Landau, Y. Reizner, and D. Berger, Fuel 111, 157 (2013).

    Article  CAS  Google Scholar 

  15. Q. Liu, H. Zuo, Q. Zhang, et al., Chin. J. Catal. 35, 748 (2014).

    Article  CAS  Google Scholar 

  16. C. Wang, Z. Tian, L. Wang, et al., ChemSusChem 5, 1974 (2012).

    Article  CAS  Google Scholar 

  17. O. V. Kikhtyanin, A. E. Rubanov, A. B. Ayupov, and G. V. Echevsky, Fuel 89, 3085 (2010).

    Article  CAS  Google Scholar 

  18. D. Kubicka, M. Bejblova, and J. Vlk, Top. Catal. 53, 168 (2010).

    Article  CAS  Google Scholar 

  19. J. Duan, J. Han, H. Sun, et al., Catal. Commun. 17, 76 (2012).

    Article  CAS  Google Scholar 

  20. R. Zarchin, M. Rabaev, R. Vidruk-Nehemya, et al., Fuel 139, 684 (2015).

    Article  CAS  Google Scholar 

  21. F. P. Sousa, L. Noemí Silva, D. B. de Rezende, et al., Fuel 223, 149 (2018).

    Article  CAS  Google Scholar 

  22. S. Janampelli and S. Darbha, Catal. Today 309, 219 (2018).

    Article  CAS  Google Scholar 

  23. A. A. Nepomnyashchiy, E. A. Buluchevskiy, A. V. Lavrenov, et al., Russ. J. Appl. Chem. 90, 1944 (2017).

    Article  CAS  Google Scholar 

  24. K. W. Jeona, J. O. Shima, J. W. Choa, et al., Fuel 236, 928 (2019).

    Article  Google Scholar 

  25. T. R. Karpova, E. A. Buluchevskii, A. V. Lavrenov, et al., Khim. Interesah Ustoich. Razvit. 21, 61 (2013).

    CAS  Google Scholar 

  26. V. L. Yurpalov, V. A. Drozdov, T. R. Karpova, and A. V. Lavrenov, Khim. Interesah Ustoich. Razvit. 25, 109 (2017).

    CAS  Google Scholar 

  27. D. Kubička, J. Horáček, M. Setnička, et al., Appl. Catal., B 145, 101 (2014).

    Article  Google Scholar 

  28. E. W. Qian, N. Chen, and S. Gong, J. Mol. Catal., A 387, 76 (2014).

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Funding

This work was performed under the state task to Institute of Hydrocarbon Processing of the Siberian Branch of the Russian Academy of Sciences in accordance with the Basic Research Program for the State Academies of Sciences for 2013–2020 (direction V.46, project no. V.46.4.4; state registration in the Unified State Information System for Recording the Results of Research, Development, and Engineering Activity no. AAAA-A17-117021450098-2).

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Authors and Affiliations

  1. Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, 644024, Omsk, Russia

    A. A. Nepomnyashchii, E. A. Buluchevskii & A. V. Lavrenov

Authors
  1. A. A. Nepomnyashchii
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  2. E. A. Buluchevskii
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  3. A. V. Lavrenov
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Correspondence to E. A. Buluchevskii.

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Translated by M. Timoshinina

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Nepomnyashchii, A.A., Buluchevskii, E.A. & Lavrenov, A.V. Sunflower Oil Hydrodeoxygenation in the Presence of NiMoS/B2O3–Al2O3 Catalysts. Pet. Chem. 59, 1049–1054 (2019). https://doi.org/10.1134/S0965544119090123

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  • DOI: https://doi.org/10.1134/S0965544119090123

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