Skip to main content
SpringerLink
Log in

The Effect of the Active Component Content on the Catalytic Activity of Nickel Sulfide Catalysts in Olefin Synthesis from Stearic Acid

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The effect of active component content on the catalytic activity of supported sulfide catalysts in the synthesis of C17 olefins from stearic acid has been studied. It has been shown that an increase in the nickel content leads to a decrease in the catalyst activity; in addition, there is a negative correlation between the activity and the fraction of large particles on the support surface. The highest heptadecene selectivity (50–60%) is observed for alumina-supported catalysts owing to the higher degree of dispersion of the active component.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Catalytic Process Development for Renewable Materials, Ed. by P. Imhof and J. C. van der Waal (Wiley–VCH, Weinheim, 2013).

    Google Scholar 

  2. A. S. Berenblyum, V. Ya. Danyushevsky, P. S. Kuznetsov, et al., Pet. Chem. 56, 663 (2016).

    Article  CAS  Google Scholar 

  3. K. Bergamaski, A. LN. Pinheiro, E. Teixeira-Neto, and F. C. Nart, J. Phys. Chem. B 110, 19271 (2006).

    Article  CAS  PubMed  Google Scholar 

  4. O. M. Wilson, M. R. Knecht, J. C. Garcia-Martinez, and R. M. Crooks, J. Am. Chem. Soc. 128, 4510 (2006).

    Article  CAS  PubMed  Google Scholar 

  5. W. P. Zhou, A. Lewera, R. Larsen, et al., J. Phys. Chem. B 110, 13393 (2006).

    Article  CAS  PubMed  Google Scholar 

  6. R. Reske, H. Mistry, F. Behafarid, et al., J. Am. Chem. Soc. 136, 6978 (2014).

    Article  CAS  PubMed  Google Scholar 

  7. B. R. Cuenya, Thin Solid Films, 518, 3127 (2010).

    Article  CAS  Google Scholar 

  8. M. Haruta, J. New Mater. Electrochem. Syst. 7, 163 (2004).

    CAS  Google Scholar 

  9. H. A. Al-Wadhaf, V. M. Karpov, and E. A. Katsman, Catal. Commun. 116, 67 (2018).

    Article  CAS  Google Scholar 

  10. A. S. Berenblyum, T. A. Podoplelova, E. A. Katsman, et al., Kinet. Catal. 53, 595 (2012).

    Article  CAS  Google Scholar 

  11. E. A. Katsman, V. Ya. Danyushevsky, P. S. Kuznetsov, et al., Pet. Chem. 57, 1190 (2017).

    Article  CAS  Google Scholar 

  12. A. S. Berenblyum, L. I. Lakhman, I. I. Moiseev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1287 (1975).

  13. E. A. Katsman, O. B. Vetrova, and F. D. Klebanova, Khim. Prom-st., No. 4, 210 (1998).

  14. J. D. Hanawalt, H. W. Rinn, and L. K. Frevel, Ind. Eng. Chem. 10, 457 (1938).

    CAS  Google Scholar 

  15. V. I. Bukhtiyarov and M. G. Slin’ko, Russ. Chem. Rev. 70, 167 (2001).

    Article  CAS  Google Scholar 

  16. V. Ya. Danyushevsky, V. Yu. Murzin, P. S. Kuznetsov, et al., Russ. J. Phys. Chem. A 92, 66 (2018).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Fine Chemical Technologies (Moscow Technological University), Moscow, Russia

    E. A. Katsman, V. Ya. Danyushevsky, V. M. Karpov, P. S. Kuznetsov, O. N. Shishilov & A. S. Berenblyum

Authors
  1. E. A. Katsman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Ya. Danyushevsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Karpov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. S. Kuznetsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. N. Shishilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. S. Berenblyum
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. A. Katsman.

Additional information

Translated by M. Timoshinina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Katsman, E.A., Danyushevsky, V.Y., Karpov, V.M. et al. The Effect of the Active Component Content on the Catalytic Activity of Nickel Sulfide Catalysts in Olefin Synthesis from Stearic Acid. Pet. Chem. 59, 622–628 (2019). https://doi.org/10.1134/S0965544119060112

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544119060112

Keywords:

Search

Navigation