Skip to main content
SpringerLink
Log in

Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The interaction of 2-monosubstituted 1,3-dioxolanes with 3-hexyl-1-ethylaluminacyclopentane leads to the cleavage of the Al–C bond of the metallocycle and the formation of ethylene glycol monoethers after hydrolysis of the resulting reaction mixture. Catalytic amounts of ZrCl4 or Ni(acac)2 activate the process. The reaction of 2-monosubstituted 1,3-dioxolanes with 1-ethyl-3-naphthylaluminacyclopentane yields the product of cleavage of the exocyclic Al–Et bond of aluminacyclopentane.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. S.-M. Yeh, H. Lee. Y. Wang, and T.-Y. Luh, J. Org. Chem. 62, 8315 (1997).

    Article  CAS  PubMed  Google Scholar 

  2. T. F. Dekhtyar’, O. S. Vostrikova, and S. S. Zlotskii, Bashkir. Khim. Zh. 16 (1), 52 (2009).

    Google Scholar 

  3. O. S. Vostrikova, T. F. Dekhtyar’, and S. S. Zlotskii, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 48 (5), 157 (2005).

    CAS  Google Scholar 

  4. T. F. Dekhtyar’, O. S. Vostrikova, and S. S. Zlotskii, Bashkir. Khim. Zh. 10 (3), 38 (2003).

    Google Scholar 

  5. U. M. Dzhemilev, A. G. Ibragimov, and A. P. Zolotarev, Izv. Akad. Nauk SSSR, Ser. Khim., No. 1, 207 (1989).

  6. M. Renoll and M. S. Newmann, in Organic Synthesis (Wiley, New York, 1955), Vol. 3, p. 502.

    Google Scholar 

  7. Beilstein’s Handbook of Organic Chemistry, Ed. by R. Luckenbach (Springer, New York, 1987), Vol. 19, Chs. 1, 6.

    Google Scholar 

  8. Yu. T. Gafarova, Extended Abstract of Candidate’s Dissertation in Chemistry (Ufa, 2001).

  9. T. F. Dekhtyar’, E. F. Dekhtyar’, O. S. Vostrikova, et al., Russ. J. Gen. Chem. 74, 903 (2004).

    Article  Google Scholar 

  10. O. S. Vostrikova, Yu. T. Gafarova, V. A. Dokichev, and S. S. Zlotskii, Izv. Akad. Nauk, Ser. Khim., No. 8, 1550 (1999).

  11. Yu. T. Gafarova, E. F. Dekhtyar’, T. F. Dekhtyar’, et al., Izv. Akad. Nauk, Ser. Khim., 951 (2003).

  12. E. F. Dekhtyar’, T. F. Dekhtyar’, O. S. Vostrikova, and S. S. Zlotskii, Bashkir. Khim. Zh. 16 (2), 93 (2009).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Bashkir State University, Sterlitamak Branch, 453103, Sterlitamak, Bashkortostan, Russia

    T. F. Dekhtyar’ & A. A. Bogomazova

  2. Ufa State Petroleum Technological University, 450062, Ufa, Bashkortostan, Russia

    O. S. Vostrikova, S. S. Zlotskii & N. N. Mikhailova

Authors
  1. T. F. Dekhtyar’
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Vostrikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. S. Zlotskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Bogomazova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. N. Mikhailova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. F. Dekhtyar’.

Additional information

Translated by E. Boltukhina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dekhtyar’, T.F., Vostrikova, O.S., Zlotskii, S.S. et al. Interaction of 2-Monosubstituted 1,3-Dioxolanes with Aluminacyclopentanes. Pet. Chem. 59, 650–655 (2019). https://doi.org/10.1134/S0965544119060082

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544119060082

Keywords:

Search

Navigation