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Platinum Catalysts Supported on Iron-Pillared Sodium- and Calcium-Saturated Montmorillonite in n-Hexane Isomerization

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Abstract

The activity of 0.1%Pt and 0.35%Pt catalysts supported on iron-pillared Na- and Ca-saturated montmorillonite has been tested in the n-hexane isomerization reaction. It has been found that a decrease in the platinum content to 0.1% leads to the formation of high amounts of diisomeric hexanes and heptanes. The activity of the catalysts has been correlated with their physicochemical characteristics determined by the BET, ammonia TPD, electron microscopy, and Mossbauer spectroscopy methods. The high strength of the proposed catalysts, high yields of C6 and C7 di- and tri-isomers from n-hexane in the presence of catalysts with a low Pt content, the use of available and cheap natural materials, and a fairly high n-hexane conversion suggest that these catalysts can be used in the isomerization of low-octane light naphtha to high-octane isomers.

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REFERENCES

  1. E. A. Yasakova, A. V. Sitdikova, and A. F. Akhmetov, Neftegaz. Delo, No. 1, 1 (2010).

    Google Scholar 

  2. V. K. Smirnov, E. L. Talisman, and V. M. Kapustin, Neftepererab. Neftekhim., No. 2, 14 (2005).

  3. A. V. Kostenko, M. M. Goev, E. V. Ferkel’, et al., Neftepererab. Neftekhim., No. 2, 58 (2006).

  4. A. Hollo, J. Hancsot, and D. Kallo, Appl. Catal., A 229, 93 (2002).

  5. C. Y. Chen, X. Quyang, S. I. Zones, et al., Microporous Mesoporous Mater. 164, 71 (2012).

    Article  CAS  Google Scholar 

  6. O. S. Travkina, R. Z. Kuvatova, I. N. Pavlova, and A. K. Ramadan, Pet. Chem. 56, 41 (2016).

    Article  CAS  Google Scholar 

  7. A. K. Sinha and S. Sivasanker, Catal. Today 49, 293 (1999).

    Article  CAS  Google Scholar 

  8. S. V. Konnov, V. L. Sushkevich, Yu. V. Monachova, et al., Studies in Surface Science and Catalysts, vol. 174: Zeolites and Related Materials: Trends, Targets and Challenges, Ed. by A. Gédéon, P. Massiani, and F. Babonneau (Elsevier, Amsterdam, 2008), Part B, p. 1167.

  9. P. N. Kuznetsov, V. P. Tverdokhlebov, L. I. Kuz-netsova, et al., Zh. Sib. Fed. Univ.: Ser. Tekh. Tekhnol., No. 4, 438 (2011).

  10. M. D. Smolikov, K. V. Kazantsev, E. V. Zatolokina, et al., Kinet. Catal. 51, 584 (2010).

    Article  CAS  Google Scholar 

  11. G. A. Urzhuntsev and G. V. Echevskii, Katal. Prom-sti. 18 (1), 60 (2018).

    Google Scholar 

  12. G. D. Yadav and J. J. Nair, Microporous Mesoporous Mater. 33, 1 (1999).

    Article  CAS  Google Scholar 

  13. T. Yamoguchi, Appl. Catal., A 222, 237 (2001).

  14. R. Issaadi, F. Garin, and Ch. E. Chitour, Catal. Today 113, 174 (2006).

    Article  CAS  Google Scholar 

  15. R. Issaadi, F. Garin, Ch. E. Chitour, and G. Maire, Appl. Catal., A 207, 323 (2001).

  16. R. Issaadi and F. Garin, Appl. Catal., A 243, 367 (2003).

  17. N. A. Zakarina, M. M. Malimbaeva, and G. V. Akulova, Dokl. Natl. Akad. Nauk Rep. Kaz., No. 1, 12 (2009).

  18. S. Balsi, E. Gokcay, and Ch. E. Chitour, Turk. J. Chem. 33, 843 (2009).

    Google Scholar 

  19. M. Akcay, Appl. Catal., A 294, 156 (2005).

  20. A. Moronto, T. Obeto, G. Carruyo, et al., Appl. Catal., A 334, 173 (2008).

  21. M. N. Timofeeva, S. Ts. Khankhasaeva, Yu. A. Chesalov, et al., Appl. Catal., B 88, 127 (2009).

    Article  CAS  Google Scholar 

  22. A. V. Abramova, E. V. Slivinskii, Yu. Ya. Gol’dfarb, et al., Kinet. Catal. 46, 758 (2005).

    Article  CAS  Google Scholar 

  23. A. K. Akurpekova, L. D. Volkova, and N. A. Zakarina, Izv. Natl. Akad. Nauk Rep. Kaz., Ser. Khim., No. 2, 9 (2009).

  24. N. A. Zakarina, O. K. Kim, L. D. Volkova, et al., in Proceedings of XII European Congress on Catalysis “EuropaCat-XII” (Kazan, 2015), p. 144.

  25. N. A. Zakarina, A. R. Brodskii, V. A. Yaskevich, et al., Proceedings of XIV International Conference “Mössbauer Spectroscopy and Its Application” ICMSA-2016 (Kazan, 2016), p. 142.

  26. V. G. Kazanskii, Zh. Fiz. Khim. 59, 1057 (1985).

    CAS  Google Scholar 

  27. M. D. Smolikov, V. B. Goncharov, E. M. Sadovskaya, et al., Catal. Ind. 6, 134 (2014).

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors thank A.R. Brodskii, L.V. Komashko, and V.I. Yaskevich for recording and interpreting the electron and Mossbauer spectroscopy data. This work was supported in part by a grant of the Ministry of Education and Science of the Republic of Kazakhstan (project no. АР05132064).

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Authors and Affiliations

  1. Sokol’skii Institute of Fuel, Catalysis, and Electrochemistry, Almaty, Republic of Kazakhstan

    N. A. Zakarina, O. K. Kim, L. D. Volkova & D. A. Zhumadullaev

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  1. N. A. Zakarina
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  2. O. K. Kim
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  3. L. D. Volkova
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  4. D. A. Zhumadullaev
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Correspondence to O. K. Kim.

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Translated by M. Timoshinina

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Zakarina, N.A., Kim, O.K., Volkova, L.D. et al. Platinum Catalysts Supported on Iron-Pillared Sodium- and Calcium-Saturated Montmorillonite in n-Hexane Isomerization. Pet. Chem. 58, 841–848 (2018). https://doi.org/10.1134/S0965544118100183

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