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Butane–butylene fraction cracking over modified ZSM-5 zeolite

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Abstract

The effect of temperature (530–590°C), weight hourly space velocity (2.5–7.0 h–1), and the Si/Al ratio of the ZSM-5 zeolite (30, 55, 80, 300) on the cracking of a butane–butylene fraction containing 85 wt % butylenes has been studied. The HZSM-5 zeolite has been modified with phosphorus. The effect of modification on the catalyst activity in cracking reactions has been studied. The ethylene and propylene yield achieves 38.4 wt % at a degree of conversion of butylenes of 81.5%. The ethylene to propylene ratio is 0.55.

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Authors and Affiliations

  1. Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia

    E. O. Altynkovich, O. V. Potapenko, T. P. Sorokina, V. P. Doronin, T. I. Gulyaeva & V. P. Talzi

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  1. E. O. Altynkovich
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  2. O. V. Potapenko
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  3. T. P. Sorokina
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  4. V. P. Doronin
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  5. T. I. Gulyaeva
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  6. V. P. Talzi
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Correspondence to E. O. Altynkovich.

Additional information

Original Russian Text © E.O. Altynkovich, O.V. Potapenko, T.P. Sorokina, V.P. Doronin, T.I. Gulyaeva, V.P. Talzi, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 2, pp. 156–162.

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Altynkovich, E.O., Potapenko, O.V., Sorokina, T.P. et al. Butane–butylene fraction cracking over modified ZSM-5 zeolite. Pet. Chem. 57, 215–221 (2017). https://doi.org/10.1134/S0965544117010030

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  • DOI: https://doi.org/10.1134/S0965544117010030

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