Skip to main content
SpringerLink
Log in

Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Nickel–tungsten sulfide catalysts for the hydrogenation and hydrodesulfurization of aromatic hydrocarbons are synthesized by the in situ decomposition of thio salts using different methods: the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in an ionic liquid, the in situ decomposition of a [BMPip]2Ni(WS4)2 precursor in a hydrocarbon feedstock, the in situ breaking of a SPAN-80 surfactant-stabilized suspension of solid Ni/(NH4)2WS4 precursor particles in a hydrocarbon feedstock, and the decomposition of oil-soluble precursors (tungsten hexacarbonyl and nickel(II) 2-ethylhexanoate) in a hydrocarbon feedstock. The resulting catalysts are characterized by X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy; their catalytic activity is studied in a batch reactor using the example of the hydrofining of light cycle oils with different compositions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Stratiev, D., Shishkova, I., Obryvalina, A.N., and Telyashev, R.G., Mir Nefteprod., 2011, vol. 2, p. 16.

    Google Scholar 

  2. EN (European Standard) 590:2010, Automotive fuels— Diesel—Requirements and Test Methods, 2010.

  3. Stanislaus, A., Marafi, A., and Rana, M.S., Catal. Today, 2010, vol. 153, nos. 1–2, p. 1.

    Article  CAS  Google Scholar 

  4. Toulhoat, H. and Raybaund, P., Catalysis by Transition Metal Sulphides: From Molecular Theory to Industrial Application, Editions Technip, 2013.

    Google Scholar 

  5. Song, Ch. and Ma, X., Appl. Catal., B, 2003, vol. 41, p. 207.

    Article  Google Scholar 

  6. Kapustin, V.M. and Gureev, A.A., Tekhnologiya pererabotki nefti (Oil Refining Technology), part 2: Destruktivnye protsessy (Destructive Processes), Moscow: KolosS, 2007.

    Google Scholar 

  7. Yi, Y., Jin, X., Wang, L., Zhang, Q., Xiong, G., and Liang, C., Catal. Today, 2011, vol. 175, p. 460.

    Article  CAS  Google Scholar 

  8. Olivas, A., Zepeda, T.A., Villalpando, I., and Fuentes, S., Catal. Commun., 2008, vol. 9, p. 1317.

    Article  CAS  Google Scholar 

  9. Zdrazil, M., Catal. Today, 1988, vol. 3, p. 269.

    Article  CAS  Google Scholar 

  10. Wilkinson, K., Merchan, M.D., and Vasudevan, P.T., J. Catal., 1997, vol. 171, p. 325.

    Article  CAS  Google Scholar 

  11. Cornils, B. and Herrmann, W.A., Applied Homogeneous Catalysis with Organometallic Compounds, Weinheim: VCH, 2002.

    Book  Google Scholar 

  12. Scholten, J.D., Leal, B.C., and Dupont, J., ACS Catal., 2012, vol. 2, p. 184.

    Article  CAS  Google Scholar 

  13. Voggu, R., Shireen, A., and Rao, C.N.R., Dalton Trans., 2010, vol. 39, p. 6021.

    Article  CAS  Google Scholar 

  14. Desset, S.L., Hintermair, U., Gong, Zh., Santini, C.C., and Cole-Hamilton, D.J., Top. Catal., 2010, vol. 53, nos. 13–14, p. 963.

    Article  CAS  Google Scholar 

  15. Taubert, A. and Li, Z., Dalton Trans., 2007, p. 1477.

    Google Scholar 

  16. Ding, K.L., Miao, Z.J., Liu, Z.J., Zhang, Z.F., Han, B.X., An, G.M., Miao, S.D., and Xie, Y., J. Am. Chem. Soc., 2007, vol. 129, p. 6362.

    Article  CAS  Google Scholar 

  17. Kowsari, E., The design of nanoscale inorganic materials with controlled size and morphology by ionic liquids, in Ionic Liquids: Theory, Properties, New Approaches, Kokorin, A., Ed., Croatia: InTech, 2011, p. 511.

    Google Scholar 

  18. Lau, V.W.-H., Masters, A.F., Bond, A.M., and Maschmeyer, T., Chem.- Eur. J., 2012, vol. 18, p. 8230.

    Article  CAS  Google Scholar 

  19. Yim, T., Lee, H.Y., Kim, H.-J., Mun, J., Kim, S., Oh, S.M., and Kim, Y.G., Bull. Korean Chem. Soc., 2007, vol. 28, p. 1567.

    Article  CAS  Google Scholar 

  20. McDonald, W., Friesen, G.D., Rosenhein, L.D., and Newton, W.E., Inorg. Chim. Acta, 1983, vol. 72, p. 205.

    Article  CAS  Google Scholar 

  21. Sizova, I.A., Serdyukov, S.I., Maksimov, A.L., and Sinikova, N.A., Pet. Chem., 2015, vol. 55, no. 1, p. 38.

    Article  CAS  Google Scholar 

  22. Sizova, I.A., Serdyukov, S.I., and Maksimov, A.L., Pet. Chem., 2015, vol. 55, no. 6, p. 468.

    Article  Google Scholar 

  23. Sizova, I.A., Serdyukov, S.I., and Maksimov, A.L., Pet. Chem., 2016, vol. 56, no. 2, p. 131.

    Article  CAS  Google Scholar 

  24. Sizova, I.A., Kulikov, A.B., Onishchenko, M.I., Serdyukov, S.I., and Maksimov, A.L., Pet. Chem., 2016, vol. 56, no. 1, p. 44.

    Article  CAS  Google Scholar 

  25. Jin, X., Ma, C., Yi, Y., Zhang, Q., Qiu, J., and Liang, C., J. Phys. Chem. Solids, 2010, vol. 71, p. 642.

    Article  CAS  Google Scholar 

  26. Tayeb, K., Lamonier, C., Lancelot, C., Fournier, M., Payen, E., Bonduelle, A., and Bertonici, F.P.A., Catal. Today, 2010, vol. 150, nos. 3–4, p. 207.

    Article  Google Scholar 

  27. Vrinat, M., Nie, H., Mauge, F., Shi, Y., Lacroix, M., and Li, D., Catal. Today, 2004, vols. 93–95, p. 751.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    I. A. Sizova & A. L. Maksimov

  2. Department of Chemistry, Moscow State University, Moscow, Russia

    A. L. Maksimov

Authors
  1. I. A. Sizova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Maksimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Sizova.

Additional information

Original Russian Text © I.A. Sizova, A.L. Maksimov, 2016, published in Nanogeterogennyi Kataliz, 2016, Vol. 1, No. 1, pp. 50–62.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sizova, I.A., Maksimov, A.L. Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts. Pet. Chem. 56, 510–521 (2016). https://doi.org/10.1134/S0965544116060098

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544116060098

Keywords

Search

Navigation