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Morphology, Mineralogy, and Composition of Sulfide Droplets in Picrodolerite from a Near-Bottom Apophysis of the Yoko-Dovyren Layered Intrusion

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Abstract

The paper presents data on sulfide globules in picrodolerites from a bottom apophysis of the Yoko-Dovyren massif, northern Transbaikalia. Textural features of the rocks indicate that they crystallized at rapid magma cooling. Their composition is similar to that of chilled olivine gabbronorites from the lower contact of the massif. Many droplet-shaped sulfides, which range from 2 to 15 mm, were identified in one of the samples using X-ray computed tomography. The largest of these globules was drilled out and studied in detail to clarify its inner structure, which consists of the main spheroid and a surrounding halo of disseminated sulfides. The main globule and surrounding halo significantly differ in composition (the halo is richer in Cu), as was calculated using the average compositions of the dominant sulfide phases and their relative proportions. The weighted mean (with regard for halo) composition can be assumed as an approximation of the composition of the initial sulfide liquid that was formed near the chill zone of the gabbronorite apophysis from the main intrusive chamber. The Cu content in the initial sulfide corresponds to the results of thermodynamic modeling (with the COMAGMAT-5 program package) of the geochemistry of primitive sulfides in ultramafite rocks from the basal zone of the massif. The differences in the composition of the halo and the main globule indicate the possibility of local migration (within a few millimeters) of the residual sulfide liquids enriched in Cu when the protosulfide melt differentiated. As a physical mechanism that produced the halo, we assumed that the latest sulfide fraction was pressed off into the pore space of rapidly crystallizing olivine orthocumulates.

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Notes

  1. Connectivity is calculated as the vol % of the largest object of the total volume of a given X-ray contrasting component (Korost et al., 2019).

REFERENCES

  1. Ariskin, A.A., Konnikov, E.G., Danyushevsky, L.V., et al., The Dovyren intrusive complex: problems of petrology and ni sulfide mineralization, Geochem. Int., 2009, vol. 47, no. 5, pp. 425–453.

    Article  Google Scholar 

  2. Ariskin, A.A., Konnikov, E.G., Danyushevsky, L.V., et al., Geochronology of the Dovyren intrusive complex, northwestern Baikal Area, Russia, in the Neoproterozoic, Geochem. Int., 2013, no. 11, pp. 859–875.

    Article  Google Scholar 

  3. Ariskin, A.A., Danyushevsky, L.V., Bychkov, K.A., et al., Modeling solubility of Fe–Ni sulfides in basaltic magmas: the effect of Ni in the melt, Econ. Geol., 2013, vol. 108, no. 8, pp. 1983–2003.

    Article  Google Scholar 

  4. Ariskin, A.A., Danyushevsky, L.V., Konnikov, E.G., et al., The Dovyren intrusive complex (northern Baikal region, Russia): isotope-geochemical markers of contamination of parental magmas and extreme enrichment of source, Russ. Geol. Geophys., 2015, vol.56, no. 3, pp. 411–434.

    Article  Google Scholar 

  5. Ariskin, A.A., Kislov, E.V., Danyushevsky, L.V., et al., Cu–Ni–PGE fertility of the Yoko-Dovyren layered massif (northern Transbaikalia, Russia): thermodynamic modeling of sulfide compositions in low mineralized dunites based on quantitative sulfide mineralogy, Miner. Deposita, 2016, vol. 51, pp. 993–1011.

    Article  Google Scholar 

  6. Ariskin, A.A., Bychkov, K.A., and Nikolaev, G.S., Modeling of trace-element composition of sulfide liquid in a crystallizing basalt magma: development of the R-Factor concept, Geochem. Int., 2017, vol. 55, no. 5, pp. 465–473.

    Article  Google Scholar 

  7. Ariskin, A.A., Danyushevsky, L., Nikolaev, G., et al., The Dovyren intrusive complex (southern Siberia, Russia): insights into dynamics of an open magma chamber with implications for parental magma origin, composition, and Cu–Ni–PGE fertility, Lithos, 2018a, vol. 302–303, pp. 242–262.

    Article  Google Scholar 

  8. Ariskin, A.A., Nikolaev, G.S., Danyushevsky, L.V., et al., Genetic interpretation of the distribution of PGE and chalcogens in sulfide-mineralized rocks from the Yoko-Dovyren layered intrusion, Geochem. Int., 2018b, vol. 56, no. 13, pp. 1322–1340.

    Article  Google Scholar 

  9. Baker, D.R. and Moretti, R., Modeling the solubility of sulfur in magmas: a 50-year old geochemical challenge, Rev. Mineral. Geochem., 2011, vol. 73, pp. 167–213.

    Article  Google Scholar 

  10. Barnes, S-J. and Lightfoot, P.C., Formation of magmatic nickel–sulfide ore deposits and processses affecting their copper and platinum-group element contents, Hedenquist, J.W., Thompson, J.F.H., Goldfarb, R.J., and Richards, J.P., Eds., Econ. Geol., 2005, vol. 100, pp. 179–213

  11. Barnes, S.-J., Cox, R., and Zientek, M., Platinum-group element, gold, silver and base metal distribution in compositionally zoned sulfide droplets from the Medvezky Creek Mine, Noril’sk, Russia, Contrib. Mineral. Petrol., 2006, vol. 152, pp. 187–200.

    Article  Google Scholar 

  12. Barnes, J.S., Le Vaillant, M., Godel, B., and Lesher, C.M., Droplets and bubbles: solidification of sulphide-rich vapour-saturated orthocumulates in the Norilsk–Talnakh Ni–Cu–PGE ore-bearing intrusions, J. Petrol., 2019, vol. 60, pp. 1–31.

    Article  Google Scholar 

  13. Barnes, S.J., Fiorentini, M.L., Austin, P., et al., Three-dimensional morphology of magmatic sulfides sheds light on ore formation and sulfide melt migration, Geology, 2008, vol. 36, pp. 655–658.

    Article  Google Scholar 

  14. Barnes, S.J., Cruden, A.R., Arndt, N., and Saumur, B.M., The mineral system approach applied to magmatic Ni–Cu–PGE sulphide deposits, Ore Geol. Rev., 2016, vol. 76, pp. 296–316.

    Article  Google Scholar 

  15. Barnes, J.S. Mungall, J.E., and Le Vaillant, M., et al., Sulfide–silicate textures in magmatic Ni–Cu–PGE sulfide ore deposits: disseminated and net-textured ores, Am. Mineral., 2017, vol. 102, pp. 473–506.

    Article  Google Scholar 

  16. Boudreau, A., Hydromagmatic Processes and Platinum-Group Element Deposits in Layered Intrusions, Cambridge University Press, 2019.

    Book  Google Scholar 

  17. Campbell, I.H. and Naldrett, A.J., The influence of silicate:sulfide ratios on the geochemistry of magmatic sulfides, Econ. Geol., 1979, vol. 74, no. 6, pp. 1503–1506.

    Article  Google Scholar 

  18. Christa, H-M. and Couderc, J-J., TEM study of mechanical twinning in experimentally deformed chalcopyrite (CuFeS2) single crystals, Europ. J. Mineral., 1989, vol. 1, no. 2, pp. 295–314.

    Article  Google Scholar 

  19. Chung, H.-Y. and Mungall, J.E., Physical constraints on the migration of immiscible fluids through partially molten silicates, with special reference to magmatic sulfide ores, Earth Planet. Sci. Lett., 2009, vol. 286, pp. 14–22.

    Article  Google Scholar 

  20. Czamanske, G.K., Kunilov, V.E., Zientek, M.L., et al., A proton microprobe study of magmatic sulfide ores from the Noril’sk–Talnakh district, Siberia, Can. Mineral., 1992, vol. 30, pp. 249–287.

    Google Scholar 

  21. Distler, V.V. and Stepin, A.G., Low-sulfide PGE-bearing horizon of the Yoko–Dovyren layered mafic-ultramafic intrusion (Northern Baikal Region),Dokl. Akad. Nauk, 1993, vol. 328, no. 4, pp. 498–501.

    Google Scholar 

  22. Duran, C.J., Barnes, S-J., Pleše, P., et al., Fractional crystallization-induced variations in sulfides from the Noril’sk–Talnakh mining district (Polar Siberia, Russia), Ore Geol. Rev., 2007, vol. 90, pp. 326–351.

    Article  Google Scholar 

  23. Ebel, D.S. and Naldrett, A.J., Fractional crystallization of sulfide ore liquids at high temperature, Econ. Geol., 1996, vol. 91, pp. 607–621.

    Article  Google Scholar 

  24. Ernst, R.E., Hamilton, M.A., Soderlund, U., et al., Long-lived connection between southern siberia and northern laurentia in the Proterozoic, Nature Geosci., 2016, vol. 9, pp. 464–469.

    Article  Google Scholar 

  25. Fleet, M.E., Phase equilibria at high temperatures, Rev. Mineral. Geochem., 2006, vol. 61, pp. 365–419.

    Article  Google Scholar 

  26. Fortin, M.-A., Riddle, J., Desjardins-Langlais, Y., and Baker, D.R., The effect of water on the sulfur concentration at sulfide saturation (SCSS) in natural melts, Geochim. Cosmochim. Acta, 2015, vol. 160, pp. 100–116.

    Article  Google Scholar 

  27. Francis, R.D., Sulfide globules in mid-ocean ridge basalts (MORB) and the effect of oxygen abundance in Fe–S–O liquids on the ability of those liquids to partition metals from MORB and komatiitic magmas, Chem. Geol., 1990, vol. 85, pp. 199–213.

    Article  Google Scholar 

  28. Godel, B., Barnes, S.-J., and Maier, W.D., 3-D distribution of sulfide minerals in the Merensky Reef (Bushveld Complex, South Africa) and the J-M reef (Stillwater Complex, USA) and their relationship to microstructures using x-ray computed tomography, J. Petrol., 2006, vol. 47, pp. 1853–1872.

    Article  Google Scholar 

  29. Holwell, D.A. and McDonald, I., A review of the behavior of platinum group elements within natural magmatic sulfide ore systems. The importance of semimetals in governing partitioning behavior, Platinum Metals Rev., 2010, vol. 54, no. 1, pp. 26–36.

    Article  Google Scholar 

  30. Holwell, D.A. and Keays, R.R., The formation of low-volume, high-tenor magmatic PGE–Au sulfide mineralization in closed systems: evidence from precious and base metal geochemistry of the Platinova Reef, Skaergaard intrusion, East Greenland, Econ. Geol., 2014, vol. 109, pp. 387–406.

    Article  Google Scholar 

  31. Holwell, D.A. Barnes, S.J., and Le Vaillant, M., et al., 3D textural evidence for the formation of ultra-high tenor precious metal bearing sulphide microdroplets in offset reefs: an extreme example from the Platinova Reef, Skaergaard intrusion, Greenland, Lithos, 2016, vol. 256-257, pp. 55–74.

    Article  Google Scholar 

  32. Kacharovskaya, L.N., Sulfide copper–nickel ores of the Yoko–Dovyren layered pluton (compositions and conditions of formation), Extended Abstract of Candidate (Geol.-Min.) Dissertation, Ulan-Ude: GI BNTs, 1986.

  33. Kislov, E.V., Ioko-Dovyrenskii rassloennyi massiv (Yoko–Dovyren Layered Massif), Ulan-Ude: Izd-vo Buryatskogo nauchnogo tsentra, 1998.

  34. Konnikov, E.G., Differentsirovannye giperbazit-bazitovye kompleksy dokembriya Zabaikal’ya (Precambrian Differentiated Ultramafic–Mafic Complexes of Transbaikalia), Novosibirsk: Nauka, 1986.

  35. Korost, D.V., Ariskin, A.A., Pshenitsyn, I.V., and Khomyak, A.N., X-Ray computed tomography as a method for reproducing 3D characteristics of sulfides and spinel disseminated in plagiodunites from the Yoko-Dovyren intrusion, Petrology, 2019, vol. 27, no. 4, pp. 370–385.

    Article  Google Scholar 

  36. Krivolutskaya, N.A., Gongalsky, B.I., Kedrovskaya, Т.В., et al., Geology of the western flanks of the Oktyabr’skoe deposit, Noril’sk District, Russia: evidence of a closed magmatic system, Miner. Deposita, 2018, vol. 54, pp. 611–630. https://doi.org/10.1007/s00126-018-0827-z

    Article  Google Scholar 

  37. Kullerud, G., Yund, R.A., and Moh, G.H., Phase relations in the Cu–Fe–S, Cu–Ni–S, and Fe–Ni–S systems, Econ. Geol. Monogr., 1969, vol. 4, pp. 323–343.

    Google Scholar 

  38. Le Vaillant, M., Barnes, S.J., Mungall, J.E., and Mungall, E., Role of de-gassing of the Noril’sk nickel deposits in the Permo-Triassic mass extinction event, Proc. National Academy Sci., 2017, vol. 114, pp. 2485–2490.

    Article  Google Scholar 

  39. Likhachev, A.P., Platino-medno-nikelevye i platinovye mestorozhdeniya (Platinum–Cooper–Nickel and Platinum Deposits), Moscow: Eslan, 2006.

  40. Mungall, J.E., Late-stage sulfide liquid mobility in the main mass of the Sudbury igneous complex: examples from the Victor Deep, McCreedy East, and Trillabelle deposits, Econ. Geol., 2002, vol. 97, pp. 1563–1576.

    Article  Google Scholar 

  41. Mungall, J.E. and Su, S., Interfacial tension between magmatic sulfide and silicate liquids: constraints on kinetics of sulfide liquation and sulfide migration through silicate rocks, Earth Planet. Sci. Lett., 2005, vol. 234, pp. 135–149.

    Article  Google Scholar 

  42. Mungall, J.E. and Brenan, J.M., Partitioning of platinum-group elements and Au between sulfide liquid and basalt and the origins of mantle–crust fractionation of the chalcophile elements, Geochim. Cosmochim. Acta, 2014, vol. 125, pp. 265–289.

    Article  Google Scholar 

  43. Naldrett, A.J., Magmatic Sulfide Deposits: Geology, Geochemistry and Exploration, Heidelberg-Berlin: Springer-Verlag, 2004.

    Book  Google Scholar 

  44. Naldrett, A.J., Fundamentals of magmatic sulfide deposits, magmatic Ni-Cu and PGE deposits, Geology, Geochemistry and Genesis:Reviews in Economic Geology, Li C. and Ripley, E.M., Eds. Soc. Econom. Geol., 2011, vol. 17, pp. 1–50.

    Google Scholar 

  45. Naldrett, A.J., Hewins, R.H., Dressler, B.O., and Rao, B.V., The contact sublayer of the Sudbury igneous complex, The Geology and Ore Deposits of the Sudbury Structure, Pye, E.G., Naldrett, A.J., and Giblin, P.E., Eds., Ontario Geol. Surv. Spec., 1984, vol. 1, pp. 253–274.

    Google Scholar 

  46. Novikov, G.V., Pirrotiny: kristallicheskaya i magnitnaya struktura, fazovye prevrashcheniya (Pyrrhotite: Crystalline and Magnetic Structure, Phase Transformations), Moscow: Nauka, 1988.

  47. Orsoev, D.A., Mekhonoshin, A.S., Kanakin, S.V., et al., Gabbro-peridotite sills of the Late Riphean Dovyren plutonic complex (northern Baikal area, Russia), Russ. Geol. Geophys., 2018, vol. 59, no. 5, pp. 472–485.

    Article  Google Scholar 

  48. Patten, C., Barnes, S.-J., Mathez, E.A., and Jenner, F.E., Partition coefficients of chalcophile elements between sulfide and silicate melts and the early crystallization history of sulfide liquid: La-ICP-MS analysis of MORB sulfide droplets, Chem. Geol., 2013, vol. 358, pp. 170–188.

    Article  Google Scholar 

  49. Prichard, H.M., Hutchinson, D., and Fisher, P. C., Petrology and crystallization history of multiphase sulfide droplets in a mafic dike from Uruguay: implications for the origin of Cu–Ni–PGE sulfide deposits, Econ. Geol., 2004, vol. 99, pp. 365–376.

    Article  Google Scholar 

  50. Robertson, J.C., Barnes, J.S., and Le Vaillant, M., Dynamics of magmatic sulphide droplets during transport in silicate melts and implications for magmatic sulphide ore formation, J. Petrol., 2016, vol. 56, pp. 2445–2472.

    Article  Google Scholar 

  51. Ryabov, V.V., Shevko, A.Ya., and Gora, M.P., Magmaticheskie obrazovaniya Noril’skogo raiona (Magmatic Complexes of the Norilsk Area), Novosibirsk: Nonparel’, 2001, vol. 1.

  52. Rytsk, E.Yu., Shalaev, V.S., Rizvanova, N.G., et al., The Olokit Zone of the Baikal Fold Region: new isotope-geochronological and petrogeochemical data, Geotectonics, 2002, no. 1, pp. 24–35.

  53. Sinyakova, E.F. and Kosyakov, V.I., The behavior of noble-metal admixtures during fractional crystallization of As- and Co-containing Cu–Fe–Ni–sulfide melts, Russ. Geol. Geophys., 2019, vol. 53, no. 10, pp. 1055–1078.

    Article  Google Scholar 

  54. Sinyakova, E.F., Kosyakov, V.I., and Borisenko, A.S., Effect of the presence of As, Bi, and Te on the behavior of Pt metals during fractionation crystallization of sulfide magma, Dokl. Earth Sci., 2017, vol. 477, no. 2, pp. 1422–1425.

    Article  Google Scholar 

  55. Sluzhenikin, S.F., Distler, V.V., Dyuzhikov, O.A., et al., Low-sulfide platinum mineralization in the Norilsk differentiated intrusions, Geol. Rudn. Mestorozhd., 1994, vol. 36, no. 3, pp. 195–217.

    Google Scholar 

  56. Spiridonov, E.M., Ore-magmatic systems of the Noril’sk ore field, Russ. Geol. Geophys., 2010, vol. 51, pp. 1059–1077.

    Article  Google Scholar 

  57. Spiridonov, E.M., Orsoev, D.A., Ariskin, A.A., et al., Hg- and Cd-bearing Pd, Pt, Au, and Ag minerals in sulfide-bearing mafic and ultramafic rocks of the Yoko-Dovyren Intrusion in the Baikalides of the Northern Baikal Area, Geochem. Int., 2019, vol. 64, no. 1, pp. 42–55.

    Article  Google Scholar 

  58. Taylor, L.A. and Finger, L.W., Structural refinement and composition of mackinawite, Carnegie Inst. Washington, Geophysical Laboratory Annual Report, 1970, vol. 69.

  59. Tolstykh, N.D., Orsoev, D.A., Krivenko, A.P., and Izokh, A.E., Blagorodnometall’naya mineralizatsiya v rassloennykh ul’trabazit-bazitovykh massivakh yuga Sibirskoi platformy (Noble-Metal Mineralization in Layered Ultramafic–Mafic Massifs of the Southern Siberian Platform), Novosibirsk: Parallel’, 2008.

  60. Tsujimura, T. and Kitakaze, A., New phase relations in the Cu–Fe–S system at 800oC; constraint of fractional crystallization of a sulfide liquid, N. Jb. Mineral. Mh, 2004, vol. 10, pp. 433–444.

    Article  Google Scholar 

  61. Vishnevskiy, A.V. and Cherdantseva, M.V., Merenskyite and other precious metal minerals in sulfide blebs from the Rudniy ultramafic-mafic intrusion, northwest Mongolia, Can. Mineral., 2016, vol. 54, pp. 519–535.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The authors thank N.N. Korotaeva and E.M. Spiridonov (Moscow State University) for help with analysis and identification of sulfide phases. V.A. Turkov and K.M. Ryazantsev (Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences) are thanked for manufacturing polished sections of our samples and samples for X-ray tomography study. Informative comments and valuable recommendations were provided by the reviewers, S.F. Sluzhenikin and M.A. Yudovskaya (Institute of the Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences) and led us to significantly improve the manuscript.

Funding

This study was supported by the Russian Science Foundation, project no. 16-17-10129. The unique thin polished sections and quantitative evaluations of the proportions of sulfides were made under a government-financed research project for the Vernadsky Institute. Analytical studies at the Laboratory of Analytical Techniques of High Spatial Resolution at the Department of Petrology, Moscow State University, were conducted on a JEOL JXA-8230 microprobe, which was purchased under the Program for the Development of the Moscow State University.

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  1. Faculty of Geology, Moscow State University, 119234, Moscow, Russia

    I. V. Pshenitsyn, A. A. Ariskin, G. S. Nikolaev, D. V. Korost, V. O. Yapaskurt & S. N. Sobolev

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry (GEOKhI), Russian Academy of Sciences, 119991, Moscow, Russia

    I. V. Pshenitsyn & A. A. Ariskin

  3. Geological Institute, Siberian Branch, Russian Academy of Sciences, 670047, Ulan-Ude, Russia

    E. V. Kislov

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  1. I. V. Pshenitsyn
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Pshenitsyn, I.V., Ariskin, A.A., Nikolaev, G.S. et al. Morphology, Mineralogy, and Composition of Sulfide Droplets in Picrodolerite from a Near-Bottom Apophysis of the Yoko-Dovyren Layered Intrusion. Petrology 28, 246–262 (2020). https://doi.org/10.1134/S0869591120030066

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