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Simulating of multicomponent diffusion at industrial-waste migration in a heterogeneously layered medium

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Abstract

In most cases, the migration of groundwater from pollution sources takes place in heterogeneous media, the storage of which is mostly determined by nearly impermeable blocks of porous rocks, while the advection takes place through canals of small storage. The exchange between the blocks and the canals is commonly described by Fick’s law for each solution component separately. Nine-component solutions at waste disposal sites at Tomsk and Dimitrovgrad are used as examples to demonstrate the effects arising at such migration and making the results to differ (sometimes, considerably) from those derived from a model of independent diffusion.

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References

  1. Kratkii spravochnik fiziko-khimicheskikh velichin (A Concise Reference Book of Physicochemical Characteristics), Mishchenko K.P. and Ravdelya, A.A., Ed., Leningrad: Khimiya, 1974.

  2. Lekhov, A.V., Fiziko-khimicheskaya gidrogeodinamika (Physicochemical Hydrodynamics), Moscow: KDU, 2010.

    Google Scholar 

  3. Lykov, A.V., Teoriya teploprovodnosti (Theory of Heat Conduction), Moscow: Vysshaya shkola, 1967.

    Google Scholar 

  4. Mulenkova, E.V., Geohydrological conditions at the disposal site of liquid radioactive wastes (LRW) at the Research Institute of Atomic Reactors (RIAR), Dimitrovgrad, Mater. Mezhdunar. nauch. konf. studentov, aspirantov i molodykh uchenykh “Lomonosov” (Mater. Intern. Sci. Conf. of Students, Postgraduates, and Young Scientists “Lomonosov”), iss. 7, Moscow: Izd. MGU, 2002, pp. 166–167.

    Google Scholar 

  5. Robinson, R. and Stoks, R., Rastvory elektrolitov (Electrolyte Solutions), Moscow: Izd. inostr. Lit., 1963.

    Google Scholar 

  6. Rybal’chenko, A.I., Pimenov, M.K., Kostin, P.P., et al., Glubinnoe zakhoronenie zhidkikh radioaktivnykh otkhodov (Deep Disposal of Liquid Radioactive Wastes), Moscow: IzdAT, 1994.

    Google Scholar 

  7. Fedorova, Yu.V., Simulation investigations of industrial waste migration in heterogeneously layered medium, Mosk. Univ. Geol. Bull., 2009, no. 2, pp. 75–78.

    Google Scholar 

  8. Felmy, A.R. and Weare, J.H., Calculation of multicomponent ionic diffusion from zero to high concentration: I. The system Na–K–Ca–Mg–Cl–SO4–H2O at 25°C, Geochim. Cosmochim. Acta, 1991, no. 1, pp. 113–131.

    Article  Google Scholar 

  9. Lasaga, A.C., The treatment of multi-component diffusion and ion-pairs in diagenetic fluxes, Am. J. Sci., 1979, vol. 279, pp. 324–346.

    Article  Google Scholar 

  10. Miller, D.G., Rard, J.A., Eppstein, L.B., and Albright, J.G., Mutual diffusion coefficients and ionic transport coefficients l ij of MgCl2–H2O at 25°C, J. Phys. Chem., 1984, vol. 88, pp. 5739–5748.

    Article  Google Scholar 

  11. Millero, F.J., The effect of pressure on the solubility of minerals in water and seawater, Geochim. Cosmochim. Acta, 1982, vol. 46, no. 1, pp. 11–22.

    Article  Google Scholar 

  12. Truesdell, A.H. and Jones, B.F., WATEQ, A computer program for calculating chemical equilibria of natural waters, J. Res., U.S. Geological Survey, 1974, vol. 2, pp. 233–274.

    Google Scholar 

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Correspondence to Yu. V. Fedorova.

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Original Russian Text © Yu.V. Fedorova, A.V. Lekhov, 2014, published in Geoekologiya. Inzhenernaya Geologiya. Gidrogeologiya. Geokriologiya, 2014, No. 2, pp. 179–187.

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Fedorova, Y.V., Lekhov, A.V. Simulating of multicomponent diffusion at industrial-waste migration in a heterogeneously layered medium. Water Resour 42, 975–982 (2015). https://doi.org/10.1134/S0097807815070040

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  • DOI: https://doi.org/10.1134/S0097807815070040

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