Abstract
SOLEX, a solid extractant for extracting metal chlorides from solutions, has been obtained by impregnating tributyl phosphate (TBP) and iodine into granulated macroporous polystyrene stitched by divinylbenzene. The sorption properties of the product are studied. The possibility of selectively extracting scandium from chloride solutions and its desorption by water are shown. This sorbent can be used for separation from REM. The value of separation coefficients of scandium/REM exceeds 1000.
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REFERENCES
Kuz’min, V.I. and Kuz’mina, A.A., RF Patent 2590550, Izobret., Polezn. Modeli, 2016, no. 19.
Kuz’min, V.I. and Kuz’mina, A.A., Scandium extraction from chloride solutions by a mixture of tributyl phosphate and molecular iodine, Theor. Found. Chem. Eng., 2018, vol. 52, pp. 701–706. https://doi.org/10.1134/S0040579518040176
Kuzmin, V.I. and Kuzmina, A.A., Specific features of scandium chloride extraction with a mixture of tributyl phosphate and molecular iodine, Russ. J. Gen. Chem., 2017, vol. 87, no. 12, pp. 2865–2869. https://doi.org/10.1134/S1070363217120179
Samoilov, Yu.M. and Isupov, V.P., RF Patent 2081831, 1997.
Korovin, V. and Shestak, Y., Scandium extraction by TVEX–DIOMP from hydrochloric media, Ukr. Chem. J., 1996, vol. 62, pp. 22–26.
Korovin, V., Randarevich, S., Pogorelov, Y., and Bodaratsky, S., Scandium extraction by tri-butylphosphate solvent and supported on TVEX polymer matrix from hydrochloric solutions based on 31P and 45Sc NMR data, Russ. J. Coord. Chem., 1996, vol. 22, pp. 633–640.
Korovin, V., Shestak, Y., and Cortina, J.L., Study of Sc and Zr extraction reactions by reactive materials containing acidic organophosphorus extractants, Proc. International Solvent Extraction Conference, Cape Town, 2002, pp. 377–383.
Korovin, V. and Shestak, Y., Scandium extraction from hydrochloric acid media by Levextrel-type resins containing di-isooctyl methyl phosphonate, Hydrometallurgy, 2009, vol. 95, nos. 3–4, pp. 346–349. https://doi.org/10.1016/j.hydromet.2008.05.011
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Kuzmin, V.I., Kuzmina, A.A. Obtaining Solid Extractants Based on Mixtures of Tributylphosphate and Molecular Iodine and Researching the Extraction of Scandium from Chloride Solutions. Theor Found Chem Eng 55, 1073–1077 (2021). https://doi.org/10.1134/S0040579521050092
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DOI: https://doi.org/10.1134/S0040579521050092