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Interphase Distribution of Lanthanide Salts in Multicomponent Aqueous–Organic Two-Phase Systems

  • CHEMISTRY AND TECHNOLOGY OF RARE, TRACE, AND RADIOACTIVE ELEMENTS
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Abstract

The interphase distribution of lanthanide salts in ternary aqueous–organic systems of various compositions has been studied. It has been shown that the distribution of lanthanide salts in multicomponent aqueous–organic systems differs from their distribution in extraction systems. The order of extractability of lanthanide chlorides and lanthanide nitrates in a 1 : 1 : 1 system (0.5 M NaCl (NaNO3) in water–binary extractant in hexane–isopropyl alcohol) has been determined.

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REFERENCES

  1. Michelsen, O.B. and Smutz, M., Separation of yttrium, holmium, and erbium with di-(2-ethylhexyl) phosphoric acid in chloride and nitrate systems, J. Inorg. Nucl. Chem., 1971, vol. 33, no. 1, pp. 265–278. https://doi.org/10.1016/0022-1902(71)80028-3

    Article  CAS  Google Scholar 

  2. Minagawa, Y. and Yamaguchi, K., Relative extraction rates of rare earth ions from weakly acidic solution of binary mixture of rare earth chlorides by di-(2-ethyl-hexyl) phosphoric acid/kerosine, Hydrometallurgy, 1990, vol. 24, no. 3, pp. 333–350. https://doi.org/ 10.1016/0304-386X(90)90097-L

    Article  CAS  Google Scholar 

  3. Kalyakin, S.N., Kuz’min, V.I., and Mulagaleeva, M.A., The application of binary extractants based on di-(2-ethyl-hexyl) phosphoric acid to the separation of lanthanides, Tsvetn. Met., 2011, no. 3, pp. 51–54.

  4. Kalyakin, S.N., Kuz’min, V.I., and Mulagaleeva, M.A., Binary extraction of lanthanide(III) chlorides using carboxylates and dialkylphosphates of secondary and tertiary amines, Hydrometallurgy, 2015, vol. 151, pp. 116–121. https://doi.org/10.1016/j.hydromet.2014.11.013

    Article  CAS  Google Scholar 

  5. Egorova, N.S., Belova, V.V., Voshkin, A.A., Zhilov, V.I., and Khol’kin, A.I., Extraction of lanthanide chlorides by binary extractants based on phosphinic acid derivatives, Russ. J. Inorg. Chem., 2005, vol. 50, no. 11, pp. 1781–1784.

    Google Scholar 

  6. Belova, V.V., Voshkin, A.A., Kholkin, A.I., and Payrtman, A.K., Solvent extraction of some lanthanides from chloride and nitrate solutions by binary extractants, Hydrometallurgy, 2009, vol. 97, nos. 3–4, pp. 198–203. https://doi.org/10.1016/j.hydromet.2009.03.004

    Article  CAS  Google Scholar 

  7. Zakhodyaeva, Yu.A., Belova, V.V., Egorova, N.S., and Khol’kin, A.I., Extraction of rare earth metal salts using methyltrioctylammonium dialkyl phosphate and dialkyl phosphinate, Khim. Tekhnol., 2015, vol. 16, no. 1, pp. 23–29.

    Google Scholar 

  8. Kostanyan, A.E., Voshkin, A.A., and Kodin, N.V., Controlled-cycle pulsed liquid–liquid chromatography. A modified version of Craig’s counter-current distribution, J. Chromatogr. A, 2011, vol. 1218, no. 36, pp. 6135–6143. https://doi.org/10.1016/j.chroma.2010.12.103

    Article  CAS  Google Scholar 

  9. Kostanyan, A.E., On influence of sample loading conditions on peak shape and separation efficiency in preparative isocratic counter-current chromatography, J. Chromatogr. A, 2012, vol. 1254, pp. 71–77. https:// doi.org/10.1016/j.chroma.2012.07.036

    Article  CAS  Google Scholar 

  10. Kostanyan, A.E., On the description of liquid–liquid chromatography processes with a free stationary phase, Khim. Tekhnol., 2004, vol. 5, no. 8, pp. 39–42.

    Google Scholar 

  11. Kostanyan, A.E., Ignatova, S., Sutherland, I.A., Hewitson, P., Zakhodjaeva, Y.A., and Erastov, A.A., Steady-state and non-steady state operation of counter-current chromatography devices, J. Chromatogr. A, 2013, vol. 1314, pp. 94–105. https://doi.org/10.1016/ j.chroma.2013.08.100

    Article  CAS  Google Scholar 

  12. Kostanyan, A.E., Erastov, A.A., and Shishilov, O.N., Multiple dual mode counter-current chromatography with variable duration of alternating phase elution steps, J. Chromatogr. A, 2014, vol. 1347, pp. 87–95. https:// doi.org/10.1016/j.chroma.2014.04.064

    Article  CAS  Google Scholar 

  13. Kostanyan, A.E., Modeling of closed-loop recycling liquid–liquid chromatography: Analytical solutions and model analysis, J. Chromatogr. A, 2015, vol. 1406, pp. 156–164. https://doi.org/10.1016/ j.chroma.2015.06.010

    Article  CAS  Google Scholar 

  14. Kostanyan, A.E. and Erastov, A.A., Steady state preparative multiple dual mode counter-current chromatography: Productivity and selectivity. Theory and experimental verification, J. Chromatogr. A, 2015, vol. 1406, pp. 118–128. https://doi.org/10.1016/ j.chroma.2015.05.074

    Article  CAS  Google Scholar 

  15. Chollet, S., Marchal, L., Meucci, J., Renault, J.-H., Legrand, J., and Foucault, A., Methodology for optimally sized centrifugal partition chromatography columns, J. Chromatogr. A, 2015, vol. 1388, pp. 174–183. https://doi.org/10.1016/j.chroma.2015.02.043

    Article  CAS  Google Scholar 

  16. Kostanyan, A.E., Erastov, A.A., and Shishilov, O.N., Separation of liquid mixtures by dynamic countercurrent cyclic extraction, Theor. Found. Chem. Eng., 2015, vol. 49, no. 4, pp. 560–566. https://doi.org/10.1134/ S0040579515040119

    Article  CAS  Google Scholar 

  17. Kostanyan, A.E., Analysis of the three-step cyclic process of countercurrent extraction, Theor. Found. Chem. Eng., 2015, vol. 49, no. 2, pp. 183–190. https://doi.org/ 10.1134/S0040579515020050

    Article  CAS  Google Scholar 

  18. Friesen, J.B., Ahmed, S., and Pauli, G.F., Qualitative and quantitative evaluation of solvent systems for countercurrent separation, J. Chromatogr. A, 2015, vol. 1377, pp. 55–63. https://doi.org/10.1016/j.chroma.2014.11.085

    Article  CAS  Google Scholar 

  19. Ito, Y., Golden rules and pitfalls in selecting optimum conditions for high-speed counter-current chromatography, J. Chromatogr. A, 2005, vol. 1065, pp. 145–168. https://doi.org/10.1016/j.chroma.2004.12.044

    Article  CAS  Google Scholar 

  20. Hewitson, P., Sutherland, I., Kostanyan, A.E., Voshkin, A.A., and Ignatova, S., Intermittent counter-current extraction—Equilibrium cell model, scaling and an improved bobbin design, J. Chromatogr. A, 2013, vol. 1303, pp. 18–27. https://doi.org/10.1016/ j.chroma.2013.06.023

    Article  CAS  Google Scholar 

  21. Steblevskaya, N.I., Medkov, M.A., and Belobeletskaya, M.V., Extraction of the coordination compounds of rare earth elements with different ligands and its application to the synthesis of nanosized oxide composites, Vestn. Dal’nevost. Otd. Ross. Akad. Nauk, 2010, no. 5, pp. 67–74.

  22. Peppard, D.F. and Wason, G.W., Liquid-liquid extraction of trivalent rare earths using acidic phosphonates as extractants, Rare Earth Research, Kleber, E.V., Ed., New York: Macmillan, 1961, pp. 37–50.

    Google Scholar 

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ACKNOWLEDGMENTS

This work was supported in part by the Russian Foundation for Basic Research (project no. 17-03-00263) and performed under a state order to the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of basic research.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    V. V. Belova & M. M. Martynova

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  1. V. V. Belova
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  2. M. M. Martynova
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Correspondence to V. V. Belova.

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Translated by M. Timoshinina

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Belova, V.V., Martynova, M.M. Interphase Distribution of Lanthanide Salts in Multicomponent Aqueous–Organic Two-Phase Systems. Theor Found Chem Eng 53, 921–924 (2019). https://doi.org/10.1134/S0040579518050056

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  • DOI: https://doi.org/10.1134/S0040579518050056

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