Skip to main content
SpringerLink
Log in

Synthesis and physicochemical properties of NaK, K, Na, and Li forms of LSX zeolite

  • Technology of Inorganic Substances and Materials
  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

Powder LSX zeolite samples of high phase purity and near 100% crystallinity have been synthesized in NaK, K, Na, and Li forms. The effect of the chemical nature and content of the exchange cation and air calcination temperature on the degree of crystallinity and the porous structure characteristics and adsorption properties of the mentioned LSX zeolite forms were established by X-ray diffraction and adsorption methods.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Fundamentals of Adsorption Engineering), Moscow: Khimiya, 1984.

    Google Scholar 

  2. Zhdanov, S.P., Khvoshchev, S.S., and Samulevich, N.N., Sinteticheskie tseolity: Kristallizatsiya, strukturno-khimicheskoe modifitsirovanie i adsorbtsionnye svoistva (Synthetic Zeolites. Crystallization, Structural and Chemical Modification, and Adsorption Properties), Moscow: Khimiya, 1981.

    Google Scholar 

  3. Shumyatskii, Yu.I., Promyshlennye adsorbtsionnye protsessy (Industrial Adsorption Processes), Moscow: Kolos, 2009.

    Google Scholar 

  4. Glupanov, V.N., Shumyatskii, Yu.I., Seregin, Yu.A., and Brekhner, S.A., Poluchenie kisloroda i azota adsorbtsionnym razdeleniem vozdukha (Obtaining Oxygen and Nitrogen by the Adsorptive Separation of Air),. TsINTIKhIMNEFTEMASh, 1991.

    Google Scholar 

  5. Hutson, N.D., Zajic, S.C., Rege, S.U., and Yang, R.T., Air Separation by Pressure Swing Adsorption Using Superior Adsorbents, Final Technical Report, 1998–2001, DE-FG26-98FT40115, Department of Chem. Eng. Univ. Michigan, Ann Arbor, Mich., 48109-2136.

  6. Bülow, M. and Shen, D., Sorption kinetics of atmospheric gases on Li, RE(rare earth)-LSX zeolite beads as sorbents for oxygen PVSA processes, Microporous Mesoporous Mater., 2007, vol. 105, nos. 1–2, pp. 163–169.

    Article  Google Scholar 

  7. Stuckert, N.R. and Yang, R.T., CO2 capture from the atmosphere and simultaneous concentration using zeolites and amine-grafted SBA-15, Environ. Sci. Technol., 2011, vol. 45, pp. 10257–10264.

    Article  CAS  Google Scholar 

  8. Tolmachev, A.M., Nikoleshina, V.A., and Chelishchev, N.F., Study of zeolites as selective ion exchangers for separation of mixtures of substances and isotopes similar in their properties, in Sovremennye problemy fizicheskoi khimii (Current Topics in Physical Chemistry), Moscow: Mosk. Gos. Univ., 1978, vol.10.

  9. Pavlova, I.N., Ilibaev, R.S., Travkina, O.S., and Kutepov, B.I., Exchange forms of binder-free granulated zeolites A and X: Synthessis and properties, Pet. Chem., 2013, vol. 53, no. 2, pp. 102–109.

    Article  CAS  Google Scholar 

  10. Gunter, K., Crystallization of low-module FAU type zeolite, Zeolites, 1987, no. 7, pp. 451–457.

    Article  Google Scholar 

  11. Treacy, M.M.J. and Higgins, J.B., Collection of Simulated XRD Powder Patterns of Zeolites, Amsterdam: Elsevier, 2001.

    Google Scholar 

  12. Pavlova, I.N., Ilibaev, R.S., Drozdov, V.A., and Kutepov, B.I., Cation-exchange forms of binder-free granular zeolite X: Synthesis and properties, Khim. Tekhnol., 2011, vol. 12, no. 4, pp. 198–202.

    CAS  Google Scholar 

  13. Esposito, S., Ferone, C., Pansini, M., Bonaccorsi, L., and Proverbio, E., A comparative study of the thermal transformations of Ba-exchanged zeolites A, X and LSX, J. Eur. Ceram. Soc., 2004, vol. 24, no. 9, pp. 2689–2697.

    Article  CAS  Google Scholar 

  14. Hutson, N.D. and Yang, R.T., Structural effects on adsorption of atmospheric gases in mixed Li, Ag–Xzeolite, AIChE J., 2000, vol. 46, no. 11, pp. 2305–2317.

    Article  CAS  Google Scholar 

  15. Ruscher, C.H., Salman, N., Buhl, J.-Chr., and Lutz, W., Relation between growth-size and chemical composition of X and Y type zeolites, Microporous Mesoporous Mater., 2006, vol. 92, pp. 309–311.

    Article  Google Scholar 

  16. Breck, D.W., Zeolitic Molecular Sieves: Structure, Chemistry and Use, New York: Wiley, 1974.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia

    I. N. Pavlova, O. S. Travkina & B. I. Kutepov

  2. OOO Ishimbai Specialized Chemical Plant of Catalysts, ul. Levyi bereg 6, Ishimbai, 453210, Bashkortostan, Russia

    G. F. Garieva

  3. Bashkir State University, ul. Zaki Validi 32, Ufa, 450076, Bashkortostan, Russia

    A. D. Badikova

Authors
  1. I. N. Pavlova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. S. Travkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. F. Garieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. I. Kutepov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. D. Badikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. N. Pavlova.

Additional information

Original Russian Text © I.N. Pavlova, O.S. Travkina, G.F. Garieva, B.I. Kutepov, A.D. Badikova, 2015, published in Khimicheskaya Tekhnologiya, 2015, Vol. 16, No. 11, pp. 648–656.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pavlova, I.N., Travkina, O.S., Garieva, G.F. et al. Synthesis and physicochemical properties of NaK, K, Na, and Li forms of LSX zeolite. Theor Found Chem Eng 51, 543–550 (2017). https://doi.org/10.1134/S0040579516050201

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0040579516050201

Keywords

Search

Navigation