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Ion-exchange synthesis of α-modification of nickel hydroxide

  • Technology of Inorganic Substances and Materials
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Abstract

An anion-exchange method for synthesizing nickel hydroxide using industrial strongly basic AV-17-8 anionite has been proposed. The influence of conditions (concentration and nature of starting salt, amount of the anionite, process duration, etc.) on the precipitate yield has been established. The product has been investigated by scanning electron microscopy, IR and Raman spectroscopy, X-ray phase analysis, and thermal and chemical analyses. It has been established that the product is a disordered layered modification of nickel hydroxide α-Ni(OH)2, which contains anions and water molecules in the interlayer spacing. Nickel hydroxide particles are needle crystals (40–80 nm) that form agglomerates 0.3–0.5 μm in size.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia

    G. L. Pashkov, M. V. Panteleeva & E. V. Linok

  2. Siberian Federal University, Krasnoyarsk, Russia

    S. V. Saikova

Authors
  1. G. L. Pashkov
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  2. S. V. Saikova
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  3. M. V. Panteleeva
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  4. E. V. Linok
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Corresponding author

Correspondence to G. L. Pashkov.

Additional information

Original Russian Text © G.L. Pashkov, S.V. Saikova, M.V. Panteleeva, E.V. Linok, 2013, published in Khimicheskaya Tekhnologiya, 2013, Vol. 14, No. 10, pp. 585–591.

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Pashkov, G.L., Saikova, S.V., Panteleeva, M.V. et al. Ion-exchange synthesis of α-modification of nickel hydroxide. Theor Found Chem Eng 48, 671–676 (2014). https://doi.org/10.1134/S0040579514050066

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  • DOI: https://doi.org/10.1134/S0040579514050066

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