Skip to main content
SpringerLink
Log in

Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The enthalpies of dissolution of crystalline glycyl-L-tyrosine in water and in aqueous potassium hydroxide at 298.15 К were determined by the direct calorimetric method. The measurements were performed on a calorimetric unit with automatic recording of the temperature–time curve. The standard enthalpies of combustion and formation of glycyl-L-tyrosine were calculated by the additive group method based on group systematics with classification of fragments of the type of Benson classification, with the effect of the initial environment for atoms included in calculation. The standard enthalpies of formation of dipeptide and the products of its dissociation in aqueous solution were calculated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. A. V. Gumen, A. A. Butyugov, P. G. Nazarov, and V. V. Malinin, Byul. Eksp. Biol. Med. 131, 314 (2001).

    Google Scholar 

  2. N. I. Chalisova, A. N. Zakutskii, A. I. Aniskina, et al., Med. Akad. Zh. 6 (3), 57 (2006).

    Google Scholar 

  3. I. G. Kozlov, N. K. Gorina, and A. N. Cheredeeva, Immunologiya, No. 2, 45 (1997).

  4. E. A. Markevicheva, S. V. Kuptsova, and L. D. Rumin, Vopr. Med. Khim. 48, 570 (2002).

    Google Scholar 

  5. D. M. Miller, D. de Silva, L. Pickart, and S. D. Aust, Adv. Exp. Med. Biol. 264, 79 (1990).

    Article  CAS  PubMed  Google Scholar 

  6. P. P. Korostelev, Preparation of Solutions for Chemical Analysis (Akad. Nauk SSSR, Moscow, 1962) [in Russian].

    Google Scholar 

  7. A. I. Lytkin, V. P. Barannikov, V. G. Badelin, and O. N. Krutova, J. Therm. Anal. Calorim. 139, 3683 (2020).https://doi.org/10.1007/s10973-019-08604-y

    Article  CAS  Google Scholar 

  8. W. B. Parcker, Thermal Properties of Aqueous Uni-Univalent Electrolytes (NSRDS-NBS, Washington, DC, 1965), No. 2, p. 342.

  9. A. V. Volkov, O. Yu. Platonycheva, O. N. Krutova, and V. G. Gradusov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 52 (4), 7 (2009).

    CAS  Google Scholar 

  10. L. A. Kochergina, V. G. Badelin, O. N. Krutova, A. V. Volkov, and K. V. Damrina, Russ. J. Phys. Chem. A 89, 1223 (2015).

    Article  CAS  Google Scholar 

  11. V. P. Vasil’ev, V. A. Borodin, and S. B. Kopnyshev, Russ. J. Phys. Chem. A 65, 14 (1991).

    Google Scholar 

  12. A. V. Takhistov and D. A. Ponomarev, Organic Mass Spectrometry (VVM, St. Petersburg, 2002) [in Russian].

  13. T. Kiss and Z. Szucs, J. Chem. Soc., Dalton Trans. 2, 2443 (1986).

    Article  Google Scholar 

  14. V. P. Vasil’ev, Thermodynamical Properties of Electrolyte Solutions (Vysshaya Shkola, Moscow, 1982) [in Russian].

    Google Scholar 

  15. Thermal Properties of Individual Substances, Ed. by V. P. Glushko (VINITI, Moscow, 1965–1971), Vol. 3 [in Russian].

    Google Scholar 

  16. V. G. Badelin, E. Yu. Tyunina, and G. N. Tarasova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 50 (9), 76 (2007).

    CAS  Google Scholar 

  17. A. I. Lytkin, V. V. Chernikov, O. N. Krutova, and E. D. Krutova, Russ. J. Phys. Chem. A 94, 2569 (2020).

    Article  CAS  Google Scholar 

  18. A. I. Lytkin, V. V. Chernikov, O. N. Krutova, and E. D. Krutova, Russ. J. Phys. Chem. A 94, 1342 (2020).

    Article  CAS  Google Scholar 

  19. A. I. Lytkin, V. V. Chernikov, O. N. Krutova, K. V. Damrina, and I. A. Skvortsov, Russ. J. Phys. Chem. A 90, 735 (2016).

    Article  CAS  Google Scholar 

  20. L. A. Kochergina, V. G. Badelin, A. I. Lytkin, et al., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 57 (8), 11 (2014).

    CAS  Google Scholar 

  21. A. I. Lytkin, V. V. Chernikov, O. N. Krutova, and P. D. Krutov, Russ. J. Phys. Chem. A 94, 883 (2020).

    Article  CAS  Google Scholar 

  22. A. I. Lytkin, V. V. Chernikov, and O. N. Krutova, Russ. J. Phys. Chem. A 90, 1530 (2016).

    Article  CAS  Google Scholar 

  23. A. I. Lytkin, V. V. Chernikov, O. N. Krutova, I. A. Skvortsov, and A. S. Korchagina, Russ. J. Phys. Chem. A 90, 1782 (2016).

    Article  Google Scholar 

Download references

Funding

This study was performed at the Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology (ISUCT) (project no. FZZW-2023-0008). It was conducted using the resources of the ISUCT Multiaccess Center and supported by the Ministry of Science and Higher Education of Russia (grant no. 075-15-2021-671).

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    O. N. Krutova, M. I. Bazanov, V. V. Chernikov & P. D. Krutov

Authors
  1. O. N. Krutova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. I. Bazanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Chernikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. D. Krutov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to P. D. Krutov.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by L. Smolina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krutova, O.N., Bazanov, M.I., Chernikov, V.V. et al. Standard Enthalpies of Formation of Glycyl-L-tyrosine and Its Dissociation Products in Aqueous Solutions. Russ. J. Phys. Chem. 97, 2362–2366 (2023). https://doi.org/10.1134/S0036024423110171

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024423110171

Keywords:

Search

Navigation