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Phase Transition Thermodynamics: Evaporation Enthalpy of 13 Naphthalene Derivatives

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
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Abstract

The quality of naphthalene derivatives in use is assessed by their phase transition thermodynamic properties. The naphthalene derivatives’ sublimation/vaporization enthalpy was determined at 298.15 K. The evaporation enthalpy of the compounds was estimated utilizing solution calorimetry-additive scheme approach. Adiabatic solution calorimetry was applied to measure the compounds’ solution enthalpies in the benzene solvent at 298.15 K. Additionally, using an additivity scheme approach, the solvation enthalpy for naphthalene derivatives was calculated. In addition, in order to measure the evaporation enthalpy of naphthalene derivatives, gas chromatography was also applied. The results of the evaporation enthalpies were quite compatible with those found in the published data. For the first time, the evaporation enthalpy of nine naphthalene derivatives was discovered.

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  1. Department of Physical Chemistry, Butlerov Institute of Chemistry, Kazan Federal University, 420008, Kazan, Russia

    R. S. Abdullah

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Abdullah, R.S. Phase Transition Thermodynamics: Evaporation Enthalpy of 13 Naphthalene Derivatives. Russ. J. Phys. Chem. 97, 1361–1367 (2023). https://doi.org/10.1134/S0036024423070245

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