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MOF-Derived Co3O4/C Microspheres As High-Performance Anode Materials for Lithium-Ion Batteries

  • COLLOID CHEMISTRY AND ELECTROCHEMISTRY
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Abstract

Co3O4/C composites with microsphere structure were prepared by heat treatment of Co-based metal-organic framework (MOF). The structure and composition of Co3O4/C material were studied by X‑ray diffraction (XRD), scanning electron microscopy (SEM), and other test methods. In the voltage range of 0.01–3.0 V and the current density of 0.05 A g–1, the initial capacity of Co3O4/C calcined at 600°C is 1554.25 mA h g–1. After 60 times of charging and discharging at different current densities, Co3O4/C-600 has excellent rate performance and maintains a specific capacity of 1042 mA h g–1 at a current density of 0.05 A g–1. The good rate performance of Co3O4/C-600 is due to the structure which is dispersed on the carbon substrate and the excellent specific surface area. Therefore, Co3O4/C composite is considered as promising anode material for lithium batteries.

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ACKNOWLEDGMENTS

This work was supported by National International Technology Cooperation Plan (grant no. 2014DFR50570).

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Authors and Affiliations

  1. Laboratory of Environment Functional Materials of Tangshan City, Hebei Provincial Key Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering, North China University of Science and Technology, 063210, Tangshan, Hebei, China

    Ruohan Guan, Guixia Dong, Zongfeng Li & Shuangjuan Yang

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  1. Ruohan Guan
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  2. Guixia Dong
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  3. Zongfeng Li
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  4. Shuangjuan Yang
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Correspondence to Guixia Dong.

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Guan, R., Dong, G., Li, Z. et al. MOF-Derived Co3O4/C Microspheres As High-Performance Anode Materials for Lithium-Ion Batteries. Russ. J. Phys. Chem. 96 (Suppl 1), S175–S182 (2022). https://doi.org/10.1134/S0036024422140114

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