Skip to main content
SpringerLink
Log in

Vibrational Satellites and Hindered Pseudorotation in 2-Methyltetrahydrofuran

  • STRUCTURE OF MATTER AND QUANTUM CHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Microwave spectroscopy is used to study the microwave rotational spectrum of a 2-methyltetrahydrofuran molecule in three excited states of hindered pseudorotation. The rotational constants and components of the molecule’s dipole moment in these states are determined. An attempt is made to determine the shape of the potential curve of the molecule’s hindered pseudorotation, based on these data and the results from quantum-chemical calculations.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. M. G. Faizullin, R. V. Galeev, and A. Kh. Mamleev, Russ. J. Phys. Chem. A 91, 2275 (2017). https://doi.org/10.1134/S0036024417110061

    Article  CAS  Google Scholar 

  2. V. Van, W. Stahl, and H. V. L. Nguyen, J. Mol. Struct. 1123, 24 (2016). https://doi.org/10.1016/j.molstruc.2016.05.078

    Article  CAS  Google Scholar 

  3. D. Cremer and J. A. Pople, J. Am. Chem. Soc. 97, 1354 (1975). https://doi.org/10.1021/ja00839a011

    Article  CAS  Google Scholar 

  4. A. A. Granovsky, Firefly, Version 8. http://classic.chem.msu.su/gran/firefly/index.html.

  5. J. R. Durig, K. L. Kizer, and J. M. Karriker, J. Raman Spectrosc. 1, 17 (1973). https://doi.org/10.1002/jrs.1250010103

    Article  CAS  Google Scholar 

  6. D. O. Harris, G. G. Engerholm, C. A. Tolman, et al., J. Chem. Phys. 50, 2438 (1969). https://doi.org/10.1063/1.1671400

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Molecule and Crystal Physics - Subdivision of the Ufa Federal Research Centre of the Russian Academy of Sciences, 450054, Ufa, Russia

    M. G. Faizullin & R. V. Galeev

Authors
  1. M. G. Faizullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. V. Galeev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. G. Faizullin.

Additional information

Translated by A. Ivanov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Faizullin, M.G., Galeev, R.V. Vibrational Satellites and Hindered Pseudorotation in 2-Methyltetrahydrofuran. Russ. J. Phys. Chem. 96, 2137–2142 (2022). https://doi.org/10.1134/S0036024422090084

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024422090084

Keywords:

Search

Navigation