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Selective Oxidation of Glycerol to Lactic Acid over Supported Bimetallic Au–M Catalysts

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

A series of bimetallic Au–M (Pt, Pd, Cu, Ir, Ag) catalysts supported on composite oxide were prepared through the deposition of pre-formed Au–M colloids. These catalysts were evaluated in the selective oxidation of glycerol to lactic acid. The results showed that MgLaO composite oxide supported Au–Pt catalyst has the optimal catalytic activity and selectivity. Furthermore, it was found that the category of the second active component has great influence on the catalytic activity of Au–M/MgLaO (M = Pt, Pd, Cu, Ir, Ag) catalysts. XRD, XPS, TEM, HRTEM, and H2-TPR analyses demonstrated that the structure of the supports and the interaction between Au and the second active component had an effect on catalytic activity and selectivity. Meanwhile, the Au–Pt/MgLaO catalyst also presented great performance in recyclability without any obvious change in catalytic activity, but a little decrease of selectivity was observed after 7 cycles.

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ACKNOWLEDGMENTS

This work was supported by the Key Scientific Research Projects in 2017 at North Minzu University (grant no. 2017KJ15).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, North Minzu University, 750021, Yinchuan, China

    Yi-Hu Ke, Xue Wang, Jing-Yun Li, Hai Liu & Hong Yuan

  2. Key Laboratory of Chemical Engineering and Technology, State Ethnic Affairs Commission, North Minzu University, 750021, Yinchuan, China

    Yi-Hu Ke, Xue Wang, Jing-Yun Li, Hai Liu & Hong Yuan

  3. Ningxia Key Laboratory of Solar Chemical Conversion Technology, North Minzu University, 750021, Yinchuan, China

    Yi-Hu Ke, Xue Wang, Jing-Yun Li, Hai Liu & Hong Yuan

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  1. Yi-Hu Ke
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Ke, YH., Wang, X., Li, JY. et al. Selective Oxidation of Glycerol to Lactic Acid over Supported Bimetallic Au–M Catalysts. Russ. J. Phys. Chem. 95 (Suppl 2), S264–S275 (2021). https://doi.org/10.1134/S0036024421150139

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