Skip to main content
SpringerLink
Log in

Solubility and Dissolution Thermodynamics of 1,1-Bis(3-methyl-4-hydroxyphenyl)cyclohexane (MeBZ) in Different Pure Organic Solvents in the Temperature Range from 299.15 to 328.15 K

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The solubility of 1,1-bis(3-methyl-4-hydroxyphenyl)cyclohexane (MeBZ) in different pure organic solvents such as methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, acetone, 1,4-dioxane, ethylacetate, and tetrahydrofuran over a temperature range from 299.15 to 328.15 K at atmospheric pressure were measured by gravimetric method. The solubility increased significantly with increase in temperature in all studied solvents. Among the studied solvents, tetrahydrofuran showed the highest solubility at 328.15 K. The experimental solubilities were corelated with the modified Apelbalt equation and Buchowski–Ksiazczak (λh) equation.The thermodynamic parameters such as enthalpies of solution (\(\Delta H_{{{\text{sol}}}}^{^\circ }\)), Gibbs energy of dissolution (\(\Delta G_{{{\text{sol}}}}^{^\circ }\)), isobaric heat capacity(\(\Delta C_{{p\;{\text{sol}}}}^{^\circ }\)), and entropy of solutions (\(\Delta S_{{{\text{sol}}}}^{^\circ }\)) were calculated using Clark and Glew equation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. R. N. Johnson, A. G. Farnham, R. A. Glendinning, W. E. Hale, and C. N. Marriam, J. Polymer Sci., Part A 5, 2375 (1967).

    CAS  Google Scholar 

  2. E. A. Hassan, A. M. Naser, and M. M. Wassel, Paint India 28, 23 (1978);

    Google Scholar 

  3. Chem. Abstr. 90, 73352 (1979).

  4. V. V. Korshak, S. V. Vinogradova, and Y. S. Vygodskii, Macromol. J. Sci. Rev. - Macromol. Chem. 11, 45 (1974).

    Article  CAS  Google Scholar 

  5. N. A. Karmishina, E. N. Rodlovskaya, B. A. Izmailov, V. A. Vasnev, and M. I. Buzin, Russ. J. Appl. Chem. 85, 674 (2012).

    Article  CAS  Google Scholar 

  6. C. A. Wilson, US Patent No. 04457922 (1984).

  7. R. W. Gregor, J. Chem. Educ. 89, 669 (2012).

    Article  CAS  Google Scholar 

  8. M. Stolka, D. M. Pai, D. S. Renfer and J. F. Yanus, J. Polym. Sci., Part A 21, 969 (1983).

    CAS  Google Scholar 

  9. J. E. Biles, T. P. McNeal, T. H. Begley, and H. C. Hollifield, J. Agric. Food Chem. 45, 3541 (1997).

    Article  CAS  Google Scholar 

  10. J. E. Biles, K. D. White, T. P. McNeal, and T. H. Begley, J. Agric. Food Chem. 47, 1965 (1999).

    Article  CAS  Google Scholar 

  11. J. A. Riddick, W. B. Bunger, and T. Sakano, Organic Solvents—Physical Properties and Methods of Purification Techniques of Chemistry, 4th ed. (Wiley, New York, 1986).

    Google Scholar 

  12. M. V. Rao, A. J. Rojivadia, P. H. Parsania, and H. H. Parekh, J. Ind. Chem. Soc. 64, 758 (1987).

    CAS  Google Scholar 

  13. H. H. Garcher, H. N. Shukla, and P. H. Parsania, Ind. Acad. Sci. (Chem. Sci.) 103, 149 (1991).

    Google Scholar 

  14. E. S. Ha, Y. R. Lee, and M. S. Kim, J. Mol. Liq. 216, 360 (2016).

    Article  CAS  Google Scholar 

  15. F. Shakeel, N. Haq, F. K. Alanazi, and I. A. Alsarra, J. Mol. Liq. 209, 280 (2015).

    Article  CAS  Google Scholar 

  16. J. Chen, G. Nan, R. Yang, S. Zhang, X. Bian, and G. Yang, J. Mol. Liq. 204, 137 (2015).

    Article  CAS  Google Scholar 

  17. A. Patel, A. Vaghasiya, R. Gajera, and S. Baluja, J. Chem. Eng. Data 55, 574 (2010).

    Article  Google Scholar 

  18. A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 31, 85 (1999).

    Article  CAS  Google Scholar 

  19. A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 29, 1527 (1997).

    Article  CAS  Google Scholar 

  20. A. Apelblat and E. Manzurola, J. Chem. Thermodyn. 3l, 85 (1999).

    Article  Google Scholar 

  21. H. Buchowski, A. Ksiazczak, and S. Pietrzyk, J. Phys. Chem. 84, 975 (1980).

    Article  CAS  Google Scholar 

  22. A. Ksiazczak and J. Kosinski, Fluid Phase Equilib. 44, 211 (1988).

    Article  CAS  Google Scholar 

  23. A. Ksiazczak, K. Moorthi, and I. Nagata, Fluid Phase Equilib. 95, 15 (1994).

    Article  CAS  Google Scholar 

  24. M. Gantiva and F. Martinez, Fluid Phase Equilib. 293, 242 (2010).

    Article  CAS  Google Scholar 

  25. S. Baluja and R. Talaviya, J. Mol. Liq. 223, 436 (2016).

    Article  CAS  Google Scholar 

  26. E. Clarke and D. Glew, Trans. Faraday Soc. 62, 539 (1966).

    Article  CAS  Google Scholar 

  27. A. Kustov and M. Berezin, J. Chem. Eng. Data 58, 2502 (2013).

    Article  CAS  Google Scholar 

  28. C. Li, Q. Wang, B. Shen, Z. Xiong, and C. Chen, J. Chem. Eng. Data 59, 3953 (2014).

    Article  CAS  Google Scholar 

  29. C. Li, Q. Wang, B. Shen, Z. Xiong, and C. Chen, J. Chem. Eng. Data 60 (3), 925 (2015).

  30. A. C. Galvão, W. S. Robazza, A. D. Bianchi, J. A. Matiello, A. R. Paludo, and R. Thomas, J. Chem. Thermodyn. 121, 8 (2018).

    Article  Google Scholar 

  31. F. Shakeel, N. Haq, M. Raish, M. K. Anwer, and R. Al-Shdefat, J. Mol. Liq. 222, 167 (2016).

    Article  CAS  Google Scholar 

  32. F. Shakeel, M. Imran, Abida, N. Haq, F. K. Alanazi, and I. A. Alsarra, J. Mol. Liq. 230, 511 (2017).

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are highly thankful to Dr. Keyur Shah Principal, Shri M.M. Patel Institute of Science and Research, for providing infrastructure facility for performing the experiments.

Author information

Authors and Affiliations

  1. Department of Chemistry, Kadi Sarva Vishvavidyalaya, Gandhinagar, Gujarat, India

    Rizwan Ghumara & Akshay Prajapati

  2. Department of Chemistry, C.U. Shah University, Wadhwan, Gujarat, India

    Haresh Modi

  3. Department of Chemistry, Saurashtra University, Rajkot, Gujarat, India

    P. H. Parsania

  4. Department of Chemistry, Krantiguru Shyamji Krishna Verma Kachchh University, Bhuj, India

    Chirag Patel

Authors
  1. Rizwan Ghumara
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Haresh Modi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Akshay Prajapati
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Chirag Patel
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. H. Parsania
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Chirag Patel.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rizwan Ghumara, Modi, H., Prajapati, A. et al. Solubility and Dissolution Thermodynamics of 1,1-Bis(3-methyl-4-hydroxyphenyl)cyclohexane (MeBZ) in Different Pure Organic Solvents in the Temperature Range from 299.15 to 328.15 K. Russ. J. Phys. Chem. 95, 21–28 (2021). https://doi.org/10.1134/S0036024421010088

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024421010088

Keywords:

Search

Navigation