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On the Modeling of the S-Shaped Thermodynamic and Transport Behavior against the Atomic Number Z of Some Trivalent f-Element Ions in Aqueous Solutions at 298 K and Prediction for Completion of the Periodic Table of Chemical Elements

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Abstract

Ionic self-diffusion coefficients D of some trivalent lanthanide and actinide ions have been determined by the open-end capillary method (O.E.C.M.) in supporting lanthanide electrolyte 1 : 3 aqueous solutions at 25°C and optimal pH 2.50 in order to avoid hydrolysis, ion pairing and complexing of trivalent 4f ions. This study contributes to demonstrate similarities in transport and structure properties between 4f and 5f trivalent ions explained by a similar electronic configuration, ionic radius and same hydration number. These similarities are manifested in a strong causal correlation between certain properties by linear or S-shaped behaviors. In this context, we have suggested some expressions relating these properties and interesting to estimate or predict, by interpolation or extrapolation methods, some eventually not available experimental values, especially for the actinides for which the half-life is very short or the experimental conditions are very special and expensive. For this issue, we can contribute to the complement of periodic table of elements by some physicochemical properties, especially for the 5f-series, when we have some available data on the 4f‑series as well as the mathematical function of the causal correlation between these two nf-series.

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ACKNOWLEDGMENTS

This paper is a contribution to celebrate the International Year of the Periodic Table of Chemical Elements (IYPT2019) and it is dedicated to the memory of the Eminent Russian Chemist, Dmitri Ivanovich Mendeleev (1834–1907) Saint-Petersbourg, Russia. The actinide data are developed in Oak-Ridge, Tennessee USA with Prof. H. Latrous and Prof. J.H. Oliver co-worker of Prof. G.T. Seaborg (Nobel Prize in Chemistry 1951, University of California, Berkeley, USA). For this opportunity, Pr.H. Latrous thanks Dr. R.G. Haire (Oak Ridge National Laboratory Tennessee USA) for fruitful discussions during the experimental determination of transuranium ionic self-diffusion data. The lanthanide data are developed in FST, UTM, Tunisia with Professors N. Ouerfelli, M. Ammar, and H. Latrous under the honorable consultation and helpful discussions and suggestions of Prof. Marius Chemla, Tunisian origin (Univ. Pierre et Marie Curie, Paris VI, France) and Student of Irene and Frederic Joliot-Curie (Nobel Prize in Chemistry 1935).

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, 31441, Dammam, Saudi Arabia

    N. Ouerfelli

  2. Basic and Applied Scientific Research Center, Imam Abdulrahman Bin Faisal University, P.O. Box 1982, 31441, Dammam, Saudi Arabia

    N. Ouerfelli

  3. University of Tunis El Manar, Laboratoire Biophysique et de Technologies Médicales LR13ES07, Institut Supérieur des Technologies Médicales de Tunis, 1006, Tunis, Tunisia

    H. Latrous

  4. Oak-Ridge National Laboratory, P.O. Box 2008, TN 37831, Oak Ridge, Tennessee, U.S.A.

    J. H. Oliver

  5. Laboratoire LI2C-Electrochimie, UMR CNRS 7612, Université P. & M. Curie, 75252, Paris Cedex 05, France

    M. Chemla

  6. University of Tunis El Manar, Laboratoire de Diffusion ionique, Département de Physique. F.S.T., El Manar II, 2092, Tunis, Tunisia

    M. Ammar

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  1. N. Ouerfelli
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Correspondence to N. Ouerfelli.

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Ouerfelli, N., Latrous, H., Oliver, J.H. et al. On the Modeling of the S-Shaped Thermodynamic and Transport Behavior against the Atomic Number Z of Some Trivalent f-Element Ions in Aqueous Solutions at 298 K and Prediction for Completion of the Periodic Table of Chemical Elements. Russ. J. Phys. Chem. 94, 2077–2083 (2020). https://doi.org/10.1134/S0036024420100210

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