Abstract
The effect of nontransition metal and ammonium salts on the salting-out of the pseudocationic ethoxylated surfactant Ethomeen C/15 was studied under polythermal conditions. The most effective salting-out agents were the salts of multiply charged oxygen-containing acids at room temperature and alkali metal chlorides at higher temperatures. The distribution of some organic complexing reagents in Ethomeen C/15–water and NaCl–Ethomeen C/15–water systems at 60°C was studied. The distribution coefficient of the reagents was found to depend on their hydrophilicity and composition of the extraction system.
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REFERENCES
C. B. Ojeda and F. S. Rojas, Microchim. Acta 177, 1 (2012).
The Application of Green Solvents in Separation Processes, Ed. by F. Pena-Pereira and M. Tobiszewski (Elsevier, Amsterdam, 2017).
The Role of Colloidal Systems in Environmental Protection, Ed. by M. Fanun (Elsevier, Amsterdam, 2014).
A. V. Stankova, A. M. Elokhov, S. A. Denisova, and A. E. Lesnov, Russ. Chem. Bull. 67, 1608 (2018).
H. A. Maturana, H. A. Maturana, I. M. Perič, S. A. Pooley, and B. L. Rivas, Polym. Bull. 45, 425 (2000).
L. Bulgariu and D. Bulgariu, J. Chromatogr., A 1196, 117 (2008).
M. Shibukawa, N. Nakayama, T. Hayashi, et al., Anal. Chim. Acta 427, 293 (2001).
Yu. A. Zolotov, B. Z. Iofa, and L. K. Chuchalin, Extraction of the Halide Complexes of Metals (Nauka, Moscow, 1973) [in Russian].
K. Pytlakowska, V. Kozik, and M. Dabioch, Talanta 110, 202 (2013).
M. A. Bezerra, M. A. Z. Arruda, and S. L. C. Ferreira, Appl. Spectrosc. Rev. 40, 269 (2005).
S. A. Denisova, A. E. Lesnov, and N. N. Ostanina, J. Anal. Chem. 73, 427 (2018).
S. A. Denisova, N. N. Ostanina, A. E. Lesnov, and O. S. Kudryashova, Khim. Inter. Ustoich. Razvit. 21, 475 (2013).
A. M. Elokhov, A. E. Lesnov, and O. S. Kudryashova, Russ. J. Gen. Chem. 85, 2657 (2015).
S. A. Denisova, O. S. Kudryashova, A. M. Elokhov, and A. E. Lesnov, Russ. J. Inorg. Chem. 64, 810 (2019).
Y. Marcus, J. Chem. Soc., Faraday Trans. 87, 2995 (1991).
A. M. Elokhov, O. S. Kudryashova, and A. E. Lesnov, Russ. J. Inorg. Chem. 62, 1267 (2017).
A. V. Stankova, A. M. Elokhov, and O. S. Kudryashova, Russ. J. Phys. Chem. A 92, 1386 (2018).
A. M. Elokhov, A. E. Lesnov, and O. S. Kudryashova, Russ. J. Inorg. Chem. 63, 1636 (2018).
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Elokhov, A.M., Belova, D.S., Denisova, S.A. et al. Optimization of Extraction Parameters for Inorganic Salt–Ethomeen C/15–Water Systems. Russ. J. Phys. Chem. 94, 1350–1355 (2020). https://doi.org/10.1134/S0036024420070122
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DOI: https://doi.org/10.1134/S0036024420070122