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Measurement and Correlation of the Solubility, Dissolution Enthalpy, and Entropy of R-2[4-(6-Chloro-2-benzoxazolyloxy)phenoxy]propanoic Acid in Different Pure Solvents

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
  • Published:
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Abstract

The solubility of R-2[4-(6-chloro-2-benzoxazolyloxy)phenoxy]propanoic acid (abbreviated as Fenoxaprop-P) in acetone, methyl ethyl ketone (MEK), 1,4-butyrolactone, acetonitrile, DMF, isopropyl alcohol (IPA), n-butyl alcohol and THF were measured at temperatures ranging from 273.15 to 323.15 K at atmospheric pressure using a laser detecting system. First, the solubility data were correlated by the Buchowski–Ksiazczak λh equation and modified Apelblat equation. Compared with the Apelblat equation, the Buchowski–Ksiazczak λh equation can fit the solubility data well. Then, the dissolution enthalpy, entropy and Gibbs free energy of Fenoxaprop-P were predicted by the van’t Hoff and Gibbs equation.

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ACKNOWLEDGMENTS

This work was supported by the Science and Technology Research key project of the Education Department of Henan Province (no. 16A530002).

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Authors and Affiliations

  1. Environment and Chemistry Engineering Department, Yellow River Conservancy Technical Institute, 475004, Kaifeng, PR China

    Yao Xinding, Ma Jinju, Fang Ruina & Liu Wei

  2. Henan Tobacco Industry Co., Ltd, 450000, Zhengzhou, PR China

    Yuan Qishan

  3. Kaifeng Key Laboratory of Green Coating Materials, 475004, Kaifeng, PR China

    Yao Xinding, Ma Jinju, Fang Ruina & Liu Wei

Authors
  1. Yao Xinding
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  2. Ma Jinju
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  3. Fang Ruina
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  4. Yuan Qishan
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  5. Liu Wei
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Correspondence to Liu Wei.

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Yao Xinding, Jinju, M., Ruina, F. et al. Measurement and Correlation of the Solubility, Dissolution Enthalpy, and Entropy of R-2[4-(6-Chloro-2-benzoxazolyloxy)phenoxy]propanoic Acid in Different Pure Solvents. Russ. J. Phys. Chem. 93, 2340–2348 (2019). https://doi.org/10.1134/S0036024419120343

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  • DOI: https://doi.org/10.1134/S0036024419120343

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