Abstract
Isothermal phase diagrams of ternary systems fullerenol-d–LaCl3–H2O and fullerenol-d–GdCl3–H2O at 25°C are studied via saturation technique. Solubility diagrams are found to be of a simple eutonic type and are characterized by the salting-out of chloride upon adding fullerenol-d, and short branches of LaCl3 · 7H2O and GdCl3 · 6H2O crystallization, where the salting-in effect is observed.
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Funding
This work was supported by the Russian Foundation for Basic Research, project nos. 1-08-08-00143 A, 19-015-00469 А, and 19-016-00003 А.
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Translated by D. Kharitonov
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Keskinov, V.A., Semenov, K.N., Gol’tsov, T.S. et al. Phase Diagrams of Fullerenol-d–LaCl3–H2O and Fullerenol-d–GdCl3–H2O Systems at 25°С. Russ. J. Phys. Chem. 93, 2555–2558 (2019). https://doi.org/10.1134/S0036024419120124
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DOI: https://doi.org/10.1134/S0036024419120124